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Analysis of Coronado State Historic Site artifacts using X‐rays

Journal Article · · X-Ray Spectrometry, XRS
DOI:https://doi.org/10.1002/xrs.3350· OSTI ID:1983372
 [1];  [2];  [3];  [1];  [1];  [4];  [5];  [6];  [1]
  1. Engineered Materials Group, Materials Science and Technology Division Los Alamos National Laboratory Los Alamos New Mexico USA
  2. Materials Science in Radiation and Dynamics Extremes Group, Materials Science and Technology Division Los Alamos National Laboratory Los Alamos New Mexico USA
  3. Non‐destructive Testing and Evaluation Group, Engineering Technology and Design Division Los Alamos National Laboratory Los Alamos New Mexico USA
  4. Center for Integrated Nanotechnologies, Materials Physics and Applications Division Los Alamos National Laboratory Los Alamos New Mexico USA
  5. Archaeological Analysis and Graphics Albuquerque New Mexico USA
  6. New Mexico State Historic Sites Santa Fe New Mexico USA
Abstract

Two historic‐period metal artifacts were provided by the New Mexico Historic Sites to Los Alamos National Laboratory for non‐destructive analysis. The artifacts were a crossbow quarrel (or bolthead) and a reliquary pendant recovered from Kuaua Pueblo (also known as the Coronado Historic Site) in Bernalillo, NM. The quarrel is a heavily patinated metal that had been flattened due to compressive forces. The pendant consisted of a metal casing that had previously surrounded two center gemstones on the front and rear face of the pendant. The gemstone in the rear setting had fractured and was displaced from the setting, leaving only a small, loose fragment within the pendant for study. The front gem appeared to be very dark, near‐black in color, and the fragment of the rear gem was a bright red color. The artifacts were analyzed to ascertain their composition and glean insight into their provenance using the following X‐ray techniques: X‐ray computed tomography, confocal micro X‐ray fluorescence, and X‐ray diffraction. Infrared spectroscopy and electron microscopy were used on selected areas. Ultraviolet Raman spectra were collected on the two gems and the pendant. The metal material of the artifacts was found to be primarily composed of copper. The gems in the pendant were composed of manganese (front gem) and calcium (side gem).

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE; USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1983372
Alternate ID(s):
OSTI ID: 2426782
OSTI ID: 1983373
Report Number(s):
LA-UR--23-21163
Journal Information:
X-Ray Spectrometry, XRS, Journal Name: X-Ray Spectrometry, XRS Journal Issue: 1 Vol. 53; ISSN 0049-8246
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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Analysis of Coronado State Historic Site artifacts using X-rays
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