Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction

Qin, Jiayi; Liu, Hui; Zou, Peichao; Zhang, Rui; Wang, Chunyang; Xin, Huolin L.

doi:10.1021/jacs.1c11331

Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction

Journal Article · 28 January 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.1c11331· OSTI ID:1982052

Qin, Jiayi ^[1]; ^[1]; ^[1]; Zhang, Rui ^[1]; ^[1]; ^[1]

Department of Physics and Astronomy, University of California, Irvine, California 92697, United States

Not provided.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012704;

OSTI ID:: 1982052

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (66)

A Versatile Approach to Boost Oxygen Reduction of Fe‐N ₄ Sites by Controllably Incorporating Sulfur Functionality Shao, Chunfeng; Wu, Lingmin; Zhang, Haocheng Advanced Functional Materials, Vol. 31, Issue 25 https://doi.org/10.1002/adfm.202100833	journal	April 2021
Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin Advanced Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adma.201706758	journal	January 2018
Zinc‐Mediated Template Synthesis of Fe‐N‐C Electrocatalysts with Densely Accessible Fe‐N _x Active Sites for Efficient Oxygen Reduction Chen, Guangbo; Liu, Pan; Liao, Zhongquan Advanced Materials, Vol. 32, Issue 8 https://doi.org/10.1002/adma.201907399	journal	January 2020
Charge Redistribution Caused by S,P Synergistically Active Ru Endows an Ultrahigh Hydrogen Evolution Activity of S‐Doped RuP Embedded in N,P,S‐Doped Carbon Liu, Xiaoyu; Liu, Fan; Yu, Jiayuan Advanced Science, Vol. 7, Issue 17 https://doi.org/10.1002/advs.202001526	journal	July 2020
Effect of Chemical Doping on Cathodic Performance of Bicontinuous Nanoporous Graphene for Li-O ₂ Batteries Han, Jiuhui; Guo, Xianwei; Ito, Yoshikazu Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501870	journal	November 2015
Hierarchical NiCo ₂ S ₄ @NiO Core–Shell Heterostructures as Catalytic Cathode for Long‐Life Li‐O ₂ Batteries Wang, Peng; Li, Caixia; Dong, Shihua Advanced Energy Materials, Vol. 9, Issue 24 https://doi.org/10.1002/aenm.201900788	journal	May 2019
Earth-Abundant Nanomaterials for Oxygen Reduction Xia, Wei; Mahmood, Asif; Liang, Zibin Angewandte Chemie International Edition, Vol. 55, Issue 8 https://doi.org/10.1002/anie.201504830	journal	December 2015
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Synergistic Effects between Atomically Dispersed Fe−N−C and C−S−C for the Oxygen Reduction Reaction in Acidic Media Shen, Hangjia; Gracia-Espino, Eduardo; Ma, Jingyuan Angewandte Chemie International Edition, Vol. 56, Issue 44 https://doi.org/10.1002/anie.201706602	journal	September 2017
A Single‐Atom Iridium Heterogeneous Catalyst in Oxygen Reduction Reaction Xiao, Meiling; Zhu, Jianbing; Li, Gaoran Angewandte Chemie International Edition, Vol. 58, Issue 28 https://doi.org/10.1002/anie.201905241	journal	July 2019
Single‐Atom Cr−N ₄ Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media Luo, Ergui; Zhang, Hao; Wang, Xian Angewandte Chemie International Edition, Vol. 58, Issue 36 https://doi.org/10.1002/anie.201906289	journal	September 2019
Metal–Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction Lu, Xue Feng; Xia, Bao Yu; Zang, Shuang‐Quan Angewandte Chemie International Edition, Vol. 59, Issue 12 https://doi.org/10.1002/anie.201910309	journal	December 2019
Operando Cooperated Catalytic Mechanism of Atomically Dispersed Cu−N ₄ and Zn−N ₄ for Promoting Oxygen Reduction Reaction Tong, Miaomiao; Sun, Fanfei; Xie, Ying Angewandte Chemie International Edition, Vol. 60, Issue 25 https://doi.org/10.1002/anie.202102053	journal	May 2021
Rational Generation of Fe−N _x Active Sites in Fe−N−C Electrocatalysts Facilitated by Fe−N Coordinated Precursors for the Oxygen Reduction Reaction Kim, Minhyoung; Yoo, Ji Mun; Ahn, Chi‐Yeong ChemCatChem, Vol. 11, Issue 24 https://doi.org/10.1002/cctc.201901242	journal	October 2019
Engineering local coordination environments and site densities for high‐performance Fe‐N‐C oxygen reduction reaction electrocatalysis Wang, Qing; Shang, Lu; Sun‐Waterhouse, Dongxiao SmartMat, Vol. 2, Issue 2 https://doi.org/10.1002/smm2.1033	journal	June 2021
