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Solvate Structures and Computational/Spectroscopic Characterization of LiClO4 Electrolytes

Journal Article · · Journal of Physical Chemistry. C

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
U.S. Department of Energy, Office of Science, Basic Energy Sciences-Division of Materials Sciences Engineering(United States Department of Energy (DOE)); Joint Center for Energy Storage Research (JCESR); Department of Energy (DoE) Energy Innovation Hub through IAA(United States Department of Energy (DOE)); U.S. Department of Army; DEVCOM Army Research Laboratory (ARL)
OSTI ID:
1988990
Journal Information:
Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C
Country of Publication:
United States
Language:
English

References (107)

Vibrational spectra of anhydrous lithium perchlorate in crystalline and molten states journal January 1969
Ion-pair formation and anion relaxation in aqueous solutions of Group I perchlorates. A Raman spectral study journal September 1982
Ion-ion-solvent interactions in solution. II. Solutions of LiClO4 in diethyl ether journal January 1982
Ion-ion-solvent interactions in solution. 8. Spectroscopic studies of the lithium perchlorate/N,N-dimethylformamide system journal February 1984
Raman spectral studies of solutions of alkali metal perchlorates in dimethyl sulfoxide and water journal July 1985
Ion Association in Polymer Electrolytes; A Raman Study of Poly (Propylene Oxide) Based Complexes journal January 1988
Raman spectral study of solutions of LiClO4 and Sr(ClO4)2 in some organic solvents journal November 1988
Raman and Brillouin scattering of LiClO4complexed in poly(propylene‐glycol) journal August 1988
Ion pairing effects in poly(propylene glycol)–salt complexes as a function of molecular weight and temperature: A Raman scattering study using NaCF 3 SO 3 and LiClO 4 journal May 1991
On the ion association at low salt concentrations in polymer electrolytes; a Raman study of NaCF3SO3 and LiClO4 dissolved in poly(propylene oxide) journal May 1991
A comparison of acetone and poly(propylene glycol) as solvents for lithium triflate and lithium perchlorate journal December 1991
Preparation and ionic conductivities of the solid solutions of LiClO4-organic derivatives of zirconium phosphate journal October 1992
Ionic association in poly(propylene oxide) complexed with alkali metal thiocyanate, perchlorate, and fluoroborate salts journal January 1992
Vibrational studies of lithium perchlorate in propylene carbonate solutions journal June 1993
Micro‐Raman study of polydioxolane/LiClO4 and NaClO4 electrolytes journal November 1995
Fourier transform Raman spectroscopic study of lithium perchlorate solutions in acrylonitrile journal August 1995
The Effect of Polymer Structures on the Ionic Association of LiClO4 in Polyether‐Based Network Polymer Electrolytes Studied by FT‐Raman Scattering Spectroscopy journal November 1995
Raman and NMR analysis of LiClO4 concentrated solutions in ethylene carbonate-propylene carbonate journal July 1996
Polyether, Poly(N,N-dimethylacrylamide), and LiClO4 Composite Polymeric Electrolytes journal January 1996
Vibrational spectroscopic studies of interactions between LiClO4 and the plasticizer dimethylformamide journal November 1996
A Vibrational Spectroscopic Study on the Interaction Between Lithium Salt and Ethylene Carbonate Plasticizer for PAN‐Based Electrolytes journal May 1996
Competition Between the Plasticizer and Polymer on Associating with Li +  Ions in Polyacrylonitrile‐Based Electrolytes journal March 1997
Raman Spectra and Transport Properties of Lithium Perchlorate in Ethylene Carbonate Based Binary Solvent Systems for Lithium Batteries journal June 1998
Ion Association and Salvation Studies of LiClO4/Ethylene Carbonate Electrolyte by Raman and Infrared Spectroscopy journal October 1998
An electrochemical and Raman spectroscopical study of gel polymer electrolytes for lithium batteries journal February 1998
The Effect of Ethylene Carbonate and Salt Concentration on the Conductivity of Propylene Carbonate∣Lithium Perchlorate Electrolytes journal January 2000
Raman spectroscopic study of lithium and sodium perchlorate association in propylene carbonate-water mixed solvents journal January 2000
Micro-Raman study of poly(ethylene glycol) electrolytes near phase segregation compositions journal March 2001
Solvation of LiClO4 and NaClO4 in deuterated acetonitrile studied by means of infrared and Raman spectroscopy journal June 2002
Modeling viscosity and conductivity of lithium salts in γ-butyrolactone journal June 2002
Temperature dependence of lithium ion solvation in ethylene carbonate–LiClO4 solutions journal March 2003
