Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Effect of Humidity on C 1 , C 2 Product Selectivity for CO 2 Reduction in a Hybrid Gas/Liquid Electrochemical Reactor

Journal Article · · ACS Applied Energy Materials
 [1];  [2];  [2];  [3];  [1]
  1. Department of Chemistry, Duke University, Durham, North Carolina 27708, United States
  2. Reactwell, L.L.C., 1441 Canal Street, Lab 301 Box 5b, New Orleans, Louisiana 70112, United States
  3. U.S. Army DEVCOM Army Research Laboratory-South/Rice University, 6100 Main St., Houston, Texas 77005, United States; Department of Physics, Duke University, Durham, North Carolina 27708, United States

Not provided.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1981977
Journal Information:
ACS Applied Energy Materials, Vol. 5, Issue 8; ISSN 2574-0962
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (30)

What would it take for renewably powered electrosynthesis to displace petrochemical processes? journal April 2019
Electrolytic CO 2 Reduction in a Flow Cell journal March 2018
Introductory Guide to Assembling and Operating Gas Diffusion Electrodes for Electrochemical CO 2 Reduction journal February 2019
Gas diffusion electrodes and membranes for CO2 reduction electrolysers journal September 2021
Gas diffusion electrode design for electrochemical carbon dioxide reduction journal January 2020
CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2 journal February 2020
Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper journal April 2020
Role of the Carbon-Based Gas Diffusion Layer on Flooding in a Gas Diffusion Electrode Cell for Electrochemical CO 2 Reduction journal November 2020
CO 2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions journal January 2019
High Rate, Selective, and Stable Electroreduction of CO 2 to CO in Basic and Neutral Media journal October 2018
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface journal May 2018
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels journal September 2019
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products journal March 2019
Insights into the Low Overpotential Electroreduction of CO 2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer journal November 2017
Progress and Perspectives of Electrochemical CO 2 Reduction on Copper in Aqueous Electrolyte journal April 2019
Using pH Dependence to Understand Mechanisms in Electrochemical CO Reduction journal March 2022
Electrolyte Driven Highly Selective CO 2 Electroreduction at Low Overpotentials journal October 2019
Managing Hydration at the Cathode Enables Efficient CO 2 Electrolysis at Commercially Relevant Current Densities journal April 2020
Electrolysis of CO 2 to Syngas in Bipolar Membrane-Based Electrochemical Cells journal November 2016
Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces journal February 2019
High-Selectivity Electrochemical Conversion of CO 2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode journal September 2016
Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment journal January 2021
Modulating Local CO2 Concentration as a General Strategy for Enhancing C−C Coupling in CO2 Electroreduction journal May 2020
Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism journal December 2015
Strategies in catalysts and electrolyzer design for electrochemical CO 2 reduction toward C 2+ products journal February 2020
Efficient Methane Electrosynthesis Enabled by Tuning Local CO 2 Availability journal January 2020
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate journal April 2019
Computational Comparison of Late Transition Metal (100) Surfaces for the Electrocatalytic Reduction of CO to C 2 Species journal April 2018
Mechanisms and Kinetics of Acetaldehyde Reaction in Supercritical Water:  Noncatalytic Disproportionation, Condensation, and Decarbonylation journal December 2004
The Importance of Cannizzaro-Type Reactions during Electrocatalytic Reduction of Carbon Dioxide journal January 2017