Facile grafting strategy synthesis of single-atom electrocatalyst with enhanced ORR performance Ding, Rui; Liu, Yide; Rui, Zhiyan Nano Research, Vol. 13, Issue 6 https://doi.org/10.1007/s12274-020-2768-y	journal	April 2020
Atomic Co/Ni dual sites with N/P-coordination as bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries Hu, Botao; Huang, Aijian; Zhang, Xuejiang Nano Research, Vol. 14, Issue 10 https://doi.org/10.1007/s12274-021-3535-4	journal	May 2021
A Review of Al Alloy Anodes for Al–Air Batteries in Neutral and Alkaline Aqueous Electrolytes Wu, Pengfei; Wu, Shengan; Sun, Dan Acta Metallurgica Sinica (English Letters), Vol. 34, Issue 3 https://doi.org/10.1007/s40195-020-01140-x	journal	November 2020
Ultrathin Co3O4 nanosheet clusters anchored on nitrogen doped carbon nanotubes/3D graphene as binder-free cathodes for Al-air battery Liu, Yisi; Yang, Lishan; Xie, Bo Chemical Engineering Journal, Vol. 381 https://doi.org/10.1016/j.cej.2019.122681	journal	February 2020
Molten-salt-assisted thermal emitting method to transform bulk Fe2O3 into Fe single atom catalysts for oxygen reduction reaction in Zn-air battery Cao, Yuanjie; Peng, Haoyang; Chu, Shengqi Chemical Engineering Journal, Vol. 420 https://doi.org/10.1016/j.cej.2021.129713	journal	September 2021
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window Liu, Chuhao; Wu, Yue; Sun, Kaian Chem, Vol. 7, Issue 5 https://doi.org/10.1016/j.chempr.2021.02.001	journal	May 2021
Space-confined synthesis of CoNi nanoalloy in N-doped porous carbon frameworks as efficient oxygen reduction catalyst for neutral and alkaline aluminum-air batteries Jiang, Min; Yang, Jian; Ju, Jiang Energy Storage Materials, Vol. 27 https://doi.org/10.1016/j.ensm.2020.01.016	journal	May 2020
Kinetic study of Nafion degradation by Fenton reaction Sugawara, Tomoko; Kawashima, Norimichi; Murakami, Takurou N. Journal of Power Sources, Vol. 196, Issue 5 https://doi.org/10.1016/j.jpowsour.2010.10.043	journal	March 2011
All-solid-state Al–air batteries with polymer alkaline gel electrolyte Zhang, Zhao; Zuo, Chuncheng; Liu, Zihui Journal of Power Sources, Vol. 251 https://doi.org/10.1016/j.jpowsour.2013.11.020	journal	April 2014
Structural Regulation with Atomic-Level Precision: From Single-Atomic Site to Diatomic and Atomic Interface Catalysis Pan, Yuan; Zhang, Chao; Liu, Zhi Matter, Vol. 2, Issue 1 https://doi.org/10.1016/j.matt.2019.11.014	journal	January 2020
Rational design of common transition metal-nitrogen-carbon catalysts for oxygen reduction reaction in fuel cells Zheng, Yongping; Yang, Dae-Soo; Kweun, Joshua M. Nano Energy, Vol. 30 https://doi.org/10.1016/j.nanoen.2016.10.037	journal	December 2016
Synergistically enhanced single-atomic site Fe by Fe3C@C for boosted oxygen reduction in neutral electrolyte Wei, Xiaoqian; Song, Shaojia; Wu, Nannan Nano Energy, Vol. 84 https://doi.org/10.1016/j.nanoen.2021.105840	journal	June 2021
Experimental Methods for Quantifying the Activity of Platinum Electrocatalysts for the Oxygen Reduction Reaction Garsany, Yannick; Baturina, Olga A.; Swider-Lyons, Karen E. Analytical Chemistry, Vol. 82, Issue 15 https://doi.org/10.1021/ac100306c	journal	August 2010
Well-Defined Materials for Heterogeneous Catalysis: From Nanoparticles to Isolated Single-Atom Sites Li, Zhi; Ji, Shufang; Liu, Yiwei Chemical Reviews, Vol. 120, Issue 2 https://doi.org/10.1021/acs.chemrev.9b00311	journal	December 2019
S, N Dual-Doped Graphene-like Carbon Nanosheets as Efficient Oxygen Reduction Reaction Electrocatalysts Li, Jiajie; Zhang, Yumin; Zhang, Xinghong ACS Applied Materials & Interfaces, Vol. 9, Issue 1 https://doi.org/10.1021/acsami.6b12547	journal	December 2016
Activating Edge-Mo of 2H-MoS₂ via Coordination with Pyridinic N–C for pH-Universal Hydrogen Evolution Electrocatalysis Qin, Jiayi; Xi, Cong; Zhang, Rui ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.0c04415	journal	March 2021
Microporous Framework Induced Synthesis of Single-Atom Dispersed Fe-N-C Acidic ORR Catalyst and Its in Situ Reduced Fe-N ₄ Active Site Identification Revealed by X-ray Absorption Spectroscopy Xiao, Meiling; Zhu, Jianbing; Ma, Liang ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.8b00138	journal	February 2018
