Coexistence and Phase Behavior of Solvent–Polystyrene-Grafted Gold Nanoparticle Systems

Izor, Sarah; Schantz, Allen; Jawaid, Ali; Grabowski, Chris; Dagher, Tony; Koerner, Hilmar; Park, Kyoungweon; Vaia, Richard

doi:10.1021/acs.macromol.1c01714

Coexistence and Phase Behavior of Solvent–Polystyrene-Grafted Gold Nanoparticle Systems

Journal Article · 19 October 2021 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c01714· OSTI ID:1981945

Izor, Sarah ^[1]; Schantz, Allen ^[2]; Jawaid, Ali ^[1]; Grabowski, Chris ^[2]; Dagher, Tony ^[2]; Koerner, Hilmar ^[2]; ^[1]; ^[2]

Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433-7702, United States; UES, Inc., Dayton, Ohio 45432, United States
Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433-7702, United States

Not provided.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012704

OSTI ID:: 1981945

Journal Information:: Macromolecules, Vol. 54, Issue 22; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (71)

50th Anniversary Perspective : Are Polymer Nanocomposites Practical for Applications? Kumar, Sanat K.; Benicewicz, Brian C.; Vaia, Richard A. Macromolecules, Vol. 50, Issue 3 https://doi.org/10.1021/acs.macromol.6b02330	journal	January 2017
Hairy nanoparticle assemblies as one-component functional polymer nanocomposites: opportunities and challenges Fernandes, Nikhil J.; Koerner, Hilmar; Giannelis, Emmanuel P. MRS Communications, Vol. 3, Issue 1 https://doi.org/10.1557/mrc.2013.9	journal	March 2013
Projectile Impact Shock-Induced Deformation of One-Component Polymer Nanocomposite Thin Films Hyon, Jinho; Gonzales, Manny; Streit, Jason K. ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c06146	journal	January 2021
Performance of Dielectric Nanocomposites: Matrix-Free, Hairy Nanoparticle Assemblies and Amorphous Polymer–Nanoparticle Blends Grabowski, Christopher A.; Koerner, Hilmar; Meth, Jeffrey S. ACS Applied Materials & Interfaces, Vol. 6, Issue 23 https://doi.org/10.1021/am506521r	journal	November 2014
A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles Choudhury, Snehashis; Mangal, Rahul; Agrawal, Akanksha Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms10101	journal	December 2015
Preparation of Ordered Monolayers of Polymer Grafted Nanoparticles: Impact of Architecture, Concentration, and Substrate Surface Energy Che, Justin; Park, Kyoungweon; Grabowski, Christopher A. Macromolecules, Vol. 49, Issue 5 https://doi.org/10.1021/acs.macromol.5b02722	journal	February 2016
Preparation and Optical Properties of Indium Tin Oxide/Epoxy Nanocomposites with Polyglycidyl Methacrylate Grafted Nanoparticles Tao, Peng; Viswanath, Anand; Schadler, Linda S. ACS Applied Materials & Interfaces, Vol. 3, Issue 9 https://doi.org/10.1021/am200841n	journal	August 2011
“Gel-like” Mechanical Reinforcement in Polymer Nanocomposite Melts Akcora, Pinar; Kumar, Sanat K.; Moll, Joseph Macromolecules, Vol. 43, Issue 2 https://doi.org/10.1021/ma902072d	journal	January 2010
Deformation Behavior of Polystyrene-Grafted Nanoparticle Assemblies with Low Grafting Density Jiao, Yang; Tibbits, Andrew; Gillman, Andrew Macromolecules, Vol. 51, Issue 18 https://doi.org/10.1021/acs.macromol.8b01524	journal	September 2018
Uniaxial Deformation and Crazing in Glassy Polymer-Grafted Nanoparticle Ultrathin Films Ethier, Jeffrey G.; Drummy, Lawrence F.; Vaia, Richard A. ACS Nano, Vol. 13, Issue 11 https://doi.org/10.1021/acsnano.9b05001	journal	October 2019
Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids Kumar, Sanat K.; Ganesan, Venkat; Riggleman, Robert A. The Journal of Chemical Physics, Vol. 147, Issue 2 https://doi.org/10.1063/1.4990501	journal	July 2017
Tuning Hierarchical Order and Plasmonic Coupling of Large-Area, Polymer-Grafted Gold Nanorod Assemblies via Flow-Coating Streit, Jason K.; Park, Kyoungweon; Ku, Zahyun ACS Applied Materials & Interfaces, Vol. 13, Issue 23 https://doi.org/10.1021/acsami.1c05262	journal	June 2021
Interaction Between Polymer Brush-Coated Spherical Nanoparticles: Effect of Solvent Quality LoVerso, Federica; Egorov, Sergei A.; Binder, Kurt Macromolecules, Vol. 45, Issue 21 https://doi.org/10.1021/ma301651z	journal	October 2012
Star Polymers in Solvents of Varying Quality Huissmann, Sebastian; Blaak, Ronald; Likos, Christos N. Macromolecules, Vol. 42, Issue 7 https://doi.org/10.1021/ma8023359	journal	March 2009
Effect of the solvent quality on the structural rearrangement of spherical brushes: coarse-grained models Lo Verso, Federica; Yelash, Leonid; Egorov, Sergei A. Soft Matter, Vol. 8, Issue 15 https://doi.org/10.1039/c2sm06836b	journal	January 2012
Impact of the Distributions of Core Size and Grafting Density on the Self-Assembly of Polymer Grafted Nanoparticles Bachhar, Nirmalya; Jiao, Yang; Asai, Makoto Macromolecules, Vol. 50, Issue 19 https://doi.org/10.1021/acs.macromol.7b01093	journal	September 2017
Mechanical Properties of Thin Glassy Polymer Films Filled with Spherical Polymer-Grafted Nanoparticles Maillard, Damien; Kumar, Sanat K.; Fragneaud, Benjamin Nano Letters, Vol. 12, Issue 8 https://doi.org/10.1021/nl301792g	journal	July 2012
Effect of solvent quality on the dispersibility of polymer-grafted spherical nanoparticles in polymer solutions Egorov, S. A.; Binder, K. The Journal of Chemical Physics, Vol. 137, Issue 9 https://doi.org/10.1063/1.4747196	journal	September 2012
Nonisotropic Self-Organization of Single-Component Hairy Nanoparticle Assemblies Koerner, Hilmar; Drummy, Lawrence F.; Benicewicz, Brian ACS Macro Letters, Vol. 2, Issue 8 https://doi.org/10.1021/mz4001805	journal	July 2013
Structure and Entanglement Network of Model Polymer-Grafted Nanoparticle Monolayers Ethier, Jeffrey G.; Hall, Lisa M. Macromolecules, Vol. 51, Issue 23 https://doi.org/10.1021/acs.macromol.8b01373	journal	November 2018
Effect of Polymer-Graft Modification on the Order Formation in Particle Assembly Structures Choi, Jihoon; Hui, Chin Ming; Schmitt, Michael Langmuir, Vol. 29, Issue 21 https://doi.org/10.1021/la4004406	journal	May 2013
Modeling the Morphology and Phase Behavior of One-Component Polymer-Grafted Nanoparticle Systems Ginzburg, Valeriy V. Macromolecules, Vol. 50, Issue 23 https://doi.org/10.1021/acs.macromol.7b01922	journal	November 2017
Size-Selective Organization of Enthalpic Compatibilized Nanocrystals in Ternary Block Copolymer/Particle Mixtures Bockstaller, Michael R.; Lapetnikov, Yonit; Margel, Shlomo Journal of the American Chemical Society, Vol. 125, Issue 18 https://doi.org/10.1021/ja034523t	journal	May 2003
Temperature-Responsive Self-Assembly of Nanoparticles Grafted with UCST Polymer Ligands Tao, Huachen; Galati, Elizabeth; Kumacheva, Eugenia Macromolecules, Vol. 51, Issue 15 https://doi.org/10.1021/acs.macromol.8b01058	journal	August 2018
