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Versatile Fe–Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C–H Bond Activation

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.1c10144· OSTI ID:1982050

Not provided.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1982050
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 1; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (67)

Triple Bonds between Transition Metals and the Heavier Elements of Groups 14 and 15 May 2007
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium July 2010
Cooperativity in Transition Metal Tetrylene Complexes August 2021
Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes August 2007
Recent advances in the chemistry of transition metal–silicon/germanium triple-bonded complexes January 2018
Understanding the Uniqueness of 2p Elements in Periodic Tables November 2020
New Element-Carbon (p-p)? Bonds April 1975
Multiple bonds to silicon: 20 years later March 2002
An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects May 2020
Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations January 2017
Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes August 2009
Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism November 2003
Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation January 2013
Metal-Silicon Triple Bonds: Nucleophilic Addition and Redox Reactions of the Silylidyne Complex [Cp(CO)2MoSi-R] December 2010
Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me 3 P) 2 (Ph 3 P)Rh≡E‐Ar*] (E=Sn, Pb) February 2021
A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium March 2009
The Ruthenostannylene Complex [Cp*(IXy)H2Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes April 2015
Heavy Tetrel Complexes of Ru Featuring Ru═E(R)X and Ru–E–R (E = Sn, Pb) Linkages October 2019
Triple Bonding to Germanium:  Characterization of the Transition Metal Germylynes (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Mes2 (M = Mo, W; Mes = −C6H2-2,4,6-Me3) and (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Trip2 (M = Cr, Mo, W; Trip = −C6H2-2,4,6-i-Pr3) and the Related Single Bonded Metallogermylenes (η5-C5H5)(CO)3M-G̈e-C6H3-2,6-Trip2 (M = Cr, W) January 2000
The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex August 2013
Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si) September 2015
Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts May 2015
Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)– and Cobalt(II)–Alkyl Complexes August 2013
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion October 2016
Can Spin State Change Slow Organometallic Reactions? November 1995
Do Spin State Changes Matter in Organometallic Chemistry? A Computational Study May 2004
Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing February 2018
Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center January 2020
The “Catalytic Nitrosyl Effect”: NO Bending Boosting the Efficiency of Rhenium Based Alkene Hydrogenations February 2013
Structural Evidence for Lewis Acid Triggered Nitrosyl Bending in Rhenium(–I) Chloro Catalysts for Alkene Hydrogenation Reactions December 2013
1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion September 2014
Fifty Years of Mössbauer Spectroscopy in Solid State Research - Remarkable Achievements, Future Perspectives December 2011
Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts May 2006
Flipping the Oxidation State Formalism: Charge Distribution in Organometallic Complexes As Reported by Carbon Monoxide January 2017
Synthesis, Structures, and Spectroscopy of the Metallostannylenes (η 5 -C 5 H 5 )(CO) 3 M−S̈n−C 6 H 3 -2,6-Ar 2 (M = Cr, Mo, W; Ar = C 6 H 2 -2,4,6-Me 3 , C 6 H 2 -2,4,6-Pr i 3 ) November 2002
Synthesis, Characterization, and CO Elimination of Ferrio-Substituted Two-Coordinate Germylenes and Stannylenes November 2011
Manganese–Tin Triple Bonds: A New Synthetic Route to the Manganese Stannylidyne Complex Cation trans-[H(dmpe)2Mn≡Sn(C6H3-2,6-Mes2)]+ (dmpe = Me2PCH2CH2PMe2, Mes = 2,4,6-Trimethylphenyl) July 2013
Characterization of the Earliest Intermediate of Fe-N 2 Protonation: CW and Pulse EPR Detection of an Fe-NNH Species and Its Evolution to Fe-NNH 2 + May 2019
Low Oxidation State Iron(0), Iron(I), and Ruthenium(0) Dinitrogen Complexes with a Very Bulky Neutral Phosphine Ligand February 2013
Tricarbonylbis(phosphine)iron(I) cation radicals. A spectroscopic and theoretical study June 1986
Mixed-valence [FeIFeII] hydrogenase active site model complexes stabilized by a bidentate carborane bis-phosphine ligand January 2012
Tin-Centered Radical and Cation:  Stable and Free July 2003
Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species March 2003
Insertion of a Transient Tin Nitride into Carbon–Carbon and Boron–Carbon Bonds November 2017
Reversible Sn–Sn Triple Bond Dissociation in a Distannyne: Support for Charge-Shift Bonding Character July 2019
Kinetic applications of electron paramagnetic resonance spectroscopy. VIII. Tetraalkoxyphosphoranyl radicals December 1972
Kinetic applications of electron paramagnetic resonance spectroscopy. XII. Self-reactions of some phosphorus centered radicals January 1974
Electron spin resonance study of dialkoxyphosphonyl radicals, (RO)2PO March 1972
An ESR study of the reactions of t-butoxyl radicals with aminophosphines September 1972
On Predicting Mössbauer Parameters of Iron-Containing Molecules with Density-Functional Theory October 2013
Long-Range Corrected Hybrid Density Functionals with Improved Dispersion Corrections November 2012
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy January 2005
Synthesis and characterization of (η 5 -C 5 Me 5 )W(NO)I 2 , a monomeric, formally 16-electron complex August 1988
Coordination and Organometallic Chemistry of Metal−NO Complexes April 2002
Application of the pople-santry-segal CNDO method to the cyclopropylcarbinyl and cyclobutyl cation and to bicyclobutane January 1968
A new integral equation formalism for the polarizable continuum model: Theoretical background and applications to isotropic and anisotropic dielectrics August 1997
The Dielectric Constant and Density of Benzene to 400 °C and 3000 bar April 1991
Efficient exploration of reaction paths via a freezing string method December 2011
Comprehensive Benchmark Results for the Domain Based Local Pair Natural Orbital Coupled Cluster Method (DLPNO-CCSD(T)) for Closed- and Open-Shell Systems December 2019
Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model March 1998
Kinetics of cis-trans isomerization and reductive elimination in dihydridobis(trimethylphosphine)platinum(II) May 1988
A Triad of Highly Reduced, Linear Iron Nitrosyl Complexes: {FeNO} 8-10 August 2016
Exploring the Limits of Dative Boratrane Bonding: Iron as a Strong Lewis Base in Low-Valent Non-Heme Iron-Nitrosyl Complexes September 2020
Tin-Mediated CH Activation and Cross-Coupling in a Single Flask August 2006
Facile C–H Bond Metathesis Mediated by a Stannylene April 2018
Bimetallic iron–tin catalyst for N2 to NH3 and a silyldiazenido model intermediate January 2020
Selectivity Effects in Bimetallic Catalysis February 2016