Imaging solid-electrolyte interphase dynamics using operando reflection interference microscopy

Feng, Guangxia; Jia, Hao; Shi, Yaping; Yang, Xu; Liang, Yanliang; Engelhard, Mark H.; Zhang, Ye; Yang, Chaojie; Xu, Kang; Yao, Yan; Xu, Wu; Shan, Xiaonan

doi:10.1038/s41565-023-01316-3

Imaging solid-electrolyte interphase dynamics using operando reflection interference microscopy

Journal Article · 01 February 2023 · Nature Nanotechnology

DOI:https://doi.org/10.1038/s41565-023-01316-3· OSTI ID:1988885

Feng, Guangxia; Jia, Hao; Shi, Yaping; Yang, Xu; Liang, Yanliang; Engelhard, Mark H.; Zhang, Ye; Yang, Chaojie; Xu, Kang; Yao, Yan; Xu, Wu; Shan, Xiaonan

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: University of Houston; University of Houston's Center for Carbon Management in Energy; US Department of Agriculture's Small Business Innovation Research programme; University Training and Research for Fossil Energy Applications (US Department of Energy); Vehicle Technologies Office of the US Department of Energy through the Advanced Battery Materials Research programme(United States Department of Energy (DOE)); US Department of Energy(United States Department of Energy (DOE)); US Department of Energy's Office of Energy Efficiency and Renewable Energy under the Vehicle Technologies Program(United States Department of Energy (DOE)); Joint Center for Energy Storage Research - US Department of Energy's Basic Energy Sciences programme(United States Department of Energy (DOE)); UL Research Institutes, Beyond Bits Technology

OSTI ID:: 1988885

Journal Information:: Nature Nanotechnology, Journal Name: Nature Nanotechnology

Country of Publication:: United States

Language:: English

References (54)