Tunable Assembly of Gold Nanorods in Polymer Solutions To Generate Controlled Nanostructured Materials Poling-Skutvik, Ryan; Lee, Jonghun; Narayanan, Suresh ACS Applied Nano Materials, Vol. 1, Issue 2 https://doi.org/10.1021/acsanm.7b00277	journal	January 2018
Theory of the grafted polymer brush Milner, S. T.; Witten, T. A.; Cates, M. E. Macromolecules, Vol. 21, Issue 8 https://doi.org/10.1021/ma00186a051	journal	August 1988
Polymer brushes at curved surfaces Wijmans, C. M.; Zhulina, E. B. Macromolecules, Vol. 26, Issue 26 https://doi.org/10.1021/ma00078a016	journal	December 1993
Suspensions of Silica Particles Grafted with Concentrated Polymer Brush: Effects of Graft Chain Length on Brush Layer Thickness and Colloidal Crystallization Ohno, Kohji; Morinaga, Takashi; Takeno, Satoshi Macromolecules, Vol. 40, Issue 25 https://doi.org/10.1021/ma071770z	journal	December 2007
Conformational Transitions of Spherical Polymer Brushes: Synthesis, Characterization, and Theory Dukes, Douglas; Li, Yu; Lewis, Sarah Macromolecules, Vol. 43, Issue 3 https://doi.org/10.1021/ma901228t	journal	February 2010
Distribution in the Grafting Density of End-Functionalized Polymer Chains Adsorbed onto Nanoparticle Surfaces Oyerokun, Folusho T.; Vaia, Richard A. Macromolecules, Vol. 45, Issue 18 https://doi.org/10.1021/ma301218d	journal	September 2012
Formation and Structure of Self-Assembled Monolayers Ulman, Abraham Chemical Reviews, Vol. 96, Issue 4, p. 1533-1554 https://doi.org/10.1021/cr9502357	journal	January 1996
Surface Chemistry of Gold Nanorods Burrows, Nathan D.; Lin, Wayne; Hinman, Joshua G. Langmuir, Vol. 32, Issue 39 https://doi.org/10.1021/acs.langmuir.6b02706	journal	September 2016
Role of Solvent Selectivity in the Equilibrium Surface Composition of Monolayers Formed from a Solution Containing Mixtures of Organic Thiols Oyerokun, Folusho T.; Vaia, Richard A.; Maguire, John F. Langmuir, Vol. 26, Issue 14 https://doi.org/10.1021/la101464j	journal	June 2010
Optical absorption spectra of pairs of small metal particles Quinten, M.; Kreibig, U.; Schönauer, D. Surface Science, Vol. 156 https://doi.org/10.1016/0039-6028(85)90244-4	journal	June 1985
Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications Ghosh, Sujit Kumar; Pal, Tarasankar Chemical Reviews, Vol. 107, Issue 11 https://doi.org/10.1021/cr0680282	journal	November 2007
X-ray Form Factor, Attenuation and Scattering Tables, NIST Standard Reference Database 66 Seltzer, Stephen National Institute of Standards and Technology https://doi.org/10.18434/T4HS32	dataset	January 1995
Analysis of small-angle scattering data from colloids and polymer solutions: modeling and least-squares fitting Pedersen, Jan Skov Advances in Colloid and Interface Science, Vol. 70 https://doi.org/10.1016/S0001-8686(97)00312-6	journal	July 1997
Phase Transitions of the Lennard-Jones System Hansen, Jean-Pierre; Verlet, Loup Physical Review, Vol. 184, Issue 1 https://doi.org/10.1103/PhysRev.184.151	journal	August 1969
The Scherrer equation and the dynamical theory of X-ray diffraction Muniz, Francisco Tiago Leitão; Miranda, Marcus Aurélio Ribeiro; Morilla dos Santos, Cássio Acta Crystallographica Section A Foundations and Advances, Vol. 72, Issue 3 https://doi.org/10.1107/S205327331600365X	journal	April 2016
Phase diagram of spherical particles interacted with harmonic repulsions Zhu, You-Liang; Lu, Zhong-Yuan The Journal of Chemical Physics, Vol. 134, Issue 4 https://doi.org/10.1063/1.3548886	journal	January 2011
