Regularity of Deuteration in Linear Polyethylene Prepared by Saturation of Polycyclopentene over Homogeneous Catalysts

Cho, Seong Hyuk; Pelczer, István; Register, Richard A.

doi:10.1021/acs.macromol.1c01754

Regularity of Deuteration in Linear Polyethylene Prepared by Saturation of Polycyclopentene over Homogeneous Catalysts

Journal Article · 08 November 2021 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c01754· OSTI ID:1981946

Cho, Seong Hyuk ^[1]; ^[2]; ^[1]

Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544, United States
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States

Not provided.

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725;

OSTI ID:: 1981946

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 22 Vol. 54; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (50)

Development of hydrogenated ring-opening metathesis polymers Otsuki, Toshihiro; Goto, Kohei; Komiya, Zen Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue S1 https://doi.org/10.1002/1099-0518(200012)38:1+<4661::aid-pola50>3.0.co;2-k	journal	January 2000
Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido- tris(triphenylphosphine)ruthenium(II) Complex Tse, Sunny Kai San; Xue, Peng; Lin, Zhenyang Advanced Synthesis & Catalysis, Vol. 352, Issue 9, p. 1512-1522 https://doi.org/10.1002/adsc.201000037	journal	May 2010
Prediction of linear viscoelastic response for entangled polyolefin melts from molecular weight distribution Wasserman, Scott H.; Graessley, William W. Polymer Engineering & Science, Vol. 36, Issue 6 https://doi.org/10.1002/pen.10472	journal	March 1996
Isotope Effects on the Crystallization Kinetics of Selectively Deuterated Poly(ε‐Caprolactone) Li, Lengwan; Chang, Dongsook; Arras, Matthias M. L. Journal of Polymer Science Part B: Polymer Physics, Vol. 57, Issue 12 https://doi.org/10.1002/polb.24831	journal	April 2019
Preparation of conjugated soybean oil and other natural oils and fatty acids by homogeneous transition metal catalysis Larock, Richard C.; Dong, Xiaoyang; Chung, Steven Journal of the American Oil Chemists' Society, Vol. 78, Issue 5 https://doi.org/10.1007/s11746-001-0284-1	journal	May 2001
Determination of the conformation of polymers in the amorphous solid state and in concentrated solution by neutron diffraction Kirste, R. Polymer, Vol. 16, Issue 2 https://doi.org/10.1016/0032-3861(75)90140-8	journal	February 1975
Small-angle neutron scattering studies of molten and crystalline polyethylene Schelten, J.; Ballard, D. G. H.; Wignall, G. D. Polymer, Vol. 17, Issue 9 https://doi.org/10.1016/0032-3861(76)90028-8	journal	September 1976
Small-angle neutron scattering studies of molecular clustering in mixtures of polyethylene and deuterated polyethylene Schelten, J.; Wignall, G. D.; Ballard, D. G. H. Polymer, Vol. 18, Issue 11 https://doi.org/10.1016/0032-3861(77)90104-5	journal	November 1977
Small-angle neutron scattering studies of isotropic polypropylene Ballard, D. G. H.; Cheshire, P.; Longman, G. W. Polymer, Vol. 19, Issue 4 https://doi.org/10.1016/0032-3861(78)90241-0	journal	April 1978
Small-angle neutron-scattering studies of partially labelled crystalline polyethylene Crist, Buckley; Nicholson, James C. Polymer, Vol. 35, Issue 9 https://doi.org/10.1016/0032-3861(94)90973-3	journal	January 1994
The isomerization of n-butenes catalyzed by RhCl(PPh3)3-I. The isomerization of 2-butenes Tuner, M.; Jouanne, J. v.; Brauer, H. -D. Journal of Molecular Catalysis, Vol. 5, Issue 6 https://doi.org/10.1016/0304-5102(79)80041-3	journal	June 1979
The isomerization of n-butenes catalyzed by RhCl(PPh3)3. II. The isomerization of 1-butene Tuner, M.; Jouanne, J. v.; Brauer, H. -D. Journal of Molecular Catalysis, Vol. 5, Issue 6 https://doi.org/10.1016/0304-5102(79)80042-5	journal	June 1979
Olefins isomerization by hydride-complexes of ruthenium Yue, Chuan Jun; Liu, Ying; He, Ren Journal of Molecular Catalysis A: Chemical, Vol. 259, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.02.066	journal	November 2006
The role of the functional group in double bond migration in allylic systems catalysed by ruthenium hydride complexes Krompiec, S.; Kuźnik, N.; Krompiec, M. Journal of Molecular Catalysis A: Chemical, Vol. 253, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.03.015	journal	July 2006
