The Effect of Annealing on the Grain Structure and Ionic Conductivity of Block Copolymer Electrolytes

Grundy, Lorena S.; Fu, Sean; Galluzzo, Michael D.; Balsara, Nitash P.

doi:10.1021/acs.macromol.2c01837

The Effect of Annealing on the Grain Structure and Ionic Conductivity of Block Copolymer Electrolytes

Journal Article · 01 December 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.2c01837· OSTI ID:1989004

Grundy, Lorena S.; Fu, Sean; Galluzzo, Michael D.; Balsara, Nitash P.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Joint Center for Energy Storage Research (JCESR), Energy Innovation Hub-US Department of Energy, Office of Science, Basic Energy Sciences; Office of Science, Office of Basic Energy Sciences, of US Department of Energy(United States Department of Energy (DOE))

OSTI ID:: 1989004

Journal Information:: Macromolecules, Vol. 55, Issue 23

Country of Publication:: United States

Language:: English

References (41)

Polymer Electrolytes No authors listed Annual Review of Materials Research https://doi.org/10.1146/annurev-matsci-071312-121705		July 2013
Poly(ethylene oxide)-based block copolymer electrolytes for lithium metal batteries: PEO-based BCEs for LMBs No authors listed Polymer International https://doi.org/10.1002/pi.5677		August 2018
Melt-Formable Block Copolymer Electrolytes for Lithium Rechargeable Batteries No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/1.1368097		January 2001
Optimization of Block Copolymer Electrolytes for Lithium Metal Batteries No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.5b01273		June 2015
Ion Conduction in Microphase-Separated Block Copolymer Electrolytes No authors listed The Electrochemical Society Interface https://doi.org/10.1149/2.F07171if		January 2017
Block copolymer electrolytes for rechargeable lithium batteries No authors listed Journal of Polymer Science Part B: Polymer Physics https://doi.org/10.1002/polb.23404		November 2013
Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Toluene Solutions No authors listed Macromolecules https://doi.org/10.1021/ma60039a019		May 1974
Lamellar diblock copolymer grain boundary morphology. 1. Twist boundary characterization No authors listed Macromolecules https://doi.org/10.1021/ma00069a016		August 1993
Sculpted grain boundaries in soft crystals No authors listed Science Advances https://doi.org/10.1126/sciadv.aax9112		November 2019
Modeling of transport of small molecules in polymer blends: Application of effective medium theory No authors listed Polymer Engineering and Science https://doi.org/10.1002/pen.760230310		February 1983
Diffusion in Lamellae, Cylinders, and Double Gyroid Block Copolymer Nanostructures No authors listed ACS Macro Letters https://doi.org/10.1021/acsmacrolett.8b00506		August 2018
Intrinsic Ion Transport Properties of Block Copolymer Electrolytes No authors listed ACS Nano https://doi.org/10.1021/acsnano.0c03713		June 2020
Ionic Conductivities of Block Copolymer Electrolytes with Various Conducting Pathways: Sample Preparation and Processing Considerations No authors listed Macromolecules https://doi.org/10.1021/ma300362f		May 2012
Ion Transport Properties of Self-Assembled Polymer Electrolytes: The Role of Confinement and Interface No authors listed The Journal of Physical Chemistry Letters https://doi.org/10.1021/jz4009536		June 2013
Structure–Conductivity Relationships in Ordered and Disordered Salt-Doped Diblock Copolymer/Homopolymer Blends No authors listed Macromolecules https://doi.org/10.1021/acs.macromol.6b01553		September 2016
Effect of Nanoscale Morphology on the Conductivity of Polymerized Ionic Liquid Block Copolymers No authors listed Macromolecules https://doi.org/10.1021/ma201067h		July 2011
Mesophase Structure-Mechanical and Ionic Transport Correlations in Extended Amphiphilic Dendrons No authors listed Science https://doi.org/10.1126/science.1100872		September 2004
Mechanisms of Ordering in Striped Patterns No authors listed Science https://doi.org/10.1126/science.290.5496.1558		November 2000