Nanoparticle Superlattices: The Roles of Soft Ligands Si, Kae Jye; Chen, Yi; Shi, Qianqian Advanced Science, Vol. 5, Issue 1 https://doi.org/10.1002/advs.201700179	journal	September 2017
Depletion-Induced Shape and Size Selection of Gold Nanoparticles Park, Kyoungweon; Koerner, Hilmar; Vaia, Richard A. Nano Letters, Vol. 10, Issue 4 https://doi.org/10.1021/nl100345u	journal	April 2010
Phase Equilibria in Polymer—Solvent Systems ^1,2 Shultz, A. R.; Flory, P. J. Journal of the American Chemical Society, Vol. 74, Issue 19 https://doi.org/10.1021/ja01139a010	journal	October 1952
Light Scattering and Phase Separation Studies on Cyclohexane Solutions of Six-Arm Star Polystyrene† Tasaka, Yoshiko; Okumoto, Mitsuhiro; Nakamura, Yo Polymer Journal, Vol. 40, Issue 7 https://doi.org/10.1295/polymj.PJ2008017	journal	May 2008
Concentration and Solvency Effects on the Pair Interaction between Colloidal Particles in a Solution of Nonadsorbing Polymer Tuinier, Remco; Fleer, Gerard J. Macromolecules, Vol. 37, Issue 23 https://doi.org/10.1021/ma048571p	journal	November 2004
Upper and Lower Critical Solution Temperatures in Polystyrene Solutions. II Saeki, S.; Kuwahara, N.; Konno, S. Macromolecules, Vol. 6, Issue 4 https://doi.org/10.1021/ma60034a024	journal	July 1973
Liquid–Liquid Demixing from Solutions of Polystyrene. 1. A Review. 2. Improved Correlation with Solvent Properties Imre, Attila; Van Hook, W. Alexander Journal of Physical and Chemical Reference Data, Vol. 25, Issue 2 https://doi.org/10.1063/1.555980	journal	March 1996
Critical amplitude scaling laws for polymer solutions Sanchez, Isaac C. The Journal of Physical Chemistry, Vol. 93, Issue 19 https://doi.org/10.1021/j100356a021	journal	September 1989
Universal size ratios of Gaussian polymers with complex architecture: radius of gyration vs hydrodynamic radius Haydukivska, Khristine; Blavatska, Viktoria; Paturej, Jarosław Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-70649-z	journal	August 2020
Rapid turbidimetric determinations of θ-conditions Cornet, C. F.; van Ballegooijen, H. Polymer, Vol. 7, Issue 6 https://doi.org/10.1016/0032-3861(66)90079-6	journal	June 1966
Phase Equilibria in Polymer—Solvent Systems. II. Thermodynamic Interaction Parameters from Critical Miscibility Data ¹ Shultz, A. R.; Flory, P. J. Journal of the American Chemical Society, Vol. 75, Issue 16 https://doi.org/10.1021/ja01112a005	journal	August 1953
Coexistence curve for polystyrene–cyclohexane near the critical point Nakata, Mitsuo; Kuwahara, Nobuhiro; Kaneko, Motozo The Journal of Chemical Physics, Vol. 62, Issue 11 https://doi.org/10.1063/1.430349	journal	June 1975
Coexistence curve and diameter of polystyrene in cyclohexane Nakata, M.; Dobashi, T.; Kuwahara, N. Physical Review A, Vol. 18, Issue 6 https://doi.org/10.1103/PhysRevA.18.2683	journal	December 1978
Phase equilibrium study of the ternary system composed of two monodisperse polystyrenes and cyclohexane Hashizume, J.; Teramoto, A.; Fujita, H. Journal of Polymer Science: Polymer Physics Edition, Vol. 19, Issue 9 https://doi.org/10.1002/pol.1981.180190913	journal	September 1981
Phase Equilibrium of the Ternary System Consisting of Two Monodisperse Polystyrenes and Cyclohexane Tsuyumoto, Michio; Einaga, Yoshiyuki; Fujita, Hiroshi Polymer Journal, Vol. 16, Issue 3 https://doi.org/10.1295/polymj.16.229	journal	March 1984
Upper and Lower Critical Solution Temperatures in Polystyrene Solutions Saeki, S.; Kuwahara, N.; Konno, S. Macromolecules, Vol. 6, Issue 2 https://doi.org/10.1021/ma60032a020	journal	March 1973