Impact of molecular weight and comonomer content on catalytic hydrogen-deuterium exchange in polyolefins Kang, Shuhui; Zeng, Yiming; Lodge, Timothy P. Polymer, Vol. 102 https://doi.org/10.1016/j.polymer.2016.09.012	journal	October 2016
Alternating crystalline lamellar structures from thermodynamically miscible poly(ε-caprolactone) H/D blends Li, Lengwan; Arras, Matthias M. L.; Li, Tianyu Polymer, Vol. 175 https://doi.org/10.1016/j.polymer.2019.05.055	journal	June 2019
Chain arrangements of selectively deuterated poly(ε-caprolactone) copolymers as revealed by neutron scattering Li, Lengwan; Li, Tianyu; Arras, Matthias M. L. Polymer, Vol. 193 https://doi.org/10.1016/j.polymer.2020.122375	journal	April 2020
Highly selective isomerization of N-allylamides and N-allylamines Krompiec, Stanisław; Pigulla, Mariola; Krompiec, Michał Tetrahedron Letters, Vol. 45, Issue 27 https://doi.org/10.1016/j.tetlet.2004.05.023	journal	June 2004
Isotopenaustauschvorgänge bei homogen katalysierten reaktionen—II Bayerl, B.; Wahren, M.; Graefe, J. Tetrahedron, Vol. 29, Issue 13 https://doi.org/10.1016/s0040-4020(01)83209-9	journal	January 1973
Highly selective synthesis of (E)-N-aryl-N-(1-propenyl) ethanamides via isomerization of N-allyl ethanamides catalyzed by ruthenium complexes Krompiec, Stanislaw; Pigulla, Mariola; Szczepankiewicz, Wojciech Tetrahedron Letters, Vol. 42, Issue 40 https://doi.org/10.1016/s0040-4039(01)01457-5	journal	October 2001
Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications Xie, Shuyi; Zhang, Bo; Mao, Yimin Macromolecules, Vol. 53, Issue 16 https://doi.org/10.1021/acs.macromol.0c01194	journal	August 2020
Incorporation of Styrene into a Model Polyolefin for Enhanced Compatibility with Polyisoprene Jangareddy, Sravya; Register, Richard A. Macromolecules, Vol. 53, Issue 20 https://doi.org/10.1021/acs.macromol.0c01781	journal	October 2020
Molecular Weight Dependence of Deuterium Exchange on Polyethylene: Direct Measurement and SANS Model Habersberger, Brian M.; Hart, Kyle E.; Gillespie, David Macromolecules, Vol. 48, Issue 16 https://doi.org/10.1021/acs.macromol.5b01075	journal	August 2015
Effect of Branching and Molecular Weight on Heterogeneous Catalytic Deuterium Exchange in Polyolefins Zeng, Yiming; López-Barrón, Carlos R.; Kang, Shuhui Macromolecules, Vol. 50, Issue 17 https://doi.org/10.1021/acs.macromol.7b01268	journal	August 2017
Solvent and Polymer Stereochemistry Play Key Roles in Deuterium Exchange and Partial Racemization of Polypropylenes Habersberger, Brian M.; Baugh, Daniel W. Macromolecules, Vol. 51, Issue 4 https://doi.org/10.1021/acs.macromol.7b02633	journal	February 2018
Selectively Deuterated Poly(ε-caprolactone)s: Synthesis and Isotope Effects on the Crystal Structures and Properties Chang, Dongsook; Li, Tianyu; Li, Lengwan Macromolecules, Vol. 51, Issue 22 https://doi.org/10.1021/acs.macromol.8b01851	journal	November 2018
Synthesis of Narrow-Distribution, High-Molecular-Weight ROMP Polycyclopentene via Suppression of Acyclic Metathesis Side Reactions Mulhearn, William D.; Register, Richard A. ACS Macro Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsmacrolett.6b00969	journal	January 2017
Observation of New Intermediates in Hydrogenation Catalyzed by Wilkinson's Catalyst, RhCl(PPh3)3, Using Parahydrogen-Induced Polarization Duckett, Simon B.; Newell, Connie L.; Eisenberg, Richard Journal of the American Chemical Society, Vol. 116, Issue 23 https://doi.org/10.1021/ja00102a023	journal	November 1994
Isomerization Reaction of Olefin Using RuClH(CO)(PPh ₃ ) ₃ Wakamatsu, Hideaki; Nishida, Mayumi; Adachi, Naoko The Journal of Organic Chemistry, Vol. 65, Issue 13 https://doi.org/10.1021/jo9918753	journal	June 2000
A Study of Deuterium Distribution in Deuterated Polyolefins by Pyrolysis−Photoionization Mass Spectrometry Zoller, David L.; Johnston, Murray V.; Qian, Kuangnan Macromolecules, Vol. 33, Issue 15 https://doi.org/10.1021/ma000049p	journal	July 2000
Thermodynamic interactions in model polyolefin blends obtained by small-angle neutron scattering Balsara, N. P.; Fetters, L. J.; Hadjichristidis, N. Macromolecules, Vol. 25, Issue 23 https://doi.org/10.1021/ma00049a009	journal	November 1992
Synthesis of Narrow-Distribution “Perfect” Polyethylene and Its Block Copolymers by Polymerization of Cyclopentene Trzaska, Scott T.; Lee, Li-Bong W.; Register, Richard A. Macromolecules, Vol. 33, Issue 25 https://doi.org/10.1021/ma0012649	journal	November 2000