Conductivities and spectroscopic studies on hyperbranched polyurethane electrolytes journal November 2002
Conductivities and Spectroscopic Studies of Polymer Electrolytes Based on Linear Polyurethane and Hybrid and Copolymer of Linear and Hyperbranched Polyurethanes journal June 2003
Spectroscopic study of poly(ethylene oxide)6: LiX complexes (X = PF6, AsF6, SbF6, ClO4) journal December 2002
Vibrational and theoretical study of the complexation of LiPF6 and LiClO4 by di(ethylene glycol) dimethyl ether journal January 2004
Inorganic-Organic Polymer Electrolytes Based on PEG400 and Al[OCH(CH[sub 3])[sub 2]][sub 3] journal January 2004
The impact of end groups on ionic interactions in low molecular weight Al2O3?polyether?LiClO4 electrolytes journal June 2004
Morphology and ionic conductivity of solid polymer electrolytes based on polyurethanes with various topological structures journal February 2004
Ionic association in liquid (polyether–AlO–LiClO) composite electrolytes journal January 2005
FT-IR and Raman study of lithium salts solutions in diethylsulfoxide journal October 2005
Amorphous Structure of Poly(Propylene Glycol) Electrolytes journal March 2005
Laser Raman and FTIR studies on Li+ interaction in PVAc–LiClO4 polymer electrolytes journal December 2006
Sol–gel preparation of a di-ureasil electrolyte doped with lithium perchlorate journal December 2006
Vibrational spectroscopic characterization of stable solvates in the LiClO4/formamide:acetonitrile system journal March 2007
Vibrational Spectroscopic Study on Ion Solvation and Association of Lithium Perchlorate in 4-Methoxymethyl-ethylene Carbonate journal April 2007
Ionic conductivity in polyethylene-b-poly(ethylene oxide)/lithium perchlorate solid polymer electrolytes journal December 2007
Spectroscopic and structural studies of di-ureasils doped with lithium perchlorate journal December 2007
Ion Association and Solvation Behavior of Some Lithium Salts in Tetrahydrofuran. A Conductivity and Raman Spectroscopic Study journal April 2008
Electric and Mechanical Relaxations of LiClO4−Propylene Carbonate Systems in 100 MHz Region journal August 2009
Li + -Ion Transfer through the Interface between Li + -Ion Conductive Ceramic Electrolyte and Li + -Ion-Concentrated Propylene Carbonate Solution journal October 2009
Formation of Contact Ion Pairs and Solvation of Li+ Ion in Sulfones: Phase Diagrams, Conductivity, Raman Spectra, and Dynamics journal February 2010
Ion-polymer and ion-ion interaction in PEO-based polymer electrolytes having complexing salt LiClO4 and/or ionic liquid, [BMIM][PF6] journal June 2011
Vibrational dephasing of the perchlorate ion in an LiClO4 melt journal August 2011
The effect of additive of Lewis acid type on lithium–gel electrolyte characteristics journal December 2011
Laser Raman and conductivity studies of plasticized polymer electrolyte P(ECH-EO):propylenecarbonate:γ-butyrolactone:LiClO4 journal December 2011
Raman study of ion pairing in solutions of lithium salts in dimethyl sulfoxide, propylene carbonate and dimethyl carbonate journal November 2014
Ionic conductivity and dielectric permittivity of PEO-LiClO 4 solid polymer electrolyte plasticized with propylene carbonate journal February 2015
Solvation Structure around the Li + Ion in Mixed Cyclic/Linear Carbonate Solutions Unveiled by the Raman Noncoincidence Effect journal July 2015
Raman Spectroscopy for Understanding of Lithium Intercalation into Graphite in Propylene Carbonated-Based Solutions journal January 2015
Microscopic Structure of Contact Ion Pairs in Concentrated LiCl- and LiClO4-Tetrahydrofuran Solutions Studied by Low-Frequency Isotropic Raman Scattering and Neutron Diffraction with 6Li/7Li Isotopic Substitution Methods journal May 2016
Electrolyte Solvation and Ionic Association journal January 2012
Electrolyte Solvation and Ionic Association II. Acetonitrile-Lithium Salt Mixtures: Highly Dissociated Salts journal January 2012
Electrolyte Solvation and Ionic Association III. Acetonitrile-Lithium Salt Mixtures–Transport Properties journal January 2013
Combined quantum chemical/Raman spectroscopic analyses of Li+ cation solvation: Cyclic carbonate solvents—Ethylene carbonate and propylene carbonate journal December 2014
Probing Electric Double-Layer Composition via in Situ Vibrational Spectroscopy and Molecular Simulations journal May 2019
Towards high energy density sodium ion batteries through electrolyte optimization journal January 2013
Current trends and future challenges of electrolytes for sodium-ion batteries journal January 2016
Recent research progresses in ether‐ and ester‐based electrolytes for sodium‐ion batteries journal July 2019
Solvate Structures and Computational/Spectroscopic Characterization of LiBF 4 Electrolytes journal July 2014
