Tailoring the Lithium Solid Electrolyte Interphase for Highly Concentrated Electrolytes with Direct Exposure to Halogenated Solvents

Thornburg, Eric S.; Haasch, Richard T.; Gewirth, Andrew A.

doi:10.1021/acsaem.1c03336

Tailoring the Lithium Solid Electrolyte Interphase for Highly Concentrated Electrolytes with Direct Exposure to Halogenated Solvents

Journal Article · 21 February 2022 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.1c03336· OSTI ID:1981971

Thornburg, Eric S. ^[1]; ^[2]; ^[1]

Department of Chemistry, University of Illinois at Urbana-Champaign, 600 S Mathews Avenue, Urbana, Illinois 61801, United States
Materials Research Laboratory Central Research Facilities, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States

Not provided.

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1981971

Journal Information:: ACS Applied Energy Materials, Vol. 5, Issue 3; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (62)

Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries Wu, Feixiang; Maier, Joachim; Yu, Yan Chemical Society Reviews, Vol. 49, Issue 5 https://doi.org/10.1039/C7CS00863E	journal	January 2020
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Towards better Li metal anodes: Challenges and strategies Zhang, Ying; Zuo, Tong-Tong; Popovic, Jelena Materials Today, Vol. 33 https://doi.org/10.1016/j.mattod.2019.09.018	journal	March 2020
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes Lu, Dongping; Shao, Yuyan; Lozano, Terence Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400993	journal	September 2014
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00371D	journal	January 2017
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Before Li Ion Batteries Winter, Martin; Barnett, Brian; Xu, Kang Chemical Reviews, Vol. 118, Issue 23 https://doi.org/10.1021/acs.chemrev.8b00422	journal	November 2018
Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes Wu, Haiping; Jia, Hao; Wang, Chongmin Advanced Energy Materials, Vol. 11, Issue 5 https://doi.org/10.1002/aenm.202003092	journal	December 2020
Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition Yan, Chong; Cheng, Xin‐Bing; Tian, Yang Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201707629	journal	April 2018
Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes McMillan, Rod; Slegr, Helen; Shu, Z. X. Journal of Power Sources, Vol. 81-82, p. 20-26 https://doi.org/10.1016/S0378-7753(98)00201-8	journal	September 1999
Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Fluoroethylene Carbonate as an Important Component for the Formation of an Effective Solid Electrolyte Interphase on Anodes and Cathodes for Advanced Li-Ion Batteries Markevich, Elena; Salitra, Gregory; Aurbach, Doron ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00163	journal	May 2017
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution Markevich, Elena; Salitra, Gregory; Chesneau, Frederick ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00300	journal	May 2017
Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes Brown, Zachary L.; Jurng, Sunhyung; Nguyen, Cao Cuong ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00705	journal	June 2018
An Artificial Lithium Protective Layer that Enables the Use of Acetonitrile-Based Electrolytes in Lithium Metal Batteries Trinh, Ngoc Duc; Lepage, David; Aymé-Perrot, David Angewandte Chemie International Edition, Vol. 57, Issue 18 https://doi.org/10.1002/anie.201801737	journal	March 2018
Fluoroethylene Carbonate as Electrolyte Additive in Tetraethylene Glycol Dimethyl Ether Based Electrolytes for Application in Lithium Ion and Lithium Metal Batteries Heine, Jennifer; Hilbig, Peter; Qi, Xin Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0011507jes	journal	January 2015