Effect of Nonuniform Deuterium Labeling on Small-Angle Neutron Scattering Results for Polymer Blends Reichart, Glenn C.; Register, Richard A.; Graessley, William W. Macromolecules, Vol. 28, Issue 26 https://doi.org/10.1021/ma00130a021	journal	December 1995
Block copolymers near the microphase separation transition. 1. Preparation and physical characterization of a model system Bates, Frank S.; Bair, H. E.; Hartney, M. A. Macromolecules, Vol. 17, Issue 10 https://doi.org/10.1021/ma00140a019	journal	October 1984
Dimensions of polymer chains in the semicrystalline solid state Tanzer, J. D.; Bartels, Craig R.; Crist, Buckley Macromolecules, Vol. 17, Issue 12 https://doi.org/10.1021/ma00142a046	journal	December 1984
Microstructure determination of nondeuterated, partially deuterated, and perdeuterated polybutadienes with cis-1,4, trans-1,4, and vinyl-1,2 units by carbon-13 NMR Van der Velden, Geert P. M.; Fetters, Lew J. Macromolecules, Vol. 23, Issue 9 https://doi.org/10.1021/ma00211a011	journal	April 1990
Solvent Selective Hydrogen–Deuterium Exchange on Saturated Polyolefins Habersberger, Brian M.; Lodge, Timothy P.; Bates, Frank S. Macromolecules, Vol. 45, Issue 19 https://doi.org/10.1021/ma301814n	journal	September 2012
Conformation of Polymer Chain in the Bulk Cotton, J. P.; Decker, D.; Benoit, H. Macromolecules, Vol. 7, Issue 6 https://doi.org/10.1021/ma60042a033	journal	November 1974
Pure Component Properties and Mixing Behavior in Polyolefin Blends Krishnamoorti, Ramanan; Graessley, William W.; Dee, Gregory T. Macromolecules, Vol. 29, Issue 1 https://doi.org/10.1021/ma950754b	journal	January 1996
Thermodynamics of Mixing for Statistical Copolymers of Ethylene and α-Olefins Reichart, Glenn C.; Graessley, William W.; Register, Richard A. Macromolecules, Vol. 31, Issue 22 https://doi.org/10.1021/ma980906d	journal	October 1998
Catalytic synthesis and post-polymerization functionalization of conjugated polyisoprene Gramlich, William M.; Hillmyer, Marc A. Polymer Chemistry, Vol. 2, Issue 9 https://doi.org/10.1039/c1py00147g	journal	January 2011
Chain conformation in the crystalline state by means of neutron scattering methods Stamm, Manfred; Fischer, Erhard W.; Dettenmaier, Manfred Faraday Discussions of the Chemical Society, Vol. 68 https://doi.org/10.1039/dc9796800263	journal	January 1979
Hydroisomerization of olefins catalyzed by tris(triphenylphosphine)rhodium (I) halides Bond, G. C.; Hillyard, R. A. Discussions of the Faraday Society, Vol. 46 https://doi.org/10.1039/df9684600020	journal	January 1968
Homogeneous catalysis of olefin isomerisation. Part V. Pent-1-ene isomerisation catalysed by solutions of RuHCl(PPh3)3 and of RuHCl(CO)(PPh3)3; variation of the isomeric composition of pent-2-ene and its attribution to steric factors Bingham, Denis; Webster, David E.; Wells, Peter B. Journal of the Chemical Society, Dalton Transactions, Issue 14 https://doi.org/10.1039/dt9740001519	journal	January 1974
The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives Osborn, J. A.; Jardine, F. H.; Young, J. F. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/j19660001711	journal	January 1966
Isotope and microstructure interactions in blends of random copolymers Rhee, Jangweon; Crist, Buckley The Journal of Chemical Physics, Vol. 98, Issue 5 https://doi.org/10.1063/1.465025	journal	March 1993
Small‐angle neutron scattering by partially deuterated polymers and their blends Balsara, N. P.; Lohse, D. J.; Graessley, W. W. The Journal of Chemical Physics, Vol. 100, Issue 5 https://doi.org/10.1063/1.466325	journal	March 1994
Hydrogen–deuterium exchange of medium ring cycloalkenes during deuterogenation with tris(triphenylphosphine)chlororhodium(I) Atkinson, J. G.; Luke, M. O. Canadian Journal of Chemistry, Vol. 48, Issue 22 https://doi.org/10.1139/v70-599	journal	November 1970
Hydrogenation of Ring-Opening Metathesis Polymer with Ruthenium Catalysts Yoshida, Yoshinori; Yoshinari, Masashi; Iio, Akira Polymer Journal, Vol. 30, Issue 10 https://doi.org/10.1295/polymj.30.819	journal	October 1998
Transition Metals for Conjugation of Polyunsaturated Acids and their Esters Krompiec, S.; Penczek, R.; Krompiec, M. Current Organic Chemistry, Vol. 13, Issue 9 https://doi.org/10.2174/138527209788452117	journal	June 2009

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