Continuous transition from double-layer to Faradaic charge storage in confined electrolytes

Fleischmann, Simon; Zhang, Yuan; Wang, Xuepeng; Cummings, Peter T.; Wu, Jianzhong; Simon, Patrice; Gogotsi, Yury; Presser, Volker; Augustyn, Veronica

doi:10.1038/s41560-022-00993-z

Continuous transition from double-layer to Faradaic charge storage in confined electrolytes

Journal Article · 01 March 2022 · Nature Energy

DOI:https://doi.org/10.1038/s41560-022-00993-z· OSTI ID:1982129

; Zhang, Yuan; Wang, Xuepeng; Cummings, Peter T.; ; ; ; ;

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1982129

Journal Information:: Nature Energy, Vol. 7, Issue 3; ISSN 2058-7546

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

References (54)

Carbon electrodes for capacitive technologies Ratajczak, Paula; Suss, Matthew E.; Kaasik, Friedrich Energy Storage Materials, Vol. 16 https://doi.org/10.1016/j.ensm.2018.04.031	journal	January 2019
Charge-transfer materials for electrochemical water desalination, ion separation and the recovery of elements Srimuk, Pattarachai; Su, Xiao; Yoon, Jeyong Nature Reviews Materials, Vol. 5, Issue 7 https://doi.org/10.1038/s41578-020-0193-1	journal	April 2020
Where Do Batteries End and Supercapacitors Begin? Simon, P.; Gogotsi, Y.; Dunn, B. Science, Vol. 343, Issue 6176 https://doi.org/10.1126/science.1249625	journal	March 2014
To Be or Not To Be Pseudocapacitive? Brousse, Thierry; Bélanger, Daniel; Long, Jeffrey W. Journal of The Electrochemical Society, Vol. 162, Issue 5 https://doi.org/10.1149/2.0201505jes	journal	January 2015
How Do Pseudocapacitors Store Energy? Theoretical Analysis and Experimental Illustration Costentin, Cyrille; Porter, Thomas R.; Savéant, Jean-Michel ACS Applied Materials & Interfaces, Vol. 9, Issue 10 https://doi.org/10.1021/acsami.6b14100	journal	March 2017
Energy Storage Data Reporting in Perspective—Guidelines for Interpreting the Performance of Electrochemical Energy Storage Systems Mathis, Tyler S.; Kurra, Narendra; Wang, Xuehang Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201902007	journal	August 2019
Pseudocapacitance: From Fundamental Understanding to High Power Energy Storage Materials Fleischmann, Simon; Mitchell, James B.; Wang, Ruocun Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.0c00170	journal	June 2020
How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes Waegele, Matthias M.; Gunathunge, Charuni M.; Li, Jingyi The Journal of Chemical Physics, Vol. 151, Issue 16 https://doi.org/10.1063/1.5124878	journal	October 2019
Demystifying the Stern layer at a metal–electrolyte interface: Local dielectric constant, specific ion adsorption, and partial charge transfer Wang, Xuepeng; Liu, Kun; Wu, Jianzhong The Journal of Chemical Physics, Vol. 154, Issue 12 https://doi.org/10.1063/5.0043963	journal	March 2021
Ion Sieving Effects in the Electrical Double Layer of Porous Carbon Electrodes: Estimating Effective Ion Size in Electrolytic Solutions Eliad, Linoam; Salitra, Gregory; Soffer, Abraham The Journal of Physical Chemistry B, Vol. 105, Issue 29 https://doi.org/10.1021/jp010086y	journal	July 2001
Qualitative Electrochemical Impedance Spectroscopy study of ion transport into sub-nanometer carbon pores in Electrochemical Double Layer Capacitor electrodes Segalini, J.; Daffos, B.; Taberna, P. L. Electrochimica Acta, Vol. 55, Issue 25 https://doi.org/10.1016/j.electacta.2010.01.003	journal	October 2010
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Chmiola, J. Science, Vol. 313, Issue 5794 https://doi.org/10.1126/science.1132195	journal	September 2006
Silica-grafted ionic liquids for revealing the respective charging behaviors of cations and anions in supercapacitors Dou, Qingyun; Liu, Lingyang; Yang, Bingjun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02152-5	journal	December 2017
Attractive forces in microporous carbon electrodes for capacitive deionization Biesheuvel, P. M.; Porada, S.; Levi, M. Journal of Solid State Electrochemistry, Vol. 18, Issue 5 https://doi.org/10.1007/s10008-014-2383-5	journal	February 2014
Solvent effect on the ion adsorption from ionic liquid electrolyte into sub-nanometer carbon pores Lin, R.; Huang, P.; Ségalini, J. Electrochimica Acta, Vol. 54, Issue 27 https://doi.org/10.1016/j.electacta.2009.07.015	journal	November 2009
Quantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ X-ray scattering Prehal, C.; Koczwara, C.; Jäckel, N. Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2016.215	journal	January 2017
