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Synthesis and structural characterization of copper–cuprizone complexes

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/d2dt01475k· OSTI ID:1982242
 [1];  [2];  [3];  [4];  [4]
  1. Department of Surgery, College of Medicine, University of Saskatchewan, 107 Wiggins Road, Saskatoon, Saskatchewan S7N 5E5, Canada
  2. Department of Physiology, School of Medicine, Johns Hopkins University, 725 North Wolfe Street, Baltimore, Maryland 21205, USA
  3. Canadian Light Source, Saskatoon, Saskatchewan S7N 4L5, Canada
  4. Molecular and Environmental Sciences Research Group, Department of Geological Sciences, University of Saskatchewan, Saskatchewan, S7N 5E2, Canada; Department of Chemistry, University of Saskatchewan, Saskatchewan, S7N 5C9, Canada

The chemistry of copper with cuprizone has challenged chemists for over 70 years. We characterize the classical ‘blue’ product, containing Cu(iii) and hydrolyzed cuprizone, and a green multimeric Cu(ii) product, containing unhydrolyzed cuprizone.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-76SF00515
OSTI ID:
1982242
Journal Information:
Dalton Transactions, Vol. 51, Issue 27; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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