Temperature Dependence of Chain Conformations and Fibril Formation in Solutions of Poly( N -isopropylacrylamide)-Grafted Methylcellulose

Coughlin, McKenzie L.; Edmund, Jerrick; Bates, Frank S.; Lodge, Timothy P.

doi:10.1021/acs.macromol.1c02206

Temperature Dependence of Chain Conformations and Fibril Formation in Solutions of Poly( N -isopropylacrylamide)-Grafted Methylcellulose

Journal Article · 10 January 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c02206· OSTI ID:1981948

^[1]; Edmund, Jerrick ^[1]; ^[1]; ^[2]

Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States; Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, United States

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1981948

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 2 Vol. 55; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (61)

Linear and Nonlinear Rheological Behavior of Fibrillar Methylcellulose Hydrogels McAllister, John W.; Lott, Joseph R.; Schmidt, Peter W. ACS Macro Letters, Vol. 4, Issue 5 https://doi.org/10.1021/acsmacrolett.5b00150	journal	April 2015
Single-chain transition of poly(N-isopropylacrylamide) in water Kubota, Kenji.; Fujishige, Shouei.; Ando, Isao. The Journal of Physical Chemistry, Vol. 94, Issue 12 https://doi.org/10.1021/j100375a070	journal	June 1990
Fibrillar Structure in Aqueous Methylcellulose Solutions and Gels Lott, Joseph R.; McAllister, John W.; Wasbrough, Matthew Macromolecules, Vol. 46, Issue 24 https://doi.org/10.1021/ma4021642	journal	December 2013
Interplay of Phase Separation and Thermoreversible Gelation in Aqueous Methylcellulose Solutions Arvidson, S. A.; Lott, J. R.; McAllister, J. W. Macromolecules, Vol. 46, Issue 1 https://doi.org/10.1021/ma3019359	journal	December 2012
Thermoresponsive poly(N-isopropylacrylamide)-g-methylcellulose hydrogel as a three-dimensional extracellular matrix for cartilage-engineered applications Sá-Lima, Helena; Tuzlakoglu, Kadriye; Mano, João F. Journal of Biomedical Materials Research Part A, Vol. 98A, Issue 4 https://doi.org/10.1002/jbm.a.33140	journal	June 2011
Salt-Dependent Structure in Methylcellulose Fibrillar Gels Liberman, Lucy; Schmidt, Peter W.; Coughlin, McKenzie L. Macromolecules, Vol. 54, Issue 5 https://doi.org/10.1021/acs.macromol.0c02429	journal	February 2021
Application of the Cascade Theory to Calculation of Particle Scattering Factors of Polydisperse Systems of Stiff Chains Franken, I.; Burchard, W. Macromolecules, Vol. 6, Issue 6 https://doi.org/10.1021/ma60036a013	journal	November 1973
Surfactant-induced lyotropic behavior of flexible polymer solutions Fredrickson, Glenn H. Macromolecules, Vol. 26, Issue 11 https://doi.org/10.1021/ma00063a029	journal	May 1993
Thermal gelation properties of methyl and hydroxypropyl methylcellulose Sarkar, N. Journal of Applied Polymer Science, Vol. 24, Issue 4 https://doi.org/10.1002/app.1979.070240420	journal	August 1979
Effect of Poly(ethylene glycol) Grafting Density on Methylcellulose Fibril Formation Morozova, Svetlana; Schmidt, Peter W.; Bates, Frank S. Macromolecules, Vol. 51, Issue 23 https://doi.org/10.1021/acs.macromol.8b01899	journal	November 2018
Thermal reversible gelation during phase separation of poly(N-isopropyl acrylamide)/water solution Zeng, Fang; Liu, Xinxing; Tong, Zhen Science in China Series B: Chemistry, Vol. 43, Issue 4 https://doi.org/10.1007/BF02969449	journal	August 2000
Internal Structure of Methylcellulose Fibrils Schmidt, Peter W.; Morozova, Svetlana; Ertem, S. Piril Macromolecules, Vol. 53, Issue 1 https://doi.org/10.1021/acs.macromol.9b01773	journal	December 2019
Scattering Functions of Semiflexible Polymers with and without Excluded Volume Effects Pedersen, Jan Skov; Schurtenberger, Peter Macromolecules, Vol. 29, Issue 23 https://doi.org/10.1021/ma9607630	journal	January 1996
Functionalization of cellulose nanocrystal films via “thiol–ene” click reaction Huang, Jian-Lin; Li, Chao-Jun; Gray, Derek G. RSC Advances, Vol. 4, Issue 14 https://doi.org/10.1039/c3ra47041e	journal	January 2014