Lithium Metal Batteries Enabled by Synergetic Additives in Commercial Carbonate Electrolytes Piao, Nan; Liu, Sufu; Zhang, Bao ACS Energy Letters, Vol. 6, Issue 5 https://doi.org/10.1021/acsenergylett.1c00365	journal	April 2021
Use of Chloroethylene Carbonate as an Electrolyte Solvent for a Lithium Ion Battery Containing a Graphitic Anode Shu, Z. X.; McMillan, R. S.; Murray, J. J. Journal of The Electrochemical Society, Vol. 142, Issue 9 https://doi.org/10.1149/1.2048734	journal	September 1995
Use of Chloroethylene Carbonate as an Electrolyte Solvent for a Graphite Anode in a Lithium‐Ion Battery Shu, Z. X.; McMillan, R. S.; Murray, J. J. Journal of The Electrochemical Society, Vol. 143, Issue 7 https://doi.org/10.1149/1.1836985	journal	July 1996
Chloroethylene Carbonate, a Solvent for Lithium‐Ion Cells, Evolving CO 2 during Reduction Winter, Martin; Novák, Petr Journal of The Electrochemical Society, Vol. 145, Issue 2 https://doi.org/10.1149/1.1838270	journal	February 1998
FTIR and DEMS investigations on the electroreduction of chloroethylene carbonate-based electrolyte solutions for lithium-ion cells Winter, M.; Imhof, R.; Joho, F. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00116-0	journal	September 1999
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D. Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00372A	journal	January 2014
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046 https://doi.org/10.1021/ja412807w	journal	March 2014
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
High‐Power Lithium Metal Batteries Enabled by High‐Concentration Acetonitrile‐Based Electrolytes with Vinylene Carbonate Additive Peng, Zhe; Cao, Xia; Gao, Peiyuan Advanced Functional Materials, Vol. 30, Issue 24 https://doi.org/10.1002/adfm.202001285	journal	April 2020
Enabling High Capacity and Coulombic Efficiency for Li‐NCM811 Cells Using a Highly Concentrated Electrolyte Philip, Maria A.; Haasch, Richard T.; Kim, Jutae Batteries & Supercaps, Vol. 4, Issue 2 https://doi.org/10.1002/batt.202000192	journal	October 2020
Fluoride in the SEI Stabilizes the Li Metal Interface in Li–S Batteries with Solvate Electrolytes Ware, Skyler D.; Hansen, Charles J.; Jones, John-Paul ACS Applied Materials & Interfaces, Vol. 13, Issue 16 https://doi.org/10.1021/acsami.1c02629	journal	April 2021
Effect of the Hydrofluoroether Cosolvent Structure in Acetonitrile-Based Solvate Electrolytes on the Li ⁺ Solvation Structure and Li–S Battery Performance Shin, Minjeong; Wu, Heng-Liang; Narayanan, Badri ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b11566	journal	November 2017
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
Review—Superconcentrated Electrolytes for Lithium Batteries Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0041514jes	journal	January 2015
Sacrificial Anion Reduction Mechanism for Electrochemical Stability Improvement in Highly Concentrated Li-Salt Electrolyte Sodeyama, Keitaro; Yamada, Yuki; Aikawa, Koharu The Journal of Physical Chemistry C, Vol. 118, Issue 26, p. 14091-14097 https://doi.org/10.1021/jp501178n	journal	June 2014
Effect of Hydrofluoroether Cosolvent Addition on Li Solvation in Acetonitrile-Based Solvate Electrolytes and Its Influence on S Reduction in a Li–S Battery See, Kimberly A.; Wu, Heng-Liang; Lau, Kah Chun ACS Applied Materials & Interfaces, Vol. 8, Issue 50 https://doi.org/10.1021/acsami.6b11358	journal	December 2016
Solvent-Mediated Li ₂ S Electrodeposition: A Critical Manipulator in Lithium-Sulfur Batteries Li, Zhejun; Zhou, Yucun; Wang, Yu Advanced Energy Materials, Vol. 9, Issue 1 https://doi.org/10.1002/aenm.201802207	journal	November 2018
