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Chemical Upcycling of Polyethylene to Value-Added α,ω-Divinyl-Functionalized Oligomers

Journal Article · · ACS Sustainable Chemistry & Engineering
 [1];  [1];  [2];  [3];  [3];  [1];  [3];  [4];  [4]
  1. Department of Chemistry and Biochemistry, University of California at Santa Barbara, Santa Barbara, California 93106, United States
  2. Department of Chemical Engineering, University of California at Santa Barbara, Santa Barbara, California 93106, United States
  3. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States
  4. Department of Chemistry and Biochemistry, University of California at Santa Barbara, Santa Barbara, California 93106, United States; Department of Chemical Engineering, University of California at Santa Barbara, Santa Barbara, California 93106, United States

Not provided.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Institute for Cooperative Upcycling of Plastics (iCOUP)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-07CH11358
OSTI ID:
1982040
Journal Information:
ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 41; ISSN 2168-0485
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (43)

Production, use, and fate of all plastics ever made July 2017
Plastic waste inputs from land into the ocean February 2015
The presence of microplastics in commercial salts from different countries April 2017
Transport and release of chemicals from plastics to the environment and to wildlife July 2009
Chemical recycling of waste plastics for new materials production June 2017
Mechanical and chemical recycling of solid plastic waste November 2017
A review on pyrolysis of plastic wastes May 2016
Degradation of Polypropylene and Polyethylene Wastes Over HZSM-5 and USY Zeolites January 2019
Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions June 2016
Upcycling Single-Use Polyethylene into High-Quality Liquid Products September 2019
Catalytic upcycling of high-density polyethylene via a processive mechanism October 2020
Trash to Treasure: Microwave-Assisted Conversion of Polyethylene to Functional Chemicals December 2017
Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization October 2020
Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds June 2016
Poly-α-olefin-based synthetic lubricants: a short review on various synthetic routes: PAO SYNTHESIS: A SHORT REVIEW September 2011
Selective oxidation of bromide in wastewater brines from hydraulic fracturing July 2013
Interplay Between Bromine and Iodine in Oxidative Dehydrogenation March 2013
Natural gas conversion to liquid fuels in a zone reactor October 2005
An integrated process for partial oxidation of alkanes January 2003
Photocatalytic Oxidation of Bromide to Bromine September 2016
Catalytic Bromination of Alkyl sp 3 C–H Bonds with KBr/Air under Visible Light August 2018
Catalytic Bromine Recovery: An Enabling Technology for Emerging Alkane Functionalization Processes September 2013
Photochemical bromination of polyolefin surfaces March 2001
Mild halogenation of polyolefins using an N -haloamide reagent January 2018
Suspension bromination of high-density polyethylene March 1979
Highly Efficient Oxidative Bromination of Alkanes with the HBr-H2O2 System in the Presence of Catalyst December 2010
Transcrystallinity in brominated UHMWPE fiber reinforced HDPE composites: morphology and dielectric properties February 2003
Surface Modification of Polyethylene through Bromination February 1999
Pathways for degradation of plastic polymers floating in the marine environment January 2015
Organic Chemistry January 2014
Alkene-assisted cis -to- trans isomerization of non-conjugated polyunsaturated alkenes January 2017
Ethenolysis of ricinoleic acid methyl ester – an efficient way to the oleochemical key substance methyl dec-9-enoate January 2012
Efficient Synthesis of α,ω-Divinyl-Functionalized Polyolefins April 2014
Acyclic diene metathesis (ADMET) depolymerization: Ethenolysis of 1,4-polybutadiene using a ruthenium complex June 1999
Robust and Selective Metathesis Catalysts for Oleochemical Applications June 2012
The Future of Ethenolysis in Biobased Chemistry December 2016
Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis December 2014
System Analyses of High-Value Chemicals and Fuels from a Waste High-Density Polyethylene Refinery. Part 1: Conceptual Design and Techno-Economic Assessment November 2019
Investigation of the Bromination/Dehydrobromination of Long Chain Alkanes August 2017
Brominated Polyethylene. Synthesis, Photooxidation and Use as the Intermediate for the Preparation of New Polymeric Stabilizers July 1998
Alkene ozonolysis July 2017
The Preparation of Aldehydes, Ketones, and Acids by Ozone Oxidation May 1943
Oxidative Cleavage of Olefins by In Situ-Generated Catalytic 3,4,5,6-Tetramethyl-2-iodoxybenzoic Acid/Oxone November 2014