Poly(N-isopropylacrylamide): experiment, theory and application Schild, H. G. Progress in Polymer Science, Vol. 17, Issue 2, p. 163-249 https://doi.org/10.1016/0079-6700(92)90023-R	journal	January 1992
Conformation of Methylcellulose as a Function of Poly(ethylene glycol) Graft Density Morozova, Svetlana; Lodge, Timothy P. ACS Macro Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acsmacrolett.7b00776	journal	November 2017
Apparatus and Methods for Measurement and Interpretation of the Angular Variation of Light Scattering; Preliminary Results on Polystyrene Solutions Zimm, Bruno H. The Journal of Chemical Physics, Vol. 16, Issue 12 https://doi.org/10.1063/1.1746740	journal	December 1948
Origins of the suppression of fibril formation in grafted methylcellulose solutions Sethuraman, Vaidyanathan; Dorfman, Kevin D. Physical Review Materials, Vol. 4, Issue 8 https://doi.org/10.1103/PhysRevMaterials.4.085601	journal	August 2020
Synthesis of allyl cellulose in NaOH/urea aqueous solutions and its thiol–ene click reactions Hu, Haoze; You, Jun; Gan, Weiping Polymer Chemistry, Vol. 6, Issue 18 https://doi.org/10.1039/C5PY00301F	journal	January 2015
Aggregation and network formation of aqueous methylcellulose and hydroxypropylmethylcellulose solutions Bodvik, Rasmus; Dedinaite, Andra; Karlson, Leif Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 354, Issue 1-3 https://doi.org/10.1016/j.colsurfa.2009.09.040	journal	February 2010
Methyl cellulose solutions and gels: fibril formation and gelation properties Coughlin, McKenzie L.; Liberman, Lucy; Ertem, S. Piril Progress in Polymer Science, Vol. 112 https://doi.org/10.1016/j.progpolymsci.2020.101324	journal	January 2021
Amphiphilic Graft Copolymer in a Selective Solvent: Intramolecular Structures and Conformational Transitions Borisov, O. V.; Zhulina, E. B. Macromolecules, Vol. 38, Issue 6 https://doi.org/10.1021/ma047464s	journal	February 2005
Injectable, Mixed Natural-Synthetic Polymer Hydrogels with Modular Properties Patenaude, Mathew; Hoare, Todd Biomacromolecules, Vol. 13, Issue 2 https://doi.org/10.1021/bm2013982	journal	February 2012
Solvent-Induced Length Variation of Cylindrical Brushes Fischer, Karl; Schmidt, Manfred Macromolecular Rapid Communications, Vol. 22, Issue 10 https://doi.org/10.1002/1521-3927(20010701)22:10<787::AID-MARC787>3.0.CO;2-Y	journal	July 2001
A rapid temperature-responsive sol–gel reversible poly(N-isopropylacrylamide)-g-methylcellulose copolymer hydrogel Liu, Wenguang; Zhang, Bingqi; Lu, William W. Biomaterials, Vol. 25, Issue 15 https://doi.org/10.1016/j.biomaterials.2003.09.077	journal	July 2004
Correlations between the Rayleigh ratio and the wavelength for toluene and benzene Wu, Hua Chemical Physics, Vol. 367, Issue 1 https://doi.org/10.1016/j.chemphys.2009.10.019	journal	January 2010
Thermodynamics of Aqueous Methylcellulose Solutions McAllister, John W.; Schmidt, Peter W.; Dorfman, Kevin D. Macromolecules, Vol. 48, Issue 19 https://doi.org/10.1021/acs.macromol.5b01544	journal	September 2015
Thermogelation of methylcellulose. Part I: molecular structures and processes Haque, Anwarul; Morris, Edwin R. Carbohydrate Polymers, Vol. 22, Issue 3 https://doi.org/10.1016/0144-8617(93)90137-S	journal	January 1993
Cylindrical molecular brushes: Synthesis, characterization, and properties Sheiko, Sergei S.; Sumerlin, Brent S.; Matyjaszewski, Krzysztof Progress in Polymer Science, Vol. 33, Issue 7 https://doi.org/10.1016/j.progpolymsci.2008.05.001	journal	July 2008
Information on Polydispersity and Branching from Combined Quasi-Elastic and Intergrated Scattering Burchard, W.; Schmidt, M.; Stockmayer, W. H. Macromolecules, Vol. 13, Issue 5 https://doi.org/10.1021/ma60077a045	journal	September 1980
Thermoreversible Gelation of Aqueous Methylcellulose Solutions Kobayashi, Kazuto; Huang, Ching-i; Lodge, Timothy P. Macromolecules, Vol. 32, Issue 21 https://doi.org/10.1021/ma990242n	journal	October 1999
