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Structural characterisation of hydrolysed Cm(III)-EDTA solution species under alkaline conditions: a TRLFS, vibronic side-band and quantum chemical study

Journal Article · · Molecular Physics
 [1];  [1];  [1];  [2];  [1]
  1. Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, Karlsruhe, Germany
  2. Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, Karlsruhe, Germany; Department of Civil & Environmental Engineering & Earth Sciences, University of Notre Dame, Notre Dame, IN, USA

Not provided.

Research Organization:
Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0014664
OSTI ID:
1982405
Journal Information:
Molecular Physics, Vol. 120, Issue 8; ISSN 0026-8976
Publisher:
Taylor & Francis
Country of Publication:
United States
Language:
English

References (21)

Ion exchange behaviour and dissociation constants of americium, curium, and californium complexes with ethylenediaminetetra-acetic acid journal January 1958
Calorimetric studies of curium complexation journal November 1985
Chemical speciation of Am, Cm and Eu with EDTA at high ionic strength: thermodynamics and laser fluorescence spectroscopy studies journal December 2005
Complexation and the laser luminescence studies of Eu(III), Am(III), and Cm(III) with EDTA, CDTA, and PDTA and their ternary complexation with dicarboxylates journal October 2009
Understanding the Solution Behavior of Minor Actinides in the Presence of EDTA 4– , Carbonate, and Hydroxide Ligands journal June 2012
Improved thermodynamic model for interaction of EDTA with trivalent actinides and lanthanide to ionic strength of 6.60m journal May 2014
A spectrophotometric study of the complexing of Am3+ with aminopolyacetic acids journal July 1969
The kinetics of exchange between lanthanide ions and lanthanum ethylenediaminetetraacetate journal January 1971
Influence of a Pre‐organized N‐Donor Group on the Coordination of Trivalent Actinides and Lanthanides by an Aminopolycarboxylate Complexant journal January 2019
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide journal May 1994
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient journal January 1993
Actinoid(III) Hydration—First Principle Gibbs Energies of Hydration Using High Level Correlation Methods journal November 2014
Calculation of Solvation Free Energies of Charged Solutes Using Mixed Cluster/Continuum Models journal August 2008
Thermodynamics of Radioactive Trace Elements in Concentrated Electrolyte Solutions: Hydrolysis of Cm 3+ in NaCl-Solutions journal December 1994
Determination of the Hydration Number of Cm(III) in Various Aqueous Solutions journal January 1996
Environmental Mobility of Pu(IV) in the Presence of Ethylenediaminetetraacetic Acid: Myth or Reality? journal May 2008
Thermodynamic model for the solubility of ThO2(am) in the aqueous Na+-H+-OH--NO3 --H2O-EDTA system journal December 2003
Andra thermodynamic database for performance assessment: ThermoChimie journal October 2014
Solubility and hydrolysis of tetravalent actinides journal January 2001