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Title: Kinetically Controlled Structural Transitions in Layered Halide-Based Perovskites: An Approach to Modulate Spin Splitting

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c05574· OSTI ID:1982066
 [1]; ORCiD logo [2];  [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]
  1. Thomas Lord Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, United States; University Program in Materials Science and Engineering, Duke University, Durham, North Carolina 27708, United States
  2. Department of Chemistry, Duke University, Durham, North Carolina 27708, United States
  3. Thomas Lord Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, United States
  4. Thomas Lord Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, United States; Department of Chemistry, Duke University, Durham, North Carolina 27708, United States

Not provided.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Hybrid Organic-Inorganic Semiconductors for Energy (CHOISE)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231; AC36-08GO28308
OSTI ID:
1982066
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 33; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (57)

Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design journal March 2016
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises journal November 2018
Tuning the Luminescence of Layered Halide Perovskites journal January 2019
Organic-inorganic electronics journal January 2001
Chiral-perovskite optoelectronics journal March 2020
Chiral Lead Halide Perovskite Nanowires for Second-Order Nonlinear Optics journal August 2018
Chiral 2D Perovskites with a High Degree of Circularly Polarized Photoluminescence journal March 2019
Circularly polarized light detection using chiral hybrid perovskite journal April 2019
Chiral-induced spin selectivity enables a room-temperature spin light-emitting diode journal March 2021
Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport journal June 2020
The First 2D Homochiral Lead Iodide Perovskite Ferroelectrics: [ R ‐ and S ‐1‐(4‐Chlorophenyl)ethylammonium] 2 PbI 4 journal February 2019
Fluorine Substitution Induced High T c of Enantiomeric Perovskite Ferroelectrics: ( R ) - and ( S ) - 3-(Fluoropyrrolidinium)MnCl 3 journal February 2019
Spin control in reduced-dimensional chiral perovskites journal August 2018
Rashba and Dresselhaus Effects in Hybrid Organic–Inorganic Perovskites: From Basics to Devices journal September 2015
Spin Selectivity in Photoinduced Charge-Transfer Mediated by Chiral Molecules journal April 2019
Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites journal January 2019
Spin-Orbit Interaction and the Effective Masses of Holes in Germanium journal July 1954
Spin Hall effects journal October 2015
Anomalous Hall effect journal May 2010
New perspectives for Rashba spin–orbit coupling journal August 2015
Electronic analog of the electro‐optic modulator journal February 1990
Giant Ambipolar Rashba Effect in the Semiconductor BiTeI journal August 2012
Transmission of chirality through space and across length scales journal May 2017
Synthesis and crystal structures of inorganic–organic hybrids incorporating an aromatic amine with a chiral functional group journal January 2006
Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling journal September 2020
Through-space transfer of chiral information mediated by a plasmonic nanomaterial journal June 2015
Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites journal August 2021
Layer-Dependent Rashba Band Splitting in 2D Hybrid Perovskites journal October 2018
Control of Crystal Symmetry Breaking with Halogen-Substituted Benzylammonium in Layered Hybrid Metal-Halide Perovskites journal February 2020
Tunable ferroelectric polarization and its interplay with spin–orbit coupling in tin iodide perovskites journal December 2014
Switchable Rashba anisotropy in layered hybrid organic–inorganic perovskite by hybrid improper ferroelectricity journal December 2020
Stimuli-responsive switchable halide perovskites: Taking advantage of instability journal August 2021
The Ehrenfest Classification of Phase Transitions: Introduction and Evolution journal May 1998
Structure validation in chemical crystallography journal January 2009
Semiconducting Perovskites (2-XC 6 H 4 C 2 H 4 NH 3 ) 2 SnI 4 (X = F, Cl, Br):  Steric Interaction between the Organic and Inorganic Layers journal March 2003
Design of above-room-temperature ferroelectric two-dimensional layered halide perovskites journal January 2022
Symmetry breaking in molecular ferroelectrics journal January 2016
Structural origins of broadband emission from layered Pb–Br hybrid perovskites journal January 2017
Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating journal June 2005
Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity journal July 2017
Reversible Crystal–Glass Transition in a Metal Halide Perovskite journal December 2020
Impact of Vibrational Entropy on the Stability of Unsolvated Peptide Helices with Increasing Length journal April 2013
Kinetics of solid state phase transformations: Measurement and modelling of some basic issues journal January 2010
Solid state phase transformation kinetics in Zr-base alloys journal March 2021
Influence of calcium carbonate and carbon nanotubes on the crystallization kinetics of polypropylene at high supercooling conference January 2016
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
Ab initio molecular simulations with numeric atom-centered orbitals journal November 2009
Tunable Semiconductors: Control over Carrier States and Excitations in Layered Hybrid Organic-Inorganic Perovskites journal October 2018
Resolving Rotational Stacking Disorder and Electronic Level Alignment in a 2D Oligothiophene-Based Lead Iodide Perovskite journal September 2019
Direct-Bandgap 2D Silver–Bismuth Iodide Double Perovskite: The Structure-Directing Influence of an Oligothiophene Spacer Cation journal April 2019
Generalized Gradient Approximation Made Simple journal October 1996
Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data journal February 2009
Hybrid functionals based on a screened Coulomb potential journal May 2003
Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)] journal June 2006
One-hundred-three compound band-structure benchmark of post-self-consistent spin-orbit coupling treatments in density functional theory journal August 2017
Rashba splitting in organic–inorganic lead–halide perovskites revealed through two-photon absorption spectroscopy journal January 2022
Molecular engineering of organic–inorganic hybrid perovskites quantum wells journal November 2019