The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
The Lithium/Air Battery: Still an Emerging System or a Practical Reality? Grande, Lorenzo; Paillard, Elie; Hassoun, Jusef Advanced Materials, Vol. 27, Issue 5 https://doi.org/10.1002/adma.201403064	journal	December 2014
Stable Cycling of Lithium Metal Batteries Using High Transference Number Electrolytes Lu, Yingying; Tikekar, Mukul; Mohanty, Ritesh Advanced Energy Materials, Vol. 5, Issue 9 https://doi.org/10.1002/aenm.201402073	journal	February 2015
Nanostructured materials for advanced energy conversion and storage devices Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno Nature Materials, Vol. 4, Issue 5, p. 366-377 https://doi.org/10.1038/nmat1368	journal	May 2005
Promises and challenges of nanomaterials for lithium-based rechargeable batteries Sun, Yongming; Liu, Nian; Cui, Yi Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.71	journal	June 2016
Dendrite-free lithium metal anodes: stable solid electrolyte interphases for high-efficiency batteries Cheng, Xin-Bing; Zhang, Qiang Journal of Materials Chemistry A, Vol. 3, Issue 14 https://doi.org/10.1039/C5TA00689A	journal	January 2015
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Graphene-Supported Nitrogen and Boron Rich Carbon Layer for Improved Performance of Lithium-Sulfur Batteries Due to Enhanced Chemisorption of Lithium Polysulfides Yuan, Shouyi; Bao, Junwei Lucas; Wang, Lina Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501733	journal	December 2015
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
Interfacial Challenges in Solid-State Li Ion Batteries Luntz, Alan C.; Voss, Johannes; Reuter, Karsten The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b02352	journal	October 2015
Anodes for Rechargeable Lithium-Sulfur Batteries Cao, Ruiguo; Xu, Wu; Lv, Dongping Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201402273	journal	April 2015
Lithium–Air Batteries with Hybrid Electrolytes He, Ping; Zhang, Tao; Jiang, Jie The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00080	journal	March 2016
Decoupling the origins of irreversible coulombic efficiency in anode-free lithium metal batteries Huang, Chen-Jui; Thirumalraj, Balamurugan; Tao, Hsien-Chu Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21683-6	journal	March 2021
A high-energy-density and long-life initial-anode-free lithium battery enabled by a Li2O sacrificial agent Qiao, Yu; Yang, Huijun; Chang, Zhi Nature Energy, Vol. 6, Issue 6 https://doi.org/10.1038/s41560-021-00839-0	journal	June 2021
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b01727	journal	October 2015
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling An, Seong Jin; Li, Jianlin; Daniel, Claus Carbon, Vol. 105 https://doi.org/10.1016/j.carbon.2016.04.008	journal	August 2016
In situ Scanning Electron Microscopy (SEM) observation of interfaces within plastic lithium batteries Orsini, F.; Du Pasquier, A.; Beaudoin, B. Journal of Power Sources, Vol. 76, Issue 1 https://doi.org/10.1016/S0378-7753(98)00128-1	journal	November 1998
Observation and Quantification of Nanoscale Processes in Lithium Batteries by Operando Electrochemical (S)TEM Mehdi, B. L.; Qian, J.; Nasybulin, E. Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00175	journal	February 2015
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Identifying the components of the solid–electrolyte interphase in Li-ion batteries Wang, Luning; Menakath, Anjali; Han, Fudong Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0304-z	journal	August 2019
Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries Ai, Qing; Fang, Qiyi; Liang, Jia Nano Energy, Vol. 72 https://doi.org/10.1016/j.nanoen.2020.104657	journal	June 2020
Electrolyte Design for In Situ Construction of Highly Zn ²⁺ ‐Conductive Solid Electrolyte Interphase to Enable High‐Performance Aqueous Zn‐Ion Batteries under Practical Conditions Zeng, Xiaohui; Mao, Jianfeng; Hao, Junnan Advanced Materials, Vol. 33, Issue 11 https://doi.org/10.1002/adma.202007416	journal	February 2021
Unraveling the Nanoscale Heterogeneity of Solid Electrolyte Interphase Using Tip-Enhanced Raman Spectroscopy Nanda, Jagjit; Yang, Guang; Hou, Tingzheng Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.05.026	journal	August 2019
Origin of extra capacity in the solid electrolyte interphase near high-capacity iron carbide anodes for Li ion batteries Chen, Dongjiang; Feng, Chao; Han, Yupei Energy & Environmental Science, Vol. 13, Issue 9 https://doi.org/10.1039/C9EE04062E	journal	January 2020
Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation Qiu, Huayu; Du, Xiaofan; Zhao, Jingwen Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13436-3	journal	November 2019
Operando X-ray photoelectron spectroscopy of solid electrolyte interphase formation and evolution in Li2S-P2S5 solid-state electrolytes Wood, Kevin N.; Steirer, K. Xerxes; Hafner, Simon E. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04762-z	journal	June 2018
Unveiling the Stable Nature of the Solid Electrolyte Interphase between Lithium Metal and LiPON via Cryogenic Electron Microscopy Cheng, Diyi; Wynn, Thomas A.; Wang, Xuefeng Joule, Vol. 4, Issue 11 https://doi.org/10.1016/j.joule.2020.08.013	journal	November 2020
Solid Electrolyte Interphase on Native Oxide-Terminated Silicon Anodes for Li-Ion Batteries Cao, Chuntian; Abate, Iwnetim Iwnetu; Sivonxay, Eric Joule, Vol. 3, Issue 3 https://doi.org/10.1016/j.joule.2018.12.013	journal	March 2019