Promoting Atomically Dispersed MnN ₄ Sites via Sulfur Doping for Oxygen Reduction: Unveiling Intrinsic Activity and Degradation in Fuel Cells Guo, Lin; Hwang, Sooyeon; Li, Boyang ACS Nano, Vol. 15, Issue 4 https://doi.org/10.1021/acsnano.0c10637	journal	March 2021
Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium Zhang, Chenhao; Sha, Junwei; Fei, Huilong ACS Nano, Vol. 11, Issue 7 https://doi.org/10.1021/acsnano.7b02148	journal	June 2017
XAS and DFT Investigation of Mononuclear Cobalt(III) Peroxo Complexes: Electronic Control of the Geometric Structure in CoO ₂ versus NiO ₂ Systems Sarangi, Ritimukta; Cho, Jaeheung; Nam, Wonwoo Inorganic Chemistry, Vol. 50, Issue 2 https://doi.org/10.1021/ic101730r	journal	January 2011
In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal–Organic Frameworks to Design Atomic Co₁–P₁N₃ Interfacial Structure for Promoting Catalytic Performance Wan, Jiawei; Zhao, Zhenghang; Shang, Huishan Journal of the American Chemical Society, Vol. 142, Issue 18 https://doi.org/10.1021/jacs.0c02229	journal	April 2020
Discriminating Catalytically Active FeN _x Species of Atomically Dispersed Fe–N–C Catalyst for Selective Oxidation of the C–H Bond Liu, Wengang; Zhang, Leilei; Liu, Xin Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b05130	journal	July 2017
Coordination of Atomic Co–Pt Coupling Species at Carbon Defects as Active Sites for Oxygen Reduction Reaction Zhang, Longzhou; Fischer, Julia Melisande Theresa Agatha; Jia, Yi Journal of the American Chemical Society, Vol. 140, Issue 34 https://doi.org/10.1021/jacs.8b04647	journal	July 2018
Versatile Strategy for Tuning ORR Activity of a Single Fe-N ₄ Site by Controlling Electron-Withdrawing/Donating Properties of a Carbon Plane Mun, Yeongdong; Lee, Seonggyu; Kim, Kyeounghak Journal of the American Chemical Society, Vol. 141, Issue 15 https://doi.org/10.1021/jacs.8b13543	journal	March 2019
Engineering Energy Level of Metal Center: Ru Single-Atom Site for Efficient and Durable Oxygen Reduction Catalysis Xiao, Meiling; Gao, Liqin; Wang, Ying Journal of the American Chemical Society, Vol. 141, Issue 50 https://doi.org/10.1021/jacs.9b09234	journal	November 2019
Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions Zhang, Jinqiang; Zhao, Yufei; Chen, Chen Journal of the American Chemical Society, Vol. 141, Issue 51 https://doi.org/10.1021/jacs.9b09352	journal	December 2019
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Zigzag carbon as efficient and stable oxygen reduction electrocatalyst for proton exchange membrane fuel cells Xue, Longfei; Li, Yongcheng; Liu, Xiaofang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06279-x	journal	September 2018
Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell Chen, Yuanjun; Ji, Shufang; Zhao, Shu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07850-2	journal	December 2018
Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction Cao, Linlin; Luo, Qiquan; Chen, Jiajia Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12886-z	journal	October 2019
Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity Shang, Huishan; Zhou, Xiangyi; Dong, Juncai Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16848-8	journal	June 2020
Iridium single-atom catalyst on nitrogen-doped carbon for formic acid oxidation synthesized using a general host–guest strategy Li, Zhi; Chen, Yuanjun; Ji, Shufang Nature Chemistry, Vol. 12, Issue 8 https://doi.org/10.1038/s41557-020-0473-9	journal	June 2020
Zirconium nitride catalysts surpass platinum for oxygen reduction Yuan, Yao; Wang, Jiacheng; Adimi, Samira Nature Materials, Vol. 19, Issue 3 https://doi.org/10.1038/s41563-019-0535-9	journal	November 2019
Challenges in applying highly active Pt-based nanostructured catalysts for oxygen reduction reactions to fuel cell vehicles Kodama, Kensaku; Nagai, Tomoyuki; Kuwaki, Akira Nature Nanotechnology, Vol. 16, Issue 2 https://doi.org/10.1038/s41565-020-00824-w	journal	January 2021
Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation Xiong, Yu; Dong, Juncai; Huang, Zheng-Qing Nature Nanotechnology, Vol. 15, Issue 5 https://doi.org/10.1038/s41565-020-0665-x	journal	March 2020