Solvate Structures and Computational/Spectroscopic Characterization of LiPF 6 Electrolytes journal April 2015
Solvate Structures and Spectroscopic Characterization of LiTFSI Electrolytes journal September 2014
Solvate Structures and Computational/Spectroscopic Characterization of Lithium Difluoro(oxalato)borate (LiDFOB) Electrolytes journal March 2013
Crystals from Concentrated Glyme Mixtures. The Single-Crystal Structure of LiClO4 journal July 2003
LiClO 4 Electrolyte Solvate Structures journal January 2004
Triglyme−Li + Cation Solvate Structures:  Models for Amorphous Concentrated Liquid and Polymer Electrolytes (I) journal December 2003
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n
journal May 2009
Polarizable Force Field Development and Molecular Dynamics Simulations of Ionic Liquids journal August 2009
(μ-1,4,7,10-Tetraoxacyclododecane)bis[(1,4,7,10-tetraoxacyclododecane)lithium] bis(perchlorate) journal March 2010
Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters journal November 2014
Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters journal March 2015
Lewis-Base Adducts of Main Group 1 Metal Compounds. XV. Adducts of Lithium(I) Perchlorate With o-Methyl-Substituted Monodentate Pyridine Bases of Increasing Bulk journal January 1992
Crystal Structure of LiClO4 journal August 2003
Coordination chemistry of lithium ion: a crystal and molecular structure review journal March 1991
Li+ cation coordination by acetonitrile—insights from crystallography journal January 2012
Lithium Perchlorate:  Ab Initio Study of the Structural and Spectral Changes Associated with Ion Pairing journal January 1996
Ab initio SCF study on LiClO4 and LiSO4 molecules: Geometries and vibrational frequencies journal March 1991
Calculation of Vibrational Spectra of Coordinated Perchlorate Ion in Dipolar Aprotic Solvents journal September 2014
Glyme−Lithium Salt Phase Behavior journal July 2006
Local Structures in Crystalline and Amorphous Phases of Diglyme−LiCF3SO3 and Poly(ethylene oxide)−LiCF3SO3 Systems:  Implications for the Mechanism of Ionic Transport journal March 2001
On the configuration of open chain α-sulfonyl carbonions: X-ray crystal structure of [(phenylsulfonyl)isopropyllithium-diglyme]2 and [(α-phenylsulfonyl)-α-(methyl)benzyllithium-diglyme]2 journal January 1988
Sulfonyl-Stabilized Allylic Norbornenyl and Norbornyl Carbanions: Structure and Stereoselectivity of Reaction with Electrophiles journal July 1999
Experimental and Theoretical Investigation of the Enantiomerization of Lithium α-tert-Butylsulfonyl Carbanion Salts and the Determination of Their Structures in Solution and in the Crystal journal July 2010
Chiral Lithiated Allylic α-Sulfonyl Carbanions: Experimental and Computational Study of Their Structure, Configurational Stability, and Enantioselective Synthesis journal October 2015
Structural Diversity in Lewis-Base Complexes of Lithium Triflamide journal September 2003
Metal Tetrahydridoborates and Tetrahydridoborato Metalates. 23.1 Amine Solvates of Lithium and Sodium Tetrahydridoborate journal August 1999
Lithiated amidines: syntheses and structural characterisations journal January 1997
Solid-State Structures and Racemization of Lithiated Schllkopf's Bis[Lactim Ether] journal October 2002
Simplifying metal-‘ate’ chemistry: formation and comprehensive characterisation of a homo-metallic amido lithiate complex journal January 2016
Synthesis of [Li(CH2SiMe3)(pmdeta)] and the crystalline monomeric bulky alkyl-lithium complexes[LiR(tmeda)]and [LiR(pmdeta)][R = CH(SiMe3)2]; X-ray crystal structrue of [Li{CH(SiMe3)2}(pmdeta)]{tmeda = Me2NCH2CH2NMe2, pmdeta = Me2N[CH2]2N(Me)[CH2]2NMe2} journal January 1982
Thermodynamically Favored Anion Rearrangements in Li and Na Complexes of (S)-N-α-(Methylbenzyl)allylamine journal February 2009
Lithiation of a Cyclen‐Derived (NNNN) Macrocycle and Its Reaction with n ‐Butyllithium journal June 2010
Synthesis and Structure of Li[(C5H4)CH2CH2(TACN-iPr2)]. A Lithium Complex Supported by a Cp/TACN-iPr2 Ligand journal May 2000
X-ray Crystal Structures and Some Solution Structures of Lithium Amides with Intramolecular Complexation of Lithium by Tertiary Amide Groups journal February 1999
Tris(1-lithio-4,7-dimethyl-1,4,7-triazacyclononane) journal June 2002
Bis(μ-N-tert-butyl-2-{N-[2-(dimethylamino)ethyl]-N-methylamino}ethanaminato)dilithium(I) journal February 2007
Electrolyte Solvation and Ionic Association. VII. Correlating Raman Spectroscopic Data with Solvate Species journal July 2020
[Si(SiMe3)3]6Ge18M (M = Cu, Ag, Au): metalloid cluster compounds as unusual building blocks for a supramolecular chemistry journal January 2008

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