Critical evaluation of the stability of highly concentrated LiTFSI - Acetonitrile electrolytes vs. graphite, lithium metal and LiFePO4 electrodes Nilsson, Viktor; Younesi, Reza; Brandell, Daniel Journal of Power Sources, Vol. 384 https://doi.org/10.1016/j.jpowsour.2018.03.019	journal	April 2018
Characterization of Reactions and Products of the Discharge and Forced Overdischarge of Li / SO 2 Cells Rupich, M. W.; Pitts, L.; Abraham, K. M. Journal of The Electrochemical Society, Vol. 129, Issue 9 https://doi.org/10.1149/1.2124314	journal	September 1982
Microscopic Formation Mechanism of Solid Electrolyte Interphase Film in Lithium-Ion Batteries with Highly Concentrated Electrolyte Takenaka, Norio; Fujie, Takuya; Bouibes, Amine The Journal of Physical Chemistry C, Vol. 122, Issue 5 https://doi.org/10.1021/acs.jpcc.7b11650	journal	January 2018
Mechanistic Insight on the Formation of a Solid Electrolyte Interphase (SEI) by an Acetonitrile-Based Superconcentrated [Li][TFSI] Electrolyte near Lithium Metal Dhattarwal, Harender S.; Chen, Yun-Wen; Kuo, Jer-Lai The Journal of Physical Chemistry C, Vol. 124, Issue 50 https://doi.org/10.1021/acs.jpcc.0c08009	journal	December 2020
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F. ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00260	journal	October 2016
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium He, Mingfu; Guo, Rui; Hobold, Gustavo M. Proceedings of the National Academy of Sciences, Vol. 117, Issue 1 https://doi.org/10.1073/pnas.1911017116	journal	December 2019
Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling Grande, Lorenzo; Paillard, Elie; Kim, Guk-Tae International Journal of Molecular Sciences, Vol. 15, Issue 5 https://doi.org/10.3390/ijms15058122	journal	May 2014
Regulating Li deposition by constructing LiF-rich host for dendrite-free lithium metal anode Yuan, Yanxia; Wu, Feng; Bai, Ying Energy Storage Materials, Vol. 16 https://doi.org/10.1016/j.ensm.2018.06.022	journal	January 2019
Lithium Metal Anodes with Nonaqueous Electrolytes Zhang, Ji-Guang; Xu, Wu; Xiao, Jie Chemical Reviews, Vol. 120, Issue 24 https://doi.org/10.1021/acs.chemrev.0c00275	journal	November 2020
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries Aurbach, Doron Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00431-6	journal	August 2000
Artificial Solid Electrolyte Interphases for Lithium Metal Electrodes by Wet Processing: The Role of Metal Salt Concentration and Solvent Choice Thanner, Katharina; Varzi, Alberto; Buchholz, Daniel ACS Applied Materials & Interfaces, Vol. 12, Issue 29 https://doi.org/10.1021/acsami.0c08938	journal	June 2020
Electrochemical Impedance Spectroscopy and X-ray Photoelectron Spectroscopy Study of Lithium Metal Surface Aging in Imidazolium-Based Ionic Liquid Electrolytes Performed at Open-Circuit Voltage Morales-Ugarte, J. E.; Benayad, A.; Santini, C. C. ACS Applied Materials & Interfaces, Vol. 11, Issue 24 https://doi.org/10.1021/acsami.9b00753	journal	May 2019
Electrochemical impedance spectroscopy of a Li–S battery: Part 1. Influence of the electrode and electrolyte compositions on the impedance of symmetric cells Conder, Joanna; Villevieille, Claire; Trabesinger, Sigita Electrochimica Acta, Vol. 244 https://doi.org/10.1016/j.electacta.2017.05.041	journal	August 2017
Understanding the Relationships between Morphology, Solid Electrolyte Interphase Composition, and Coulombic Efficiency of Lithium Metal He, Yitao; Fan, Wenda; Zhang, Yaohui ACS Applied Materials & Interfaces, Vol. 12, Issue 19 https://doi.org/10.1021/acsami.0c00789	journal	April 2020