Heterogeneous single-atom catalysis Wang, Aiqin; Li, Jun; Zhang, Tao Nature Reviews Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/s41570-018-0010-1	journal	May 2018
PdMo bimetallene for oxygen reduction catalysis Luo, Mingchuan; Zhao, Zhonglong; Zhang, Yelong Nature, Vol. 574, Issue 7776 https://doi.org/10.1038/s41586-019-1603-7	journal	September 2019
A universal principle for a rational design of single-atom electrocatalysts Xu, Haoxiang; Cheng, Daojian; Cao, Dapeng Nature Catalysis, Vol. 1, Issue 5 https://doi.org/10.1038/s41929-018-0063-z	journal	April 2018
Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells Li, Jiazhan; Chen, Mengjie; Cullen, David A. Nature Catalysis, Vol. 1, Issue 12 https://doi.org/10.1038/s41929-018-0164-8	journal	October 2018
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells Wan, Xin; Liu, Xiaofang; Li, Yongcheng Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0237-3	journal	March 2019
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction Nie, Yao; Li, Li; Wei, Zidong Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00484A	journal	January 2015
The Achilles' heel of iron-based catalysts during oxygen reduction in an acidic medium Choi, Chang Hyuck; Lim, Hyung-Kyu; Chung, Min Wook Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/C8EE01855C	journal	January 2018
MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions Wang, Hao-Fan; Chen, Liyu; Pang, Huan Chemical Society Reviews, Vol. 49, Issue 5 https://doi.org/10.1039/C9CS00906J	journal	January 2020
Fe ₁ N ₄ –O ₁ site with axial Fe–O coordination for highly selective CO ₂ reduction over a wide potential range Chen, Zhiqiang; Huang, Aijian; Yu, Ke Energy & Environmental Science, Vol. 14, Issue 6 https://doi.org/10.1039/D1EE00569C	journal	January 2021
Balanced crystal orbital overlap population—a tool for analysing chemical bonds in solids Grechnev, Alexei; Ahuja, Rajeev; Eriksson, Olle Journal of Physics: Condensed Matter, Vol. 15, Issue 45 https://doi.org/10.1088/0953-8984/15/45/014	journal	October 2003
Efficient oxygen reduction catalysis by subnanometer Pt alloy nanowires Jiang, Kezhu; Zhao, Dandan; Guo, Shaojun Science Advances, Vol. 3, Issue 2 https://doi.org/10.1126/sciadv.1601705	journal	February 2017
Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong Science, Vol. 366, Issue 6467 https://doi.org/10.1126/science.aaw7493	journal	November 2019
Graphene-Riched Co Wu, Gang; Chung, Hoon T.; Nelson, Mark 220th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3635702	conference	January 2011
Electrochemical Impedance Spectroscopy of Oxygen Reduction Reaction (ORR) in a Rotating Disk Electrode Configuration: Effect of Ionomer Content and Carbon-Support Singh, Ramesh Kumar; Devivaraprasad, Ruttala; Kar, Tathagata Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0141506jes	journal	January 2015
Oxygen Reduction Reaction Measurements on Platinum Electrocatalysts Utilizing Rotating Disk Electrode Technique: I. Impact of Impurities, Measurement Protocols and Applied Corrections Shinozaki, Kazuma; Zack, Jason W.; Richards, Ryan M. Journal of The Electrochemical Society, Vol. 162, Issue 10 https://doi.org/10.1149/2.1071509jes	journal	January 2015
The Crystal Orbital Hamilton Population (COHP) Method as a Tool to Visualize and Analyze Chemical Bonding in Intermetallic Compounds Steinberg, Simon; Dronskowski, Richard Crystals, Vol. 8, Issue 5 https://doi.org/10.3390/cryst8050225	journal	May 2018

Similar Records

Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction

Journal Article · 2022 · Journal of the American Chemical Society · OSTI ID:1844323

Activating Single‐Atom Ni Site via First‐Shell Si Modulation Boosts Oxygen Reduction Reaction

Journal Article · 2022 · Small · OSTI ID:2425448

Modulating Electronic Structure of Atomically Dispersed Nickel Sites through Boron and Nitrogen Dual Coordination Boosts Oxygen Reduction

Journal Article · 2023 · Advanced Functional Materials · OSTI ID:2425489

Related Subjects

Chemistry

Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction

Citation Formats

References (66)

Similar Records

Related Subjects