Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Microelectrode-Based Sensor for Measuring Operando Active Species Concentrations in Redox Flow Cells

Journal Article · · ACS Applied Energy Materials
 [1];  [1];  [2];  [1]
  1. Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
  2. Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States

Not provided.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1981969
Journal Information:
ACS Applied Energy Materials, Vol. 4, Issue 12; ISSN 2574-0962
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (49)

Energy storage emerging: A perspective from the Joint Center for Energy Storage Research journal June 2020
Long-Duration Electricity Storage Applications, Economics, and Technologies journal January 2020
Advanced Redox-Flow Batteries: A Perspective journal September 2015
Recent advancements in rational design of non-aqueous organic redox flow batteries journal January 2020
Assessing the levelized cost of vanadium redox flow batteries with capacity fade and rebalancing journal June 2020
Assessing capacity loss remediation methods for asymmetric redox flow battery chemistries using levelized cost of storage journal September 2021
Design Rules for Membranes from Polymers of Intrinsic Microporosity for Crossover-free Aqueous Electrochemical Devices journal December 2019
Electrolyte Lifetime in Aqueous Organic Redox Flow Batteries: A Critical Review journal February 2020
Crossover mitigation strategies for redox-flow batteries journal June 2020
Understanding and Mitigating Capacity Fade in Aqueous Organic Redox Flow Batteries journal January 2018
Trust is good, control is better: a review on monitoring and characterization techniques for flow battery electrolytes journal January 2021
A Highly Soluble Organic Catholyte for Non-Aqueous Redox Flow Batteries journal April 2015
Spectroscopic Measurement of State of Charge in Vanadium Flow Batteries with an Analytical Model of V IV -V V Absorbance journal September 2015
Coupled In Situ NMR and EPR Studies Reveal the Electron Transfer Rate and Electrolyte Decomposition in Redox Flow Batteries journal January 2021
In situ NMR metrology reveals reaction mechanisms in redox flow batteries journal March 2020
Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications journal February 2017
The lightest organic radical cation for charge storage in redox flow batteries journal August 2016
Annulated Dialkoxybenzenes as Catholyte Materials for Non-aqueous Redox Flow Batteries: Achieving High Chemical Stability through Bicyclic Substitution journal July 2017
IR Spectroscopy as a Method for Online Electrolyte State Assessment in RFBs journal June 2021
High resolution state of charge monitoring of vanadium electrolytes with IR optical sensor journal April 2013
Critical Review—Experimental Diagnostics and Material Characterization Techniques Used on Redox Flow Batteries journal January 2018
State of charge monitoring of vanadium redox flow batteries using half cell potentials and electrolyte density journal February 2018
Investigation of the use of electrolyte viscosity for online state-of-charge monitoring design in vanadium redox flow battery journal February 2018
Conductivity of Vanadium Flow Battery (VFB) Catholytes: Dependence on Sulfur and Vanadium Concentration and Temperature journal October 2017
State of charge indicators for alkaline zinc-air redox flow batteries journal June 2019
Monitoring the state of charge of all-vanadium redox flow batteries to identify crossover of electrolyte journal March 2020
The importance of key operational variables and electrolyte monitoring to the performance of an all vanadium redox flow battery: Performance of an all vanadium redox flow battery journal August 2012
Open circuit voltage of vanadium redox flow batteries: Discrepancy between models and experiments journal April 2011
Thermodynamically Rigorous Description of the Open Circuit Voltage of Redox Flow Batteries journal July 2020
State-of-charge monitoring for redox flow batteries: A symmetric open-circuit cell approach journal May 2019
A combined in situ monitoring approach for half cell state of charge and state of health of vanadium redox flow batteries journal December 2020
Electrolyte Compositions in a Vanadium Redox Flow Battery Measured with a Reference Cell journal January 2019
Using voltammetry augmented with physics-based modeling and Bayesian hypothesis testing to identify analytes in electrolyte solutions journal January 2022
Recent advances and future perspectives for automated parameterisation, Bayesian inference and machine learning in voltammetry journal January 2021
Monitoring the State of Charge of the Positive Electrolyte in a Vanadium Redox-Flow Battery with a Novel Amperometric Sensor journal January 2019
Designing high energy density flow batteries by tuning active-material thermodynamics journal January 2021
Designing Redox-Active Oligomers for Crossover-Free, Nonaqueous Redox-Flow Batteries with High Volumetric Energy Density journal May 2018
Redox Active Polymers for Non-Aqueous Redox Flow Batteries: Validation of the Size-Exclusion Approach journal January 2017
A Method for Evaluating Soluble Redox Couple Stability Using Microelectrode Voltammetry journal December 2020
Past, present and future contributions of microelectrodes to analytical studies employing voltammetric detection. A review journal January 1994
An Amperometric, Temperature-Independent, and Calibration-Free Method for the Real-Time State-of-Charge Monitoring of Redox Flow Battery Electrolytes journal July 2019
High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries journal January 2016
Quantifying Environmental Effects on the Solution and Solid-State Stability of a Phenothiazine Radical Cation journal February 2020
4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl as a model organic redox active compound for nonaqueous flow batteries journal September 2016
Quantifying Mass Transfer Rates in Redox Flow Batteries journal January 2017
Anodic oxidation of propylene carbonate on platinum, glassy carbon and polypyrrole journal May 1989
Understanding Voltammetry book December 2011
Viscous flow properties and hydrodynamic diameter of phenothiazine-based redox-active molecules in different supporting salt environments journal August 2020
Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries journal October 2014