Computational Insights into Materials and Interfaces for Capacitive Energy Storage Zhan, Cheng; Lian, Cheng; Zhang, Yu Advanced Science, Vol. 4, Issue 7 https://doi.org/10.1002/advs.201700059	journal	April 2017
Building one-dimensional oxide nanostructure arrays on conductive metal substrates for lithium-ion battery anodes Jiang, Jian; Li, Yuanyuan; Liu, Jinping Nanoscale, Vol. 3, Issue 1 https://doi.org/10.1039/C0NR00472C	journal	January 2011
Microscopic Insights into the Electrochemical Behavior of Nonaqueous Electrolytes in Electric Double-Layer Capacitors Jiang, De-en; Wu, Jianzhong The Journal of Physical Chemistry Letters, Vol. 4, Issue 8 https://doi.org/10.1021/jz4002967	journal	March 2013
Effect of pore size and its dispersity on the energy storage in nanoporous supercapacitors Kondrat, S.; Pérez, C. R.; Presser, V. Energy & Environmental Science, Vol. 5, Issue 4 https://doi.org/10.1039/c2ee03092f	journal	January 2012
Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor Largeot, Celine; Portet, Cristelle; Chmiola, John Journal of the American Chemical Society, Vol. 130, Issue 9 https://doi.org/10.1021/ja7106178	journal	March 2008
A superionic state in nano-porous double-layer capacitors: insights from Monte Carlo simulations Kondrat, S.; Georgi, N.; Fedorov, M. V. Physical Chemistry Chemical Physics, Vol. 13, Issue 23 https://doi.org/10.1039/c1cp20798a	journal	January 2011
Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores Futamura, Ryusuke; Iiyama, Taku; Takasaki, Yuma Nature Materials, Vol. 16, Issue 12 https://doi.org/10.1038/nmat4974	journal	September 2017
Outstanding room-temperature capacitance of biomass-derived microporous carbons in ionic liquid electrolyte Redondo, Edurne; Tsai, Wan-Yu; Daffos, Barbara Electrochemistry Communications, Vol. 79 https://doi.org/10.1016/j.elecom.2017.04.004	journal	June 2017
Graphitization as a Universal Tool to Tailor the Potential-Dependent Capacitance of Carbon Supercapacitors Weingarth, Daniel; Zeiger, Marco; Jäckel, Nicolas Advanced Energy Materials, Vol. 4, Issue 13 https://doi.org/10.1002/aenm.201400316	journal	May 2014
Differential capacitance of ionic liquid interface with graphite: the story of two double layers Kornyshev, A. A.; Luque, N. B.; Schmickler, W. Journal of Solid State Electrochemistry, Vol. 18, Issue 5 https://doi.org/10.1007/s10008-013-2316-8	journal	November 2013
Supercapacitor Behavior with KCl Electrolyte Lee, Hee Y.; Goodenough, J. B. Journal of Solid State Chemistry, Vol. 144, Issue 1 https://doi.org/10.1006/jssc.1998.8128	journal	April 1999
In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors Nam, Kyung-Wan; Kim, Min Gyu; Kim, Kwang-Bum The Journal of Physical Chemistry C, Vol. 111, Issue 2 https://doi.org/10.1021/jp063130o	journal	January 2007
Probing the Charge Storage Mechanism of a Pseudocapacitive MnO ₂ Electrode Using in Operando Raman Spectroscopy Chen, Dongchang; Ding, Dong; Li, Xiaxi Chemistry of Materials, Vol. 27, Issue 19 https://doi.org/10.1021/acs.chemmater.5b03118	journal	September 2015
Effects of interlayer confinement and hydration on capacitive charge storage in birnessite Boyd, Shelby; Ganeshan, Karthik; Tsai, Wan-Yu Nature Materials, Vol. 20, Issue 12 https://doi.org/10.1038/s41563-021-01066-4	journal	August 2021
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
Ex Situ and Operando XRD and XAS Analysis of MoS ₂ : A Lithiation Study of Bulk and Nanosheet Materials Quilty, Calvin D.; Housel, Lisa M.; Bock, David C. ACS Applied Energy Materials, Vol. 2, Issue 10 https://doi.org/10.1021/acsaem.9b01538	journal	September 2019
Solvent Co-intercalation into Few-layered Ti₃C₂T_x MXenes in Lithium Ion Batteries Induced by Acidic or Basic Post-treatment Bärmann, Peer; Nölle, Roman; Siozios, Vassilios ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c10153	journal	February 2021
Influences from solvents on charge storage in titanium carbide MXenes Wang, Xuehang; Mathis, Tyler S.; Li, Ke Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0339-9	journal	March 2019
Capacitive versus Pseudocapacitive Storage in MXene Ando, Yasunobu; Okubo, Masashi; Yamada, Atsuo Advanced Functional Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adfm.202000820	journal	May 2020
Layer Number Dependence of Li ⁺ Intercalation on Few-Layer Graphene and Electrochemical Imaging of Its Solid–Electrolyte Interphase Evolution Hui, Jingshu; Burgess, Mark; Zhang, Jiarui ACS Nano, Vol. 10, Issue 4 https://doi.org/10.1021/acsnano.5b07692	journal	March 2016