Interplay between Gelation and Phase Separation in Aqueous Solutions of Methylcellulose and Hydroxypropylmethylcellulose Fairclough, J. Patrick A.; Yu, Hao; Kelly, Oscar Langmuir, Vol. 28, Issue 28 https://doi.org/10.1021/la300971r	journal	June 2012
Incorporating Intermicellar Interactions in the Fitting of SANS Data from Cationic Wormlike Micelles Chen, Wei-Ren; Butler, Paul D.; Magid, Linda J. Langmuir, Vol. 22, Issue 15 https://doi.org/10.1021/la0530440	journal	July 2006
Structure and Properties of Aqueous Methylcellulose Gels by Small-Angle Neutron Scattering Chatterjee, Tirtha; Nakatani, Alan I.; Adden, Roland Biomacromolecules, Vol. 13, Issue 10 https://doi.org/10.1021/bm301123a	journal	September 2012
Laser Light Scattering Study of the Phase Transition of Poly(N-isopropylacrylamide) in Water. 1. Single Chain Wu, Chi; Zhou, Shuiqin Macromolecules, Vol. 28, Issue 24 https://doi.org/10.1021/ma00128a056	journal	November 1995
Methylcellulose fibrils: a mini review Morozova, Svetlana Polymer International, Vol. 69, Issue 2 https://doi.org/10.1002/pi.5945	journal	November 2019
Solution Properties of Poly(N-isopropylacrylamide) in Water Kubota, Kenji; Fujishige, Shouei; Ando, Isao Polymer Journal, Vol. 22, Issue 1 https://doi.org/10.1295/polymj.22.15	journal	January 1990
Thermoreversible gelation and phase separation in aqueous methyl cellulose solutions Takahashi, Masae; Shimazaki, Masako; Yamamoto, Jun Journal of Polymer Science Part B: Polymer Physics, Vol. 39, Issue 1 https://doi.org/10.1002/1099-0488(20010101)39:1<91::AID-POLB80>3.0.CO;2-C	journal	January 2000
Polymer chain stiffness vs. excluded volume: A Monte Carlo study of the crossover towards the worm-like chain model Hsu, Hsiao-Ping; Paul, Wolfgang; Binder, Kurt EPL (Europhysics Letters), Vol. 92, Issue 2 https://doi.org/10.1209/0295-5075/92/28003	journal	October 2010
Tough and Sustainable Graft Block Copolymer Thermoplastics Zhang, Jiuyang; Li, Tuoqi; Mannion, Alexander M. ACS Macro Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsmacrolett.6b00091	journal	March 2016
Gel-sol transition of methylcellulose Nishinari, Katsuyoshi; Hofmann, Kate E.; Moritaka, Hatsue Macromolecular Chemistry and Physics, Vol. 198, Issue 4 https://doi.org/10.1002/macp.1997.021980423	journal	April 1997
Understanding the Multiple Length Scales Describing the Structure of Bottle-brush Polymers by Monte Carlo Simulation Methods: Understanding the Multiple Length Scales Describing … Hsu, Hsiao-Ping; Paul, Wolfgang; Binder, Kurt Macromolecular Theory and Simulations, Vol. 20, Issue 7 https://doi.org/10.1002/mats.201000092	journal	March 2011
Cellulose modification by polymer grafting: a review Roy, Debashish; Semsarilar, Mona; Guthrie, James T. Chemical Society Reviews, Vol. 38, Issue 7 https://doi.org/10.1039/b808639g	journal	January 2009
Methylcellulose, a Cellulose Derivative with Original Physical Properties and Extended Applications Nasatto, Pauline; Pignon, Frédéric; Silveira, Joana Polymers, Vol. 7, Issue 5 https://doi.org/10.3390/polym7050777	journal	April 2015
Comb-Branched Polymers: Monte Carlo Simulation and Scaling Rouault, Y.; Borisov, O. V. Macromolecules, Vol. 29, Issue 7 https://doi.org/10.1021/ma951126x	journal	January 1996
Fibrillar Structure of Methylcellulose Hydrogels Lott, Joseph R.; McAllister, John W.; Arvidson, Sara A. Biomacromolecules, Vol. 14, Issue 8 https://doi.org/10.1021/bm400694r	journal	July 2013
Network formation in poly(N-isopropyl acrylamide)/water solutions during phase separation Zeng, Fang; Zheng, Xu; Tong, Zhen Polymer, Vol. 39, Issue 5 https://doi.org/10.1016/S0032-3861(97)00471-0	journal	March 1998
Preparation of a Thermosensitive Highly Regioselective Cellulose/ N -Isopropylacrylamide Copolymer through Atom Transfer Radical Polymerization Ifuku, Shinsuke; Kadla, John F. Biomacromolecules, Vol. 9, Issue 11 https://doi.org/10.1021/bm800911w	journal	November 2008