Surface reactions of chlorine molecules and atoms with water and sulfuric acid at low temperatures Wren, Anthony G.; Phillips, Roger W.; Tolentino, Lucio U. Journal of Colloid and Interface Science, Vol. 70, Issue 3 https://doi.org/10.1016/0021-9797(79)90062-6	journal	July 1979
Coordination of acetonitrile (CH3CN) to platinum (111): Evidence for an η2(C, N) species Sexton, B. A.; Avery, N. R. Surface Science, Vol. 129, Issue 1 https://doi.org/10.1016/0039-6028(83)90092-4	journal	June 1983
XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction Wood, Kevin N.; Teeter, Glenn ACS Applied Energy Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsaem.8b00406	journal	August 2018
ESCA spectra and molecular charge distributions for some pyrimidine and purine bases Peeling, James; Hruska, Frank E.; McIntyre, N. Stewart Canadian Journal of Chemistry, Vol. 56, Issue 11 https://doi.org/10.1139/v78-252	journal	June 1978
Cryogenic Focused Ion Beam Characterization of Lithium Metal Anodes Lee, Jungwoo Z.; Wynn, Thomas A.; Schroeder, Marshall A. ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.8b02381	journal	January 2019
Artificial Soft-Rigid Protective Layer for Dendrite-Free Lithium Metal Anode Xu, Rui; Zhang, Xue-Qiang; Cheng, Xin-Bing Advanced Functional Materials, Vol. 28, Issue 8 https://doi.org/10.1002/adfm.201705838	journal	January 2018
High-Efficiency Lithium Metal Anode Enabled by a Concentrated/Fluorinated Ester Electrolyte Chen, Shijian; Xiang, Yuxuan; Zheng, Guorui ACS Applied Materials & Interfaces, Vol. 12, Issue 24 https://doi.org/10.1021/acsami.0c06930	journal	May 2020
Lithium Azide as an Electrolyte Additive for All-Solid-State Lithium-Sulfur Batteries Eshetu, Gebrekidan Gebresilassie; Judez, Xabier; Li, Chunmei Angewandte Chemie International Edition, Vol. 56, Issue 48 https://doi.org/10.1002/anie.201709305	journal	October 2017
Salt effect on polyaddition of bifunctional cyclic carbonate and diamine Ochiai, Bungo; Inoue, Shoko; Endo, Takeshi Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 24 https://doi.org/10.1002/pola.21081	journal	January 2005
A Novel Organic “Polyurea” Thin Film for Ultralong-Life Lithium-Metal Anodes via Molecular-Layer Deposition Sun, Yipeng; Zhao, Yang; Wang, Jiwei Advanced Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adma.201806541	journal	December 2018
Solid Electrolyte Interphase Evolution on Lithium Metal in Contact with Glyme‐Based Electrolytes Nojabaee, Maryam; Küster, Kathrin; Starke, Ulrich Small, Vol. 16, Issue 23 https://doi.org/10.1002/smll.202000756	journal	May 2020
Effect of LiFSI Concentrations To Form Thickness- and Modulus-Controlled SEI Layers on Lithium Metal Anodes Wang, Muqin; Huai, Liyuan; Hu, Guohong The Journal of Physical Chemistry C, Vol. 122, Issue 18 https://doi.org/10.1021/acs.jpcc.8b02314	journal	April 2018
X-ray Photoelectron Spectroscopy Studies of Lithium Surfaces Prepared in Several Important Electrolyte Solutions. A Comparison with Previous Studies by Fourier Transform Infrared Spectroscopy Aurbach, Doron; Weissman, Idit; Schechter, Alexander Langmuir, Vol. 12, Issue 16 https://doi.org/10.1021/la9600762	journal	January 1996
Effects of High and Low Salt Concentration in Electrolytes at Lithium–Metal Anode Surfaces Camacho-Forero, Luis E.; Smith, Taylor W.; Balbuena, Perla B. The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b10774	journal	December 2016
Critical Role of Anion–Solvent Interactions for Dynamics of Solvent-in-Salt Solutions Popov, Ivan; Sacci, Robert L.; Sanders, Nicolette C. The Journal of Physical Chemistry C, Vol. 124, Issue 16 https://doi.org/10.1021/acs.jpcc.9b10807	journal	March 2020

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