Real-time mass spectrometric characterization of the solid–electrolyte interphase of a lithium-ion battery Zhou, Yufan; Su, Mao; Yu, Xiaofei Nature Nanotechnology, Vol. 15, Issue 3 https://doi.org/10.1038/s41565-019-0618-4	journal	January 2020
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM Wang, Xuefeng; Zhang, Minghao; Alvarado, Judith Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b03606	journal	November 2017
Ultra-thin solid electrolyte interphase evolution and wrinkling processes in molybdenum disulfide-based lithium-ion batteries Wan, Jing; Hao, Yang; Shi, Yang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11197-7	journal	July 2019
In Situ and Quantitative Characterization of Solid Electrolyte Interphases Cresce, Arthur v.; Russell, Selena M.; Baker, David R. Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404471v	journal	February 2014
Fluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition Pathak, Rajesh; Chen, Ke; Gurung, Ashim Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13774-2	journal	January 2020
In situ quantification of interphasial chemistry in Li-ion battery Liu, Tongchao; Lin, Lingpiao; Bi, Xuanxuan Nature Nanotechnology, Vol. 14, Issue 1 https://doi.org/10.1038/s41565-018-0284-y	journal	November 2018
Role of Solution Structure in Solid Electrolyte Interphase Formation on Graphite with LiPF ₆ in Propylene Carbonate Nie, Mengyun; Abraham, Daniel P.; Seo, Daniel M. The Journal of Physical Chemistry C, Vol. 117, Issue 48 https://doi.org/10.1021/jp409765w	journal	November 2013
Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive Qian, Jiangfeng; Xu, Wu; Bhattacharya, Priyanka Nano Energy, Vol. 15 https://doi.org/10.1016/j.nanoen.2015.04.009	journal	July 2015
Li2O-Reinforced Solid Electrolyte Interphase on Three-Dimensional Sponges for Dendrite-Free Lithium Deposition Shen, Chao; Yan, Huibo; Gu, Jinlei Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00517	journal	November 2018
Ion chromatographic determination of hydrolysis products of hexafluorophosphate salts in aqueous solution Terborg, Lydia; Nowak, Sascha; Passerini, Stefano Analytica Chimica Acta, Vol. 714 https://doi.org/10.1016/j.aca.2011.11.056	journal	February 2012
Electrochemical Impedance Imaging on Conductive Surfaces Shi, Yaping; Feng, Guangxia; Li, Xiaoliang Analytical Chemistry, Vol. 93, Issue 36 https://doi.org/10.1021/acs.analchem.1c02040	journal	August 2021
Surface Impedance Imaging Technique Foley, Kyle J.; Shan, Xiaonan; Tao, N. J. Analytical Chemistry, Vol. 80, Issue 13 https://doi.org/10.1021/ac800361p	journal	May 2008
Identification of Surface Films Formed on Lithium in Propylene Carbonate Solutions Aurbach, D. Journal of The Electrochemical Society, Vol. 134, Issue 7 https://doi.org/10.1149/1.2100722	journal	January 1987
Theoretical Investigations on Oxidative Stability of Solvents and Oxidative Decomposition Mechanism of Ethylene Carbonate for Lithium Ion Battery Use Xing, Lidan; Li, Weishan; Wang, Chaoyang The Journal of Physical Chemistry B, Vol. 113, Issue 52 https://doi.org/10.1021/jp9074064	journal	December 2009
Oxidation of propylene carbonate containing LiBF4 or LiPF6 on LiCoO2 thin film electrode for lithium batteries Kanamura, Kiyoshi; Umegaki, Takao; Ohashi, Masahiro Electrochimica Acta, Vol. 47, Issue 3 https://doi.org/10.1016/S0013-4686(01)00736-8	journal	October 2001
The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries Aurbach, Doron Journal of The Electrochemical Society, Vol. 142, Issue 9 https://doi.org/10.1149/1.2048658	journal	January 1995
Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF ₆ Parimalam, Bharathy S.; MacIntosh, Alex D.; Kadam, Rahul The Journal of Physical Chemistry C, Vol. 121, Issue 41 https://doi.org/10.1021/acs.jpcc.7b08433	journal	October 2017
Resolving Nanoscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy Huang, William; Wang, Hansen; Boyle, David T. ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00194	journal	March 2020
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries Wang, Aiping; Kadam, Sanket; Li, Hong npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0064-0	journal	March 2018
Spatial Heterogeneities and Onset of Passivation Breakdown at Lithium Anode Interfaces Leung, Kevin; Jungjohann, Katherine L. The Journal of Physical Chemistry C, Vol. 121, Issue 37 https://doi.org/10.1021/acs.jpcc.7b06983	journal	September 2017
Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure Zhang, Yaohui; Qian, Jiangfeng; Xu, Wu Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl5039117	journal	November 2014

Similar Records

Imaging solid–electrolyte interphase dynamics using operando reflection interference microscopy

Journal Article · 2023 · Nature Nanotechnology · OSTI ID:1985460

Feng, Guangxia; Jia, Hao; Shi, Yaping; +9 more

In operando Raman microscopy of the Cu/Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ solid electrolyte interphase

Journal Article · 2025 · ChemComm · OSTI ID:2483780

Weich, Ineke; Dopilka, Andrew; Kasnatscheew, Johannes; +2 more

Dynamic Structure and Chemistry of the Silicon Solid-Electrolyte Interphase Visualized by Cryogenic Electron Microscopy

Journal Article · 2019 · Matter · OSTI ID:1708932

Huang, William; Wang, Jiangyan; Braun, Michael R.; +5 more

Imaging solid-electrolyte interphase dynamics using operando reflection interference microscopy

Citation Formats

References (54)

Similar Records

Related Subjects