Molecular Weight Dependence of Methylcellulose Fibrillar Networks Schmidt, Peter W.; Morozova, Svetlana; Owens, Paige M. Macromolecules, Vol. 51, Issue 19 https://doi.org/10.1021/acs.macromol.8b01292	journal	September 2018
Studies on sol-gel transformations. I. The inverse sol-gel transformation of methylcellulose in water Heymann, E. Transactions of the Faraday Society, Vol. 31 https://doi.org/10.1039/tf9353100846	journal	January 1935
Phase separation of aqueous solution of methylcellulose Chevillard, C.; Axelos, M. A. V. Colloid & Polymer Science, Vol. 275, Issue 6 https://doi.org/10.1007/s003960050116	journal	June 1997
Reduction and analysis of SANS and USANS data using IGOR Pro Kline, Steven R. Journal of Applied Crystallography, Vol. 39, Issue 6, p. 895-900 https://doi.org/10.1107/S0021889806035059	journal	November 2006
A pilot study of poly(N-isopropylacrylamide)-g-polyethylene glycol and poly(N-isopropylacrylamide)-g-methylcellulose branched copolymers as injectable scaffolds for local delivery of neurotrophins and cellular transplants into the injured spinal cord: Laboratory investigation Conova, Lauren; Vernengo, Jennifer; Jin, Ying Journal of Neurosurgery: Spine, Vol. 15, Issue 6 https://doi.org/10.3171/2011.7.SPINE11194	journal	December 2011
Poly( N -isopropylacrylamide) Phase Diagrams: Fifty Years of Research Halperin, Avraham; Kröger, Martin; Winnik, Françoise M. Angewandte Chemie International Edition, Vol. 54, Issue 51 https://doi.org/10.1002/anie.201506663	journal	November 2015
Thermogelation of methylcellulose: rheological considerations Desbrières, J.; Hirrien, M.; Ross-Murphy, S. B. Polymer, Vol. 41, Issue 7 https://doi.org/10.1016/S0032-3861(99)00413-9	journal	March 2000
Polymer Chemistry Hiemenz, Paul C.; Lodge, Timothy P. CRC Press https://doi.org/10.1201/9781420018271	book	February 2007
Regularized Positive Exponential Sum (REPES) Program - A Way of Inverting Laplace Transform Data Obtained by Dynamic Light Scattering Jakeš, Jaromír Collection of Czechoslovak Chemical Communications, Vol. 60, Issue 11 https://doi.org/10.1135/cccc19951781	journal	January 1995
Grafting Polymers from Cellulose Nanocrystals: Synthesis, Properties, and Applications Wohlhauser, Sandra; Delepierre, Gwendoline; Labet, Marianne Macromolecules, Vol. 51, Issue 16 https://doi.org/10.1021/acs.macromol.8b00733	journal	July 2018
Phase transition of aqueous solutions of poly(N-isopropylacrylamide) and poly(N-isopropylmethacrylamide) Fujishige, Shouei; Kubota, K.; Ando, I. The Journal of Physical Chemistry, Vol. 93, Issue 8 https://doi.org/10.1021/j100345a085	journal	April 1989
2-Hydroxyethylcellulose and Amphiphilic Block Polymer Conjugates Form Mechanically Tunable and Nonswellable Hydrogels Zheng, Jukuan; Jung, Seyoung; Schmidt, Peter W. ACS Macro Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsmacrolett.6b00954	journal	January 2017
Solution Properties of Poly(N-isopropylacrylamide) Heskins, M.; Guillet, J. E. Journal of Macromolecular Science: Part A - Chemistry, Vol. 2, Issue 8 https://doi.org/10.1080/10601326808051910	journal	December 1968

Similar Records

Temperature Dependence of Chain Conformations and Fibril Formation in Solutions of Poly(N-isopropyla

Journal Article · 2021 · Macromolecules · OSTI ID:1844658

Effect of Poly(ethylene glycol) Grafting Density on Methylcellulose Fibril Formation

Journal Article · 2018 · Macromolecules · OSTI ID:1492985

Water Dynamics in Aqueous Poly- N -Isopropylacrylamide Below and Through the Lower Critical Solution Temperature

Journal Article · 2022 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1978001

Related Subjects

Polymer Science

Temperature Dependence of Chain Conformations and Fibril Formation in Solutions of Poly( N -isopropylacrylamide)-Grafted Methylcellulose

Citation Formats

References (61)

Similar Records

Related Subjects