Confined Interlayer Water Promotes Structural Stability for High-Rate Electrochemical Proton Intercalation in Tungsten Oxide Hydrates Mitchell, James B.; Geise, Natalie R.; Paterson, Alisa R. ACS Energy Letters, Vol. 4, Issue 12 https://doi.org/10.1021/acsenergylett.9b02040	journal	October 2019
Unveiling Pseudocapacitive Charge Storage Behavior in FeWO ₄ Electrode Material by Operando X‐Ray Absorption Spectroscopy Goubard‐Bretesché, Nicolas; Crosnier, Olivier; Douard, Camille Small, Vol. 16, Issue 33 https://doi.org/10.1002/smll.202002855	journal	July 2020
Direct observation of ion dynamics in supercapacitor electrodes using in situ diffusion NMR spectroscopy Forse, Alexander C.; Griffin, John M.; Merlet, Céline Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2016.216	journal	February 2017
Maximization of Spatial Charge Density: An Approach to Ultrahigh Energy Density of Capacitive Charge Storage Ma, Hongyun; Chen, Hongwu; Wu, Mingmao Angewandte Chemie, Vol. 132, Issue 34 https://doi.org/10.1002/ange.202005270	journal	July 2020
Hydration shell energy barrier differences of sub-nanometer carbon pores enable ion sieving and selective ion removal Zhang, Yuan; Peng, Jiaxing; Feng, Guang Chemical Engineering Journal, Vol. 419 https://doi.org/10.1016/j.cej.2021.129438	journal	September 2021
Time-dependent ion selectivity in capacitive charging of porous electrodes Zhao, R.; van Soestbergen, M.; Rijnaarts, H. H. M. Journal of Colloid and Interface Science, Vol. 384, Issue 1 https://doi.org/10.1016/j.jcis.2012.06.022	journal	October 2012
MXene artificial muscles based on ionically cross-linked Ti ₃ C ₂ T _x electrode for kinetic soft robotics Umrao, Sima; Tabassian, Rassoul; Kim, Jaehwan Science Robotics, Vol. 4, Issue 33 https://doi.org/10.1126/scirobotics.aaw7797	journal	August 2019
Probing local electrochemistry via mechanical cyclic voltammetry curves Tsai, Wan-Yu; Wang, Ruocun; Boyd, Shelby Nano Energy, Vol. 81 https://doi.org/10.1016/j.nanoen.2020.105592	journal	March 2021
Quantitative Information about Electrosorption of Ionic Liquids in Carbon Nanopores from Electrochemical Dilatometry and Quartz Crystal Microbalance Measurements Jäckel, Nicolas; Patrick Emge, Steffen; Krüner, Benjamin The Journal of Physical Chemistry C, Vol. 121, Issue 35 https://doi.org/10.1021/acs.jpcc.7b06915	journal	August 2017
Pressure Enhancement in Confined Fluids: Effect of Molecular Shape and Fluid–Wall Interactions Srivastava, Deepti; Santiso, Erik E.; Gubbins, Keith E. Langmuir, Vol. 33, Issue 42 https://doi.org/10.1021/acs.langmuir.7b02260	journal	September 2017
Confinement effects on chemical reactions—Toward an integrated rational catalyst design Santiso, Erik E.; Kostov, Milen K.; George, Aaron M. Applied Surface Science, Vol. 253, Issue 13 https://doi.org/10.1016/j.apsusc.2006.12.121	journal	April 2007
Restricted diffusion in liquids within fine pores Satterfield, Charles N.; Colton, Clark K.; Pitcher, Wayne H. AIChE Journal, Vol. 19, Issue 3 https://doi.org/10.1002/aic.690190332	journal	May 1973
The crossover from single file to Fickian diffusion Sané, Jimaan; Padding, Johan T.; Louis, Ard A. Faraday Discuss., Vol. 144 https://doi.org/10.1039/B905378F	journal	January 2010
Highly confined ions store charge more efficiently in supercapacitors Merlet, C.; Péan, C.; Rotenberg, B. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3701	journal	October 2013
Li- and Na-ion Storage Performance of Natural Graphite via Simple Flotation Process Laziz, Noureddine Ait; Abou-Rjeily, John; Darwiche, Ali Journal of Electrochemical Science and Technology, Vol. 9, Issue 4 https://doi.org/10.33961/JECST.2018.9.4.320	journal	December 2018
Intercalation of Metal Ions into Ti ₃ C ₂ T _x MXene Electrodes for High‐Areal‐Capacitance Microsupercapacitors with Neutral Multivalent Electrolytes Li, Shuo; Shi, Qi; Li, Yang Advanced Functional Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adfm.202003721	journal	August 2020
A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte Li, Youbing; Shao, Hui; Lin, Zifeng Nature Materials, Vol. 19, Issue 8 https://doi.org/10.1038/s41563-020-0657-0	journal	April 2020
Layered LiNi _1/3 Mn _1/3 Co _1/3 O ₂ (NMC) with Optimized Morphology for Li-Ion Batteries Zukalova, Marketa; Prochazka, Jan; Pitna Laskova, Barbora ECS Transactions, Vol. 87, Issue 1 https://doi.org/10.1149/08701.0067ecst	journal	November 2018

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