Role of Grain Boundary Defects During Grain Coarsening of Lamellar Block Copolymers No authors listed Macromolecules https://doi.org/10.1021/ma3015382		December 2012
Engineering the Kinetics of Directed Self-Assembly of Block Copolymers toward Fast and Defect-Free Assembly No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.8b05247		June 2018
Defect Annihilation Pathways in Directed Assembly of Lamellar Block Copolymer Thin Films No authors listed ACS Nano https://doi.org/10.1021/acsnano.8b04202		September 2018
Defect Annihilation in the Directed Self-Assembly of Block Copolymers in Films with Increasing Thickness No authors listed Macromolecules https://doi.org/10.1021/acs.macromol.9b01030		October 2019
Effect of Grain Size on the Ionic Conductivity of a Block Copolymer Electrolyte No authors listed Macromolecules https://doi.org/10.1021/ma501202c		July 2014
Simulation of local ion transport in lamellar block copolymer electrolytes based on electron micrographs No authors listed Journal of Polymer Science Part B: Polymer Physics https://doi.org/10.1002/polb.24268		December 2016
Interconnected ionic domains enhance conductivity in microphase separated block copolymer electrolytes No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C6TA10838E		January 2017
Anisotropic Ionic Conductivity in Block Copolymer Membranes by Magnetic Field Alignment No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja107309p		December 2010
Understanding anisotropic transport in self-assembled membranes and maximizing ionic conductivity by microstructure alignment No authors listed Soft Matter https://doi.org/10.1039/c3sm50320h		January 2013
Role of Defects in Ion Transport in Block Copolymer Electrolytes No authors listed Nano Letters https://doi.org/10.1021/acs.nanolett.9b01758		June 2019
High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation No authors listed Nano Letters https://doi.org/10.1021/nl4034818		December 2013
Orientation-Dependent Distortion of Lamellae in a Block Copolymer Electrolyte under DC Polarization No authors listed Macromolecules https://doi.org/10.1021/acs.macromol.1c01295		August 2021
Effect of thermal history on the ionic conductivity of block copolymer electrolytes No authors listed Journal of Polymer Science Part B: Polymer Physics https://doi.org/10.1002/polb.23290		April 2013
Thermodynamics of Block Copolymers with and without Salt No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp408079z		December 2013
Anionic polymerization: High vacuum techniques No authors listed Journal of Polymer Science Part A: Polymer Chemistry https://doi.org/10.1002/1099-0518(20000915)38:18<3211::AID-POLA10>3.0.CO;2-L		January 2000
Ionic Conductivity of Low Molecular Weight Block Copolymer Electrolytes No authors listed Macromolecules https://doi.org/10.1021/ma3024552		January 2013
A SAXS/WAXS/GISAXS Beamline with Multilayer Monochromator No authors listed Journal of Physics: Conference Series https://doi.org/10.1088/1742-6596/247/1/012007		October 2010
PyFAI, a versatile library for azimuthal regrouping No authors listed Journal of Physics: Conference Series https://doi.org/10.1088/1742-6596/425/20/202012		March 2013
Relationship between Segmental Dynamics Measured by Quasi-Elastic Neutron Scattering and Conductivity in Polymer Electrolytes No authors listed ACS Macro Letters https://doi.org/10.1021/acsmacrolett.8b00159		March 2018
Mechanism of ion transport in PEO/LiTFSI complexes: Effect of temperature, molecular weight and end groups No authors listed Solid State Ionics https://doi.org/10.1016/j.ssi.2012.09.020		October 2012
Temperature and concentration dependence of the ionic transport properties of poly(ethylene oxide) electrolytes No authors listed Solid State Ionics https://doi.org/10.1016/j.ssi.2021.115751		November 2021
The Reflection of X-rays by Crystals No authors listed Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences https://doi.org/10.1098/rspa.1913.0040		July 1913
Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors No authors listed Journal of Applied Crystallography https://doi.org/10.1107/S0021889809040126		October 2009

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