Light-Scattering and Phase-Separation Studies on Cyclohexane Solutions of Four-Arm Star Polystyrene Terao, Ken; Okumoto, Mitsuhiro; Nakamura, Yo Macromolecules, Vol. 31, Issue 20 https://doi.org/10.1021/ma980839n	journal	September 1998
Residual 3-Body Interactions of a θ-Polymer: Star Polymers Batoulis, J.; Kremer, K. Europhysics Letters (EPL), Vol. 7, Issue 8 https://doi.org/10.1209/0295-5075/7/8/003	journal	December 1988
Impact of Branching on the Phase Behavior of Polymers Arya, Gaurav; Panagiotopoulos, Athanassios Z. Macromolecules, Vol. 38, Issue 25 https://doi.org/10.1021/ma0515376	journal	November 2005
Self-Assembly and Critical Solubility Temperature of Supramolecular Polystyrene Bottle-Brushes in Cyclohexane Catrouillet, Sylvain; Bouteiller, Laurent; Nicol, Erwan Macromolecules, Vol. 48, Issue 5 https://doi.org/10.1021/ma5024022	journal	February 2015
The surface energy of metals Vitos, L.; Ruban, A. V.; Skriver, H. L. Surface Science, Vol. 411, Issue 1-2 https://doi.org/10.1016/S0039-6028(98)00363-X	journal	August 1998
Study of the surface tension of polymer solutions: theory and experiments in theta solvent conditions di Meglio, J. M.; Ober, R.; Paz, L. Journal de Physique, Vol. 44, Issue 9 https://doi.org/10.1051/jphys:019830044090103500	journal	January 1983
Theoretical prediction of the elastic contribution to steric stabilization Evans, R.; Smitham, J. B.; Napper, D. H. Colloid and Polymer Science, Vol. 255, Issue 2 https://doi.org/10.1007/BF01777275	journal	February 1977
A New Theoretical Approach to the Problem of Solution Behavior of Branched Polymers Candau, F.; Rempp, P.; Benoit, H. Macromolecules, Vol. 5, Issue 5 https://doi.org/10.1021/ma60029a019	journal	September 1972
Star-branched polymers. 5. The .theta. temperature depression for 8- and 12-arm polyisoprenes in dioxane Bauer, B. J.; Hadjichristidis, N.; Fetters, L. J. Journal of the American Chemical Society, Vol. 102, Issue 7 https://doi.org/10.1021/ja00527a045	journal	March 1980
Synthesis and solution properties of comb polystyrenes Roovers, J. E. L. Polymer, Vol. 16, Issue 11 https://doi.org/10.1016/0032-3861(75)90115-9	journal	November 1975
Dilute-solution properties of arborescent polystyrenes: further evidence for perturbed-hard-sphere behavior Striolo, A.; Prausnitz, J. M.; Bertucco, A. Polymer, Vol. 42, Issue 6 https://doi.org/10.1016/S0032-3861(00)00625-X	journal	March 2001
Temperature-Induced Fractionation of a Quasi-Binary Self-Associating Polymer Solution. A Phase Behavior and Polymer Self-Diffusion Investigation Joabsson, Fredrik; Nydén, Magnus; Thuresson, Krister Macromolecules, Vol. 33, Issue 18 https://doi.org/10.1021/ma991783f	journal	August 2000
Designing Algorithms To Aid Discovery by Chemical Robots Henson, Alon B.; Gromski, Piotr S.; Cronin, Leroy ACS Central Science, Vol. 4, Issue 7 https://doi.org/10.1021/acscentsci.8b00176	journal	July 2018
Deep learning for molecular design—a review of the state of the art Elton, Daniel C.; Boukouvalas, Zois; Fuge, Mark D. Molecular Systems Design & Engineering, Vol. 4, Issue 4 https://doi.org/10.1039/C9ME00039A	journal	January 2019
Deep Learning of Binary Solution Phase Behavior of Polystyrene Ethier, Jeffrey G.; Casukhela, Rohan K.; Latimer, Joshua J. ACS Macro Letters, Vol. 10, Issue 6 https://doi.org/10.1021/acsmacrolett.1c00117	journal	May 2021

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