Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Investigation of Multilayered Structures of Ionic Liquids on Graphite and Platinum Using Atomic Force Microscopy and Molecular Simulations

Journal Article · · Langmuir
 [1];  [2];  [3];  [3];  [3];  [1];  [3];  [4];  [1]
  1. McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States
  2. Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, United States; Materials Science and Engineering Program, The University of Texas at Austin, Austin, Texas 78712, United States
  3. Department of Chemical and Biomolecular Engineering, Vanderbilt University, Nashville, Tennessee 37235, United States
  4. Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, United States; Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States

Not provided.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1981941
Journal Information:
Langmuir, Vol. 38, Issue 13; ISSN 0743-7463
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (57)

Electrochemical properties of novel ionic liquids for electric double layer capacitor applications journal September 2004
Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies journal December 2009
Effect and mechanism of additives for ionic liquids as new lubricants journal April 2007
Ionic Liquids in Tribology journal June 2009
Recent Advances in Nanotribology of Ionic Liquids journal May 2021
Ionic Liquids for CO 2 Capture and Emission Reduction journal December 2010
Recyclability of Encapsulated Ionic Liquids for Post-Combustion CO 2 Capture journal March 2019
Influence of Water on the Electrified Ionic Liquid/Solid Interface: A Direct Observation of the Transition from a Multilayered Structure to a Double-Layer Structure journal April 2016
Interfacial Structure of Room-Temperature Ionic Liquids at the Solid–Liquid Interface as Probed by Sum Frequency Generation Spectroscopy journal December 2012
Sum Frequency Generation Spectroscopy Study of an Ionic Liquid at a Graphene-BaF 2 (111) Interface journal May 2014
Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface journal October 2008
Surface characterization of imidazolium ionic liquids by high-resolution Rutherford backscattering spectroscopy and X-ray photoelectron spectroscopy journal February 2010
Photoelectron Spectroscopy of Ionic Liquid-Based Interfaces journal September 2010
Nano-mechanics of ionic liquids at dielectric and metallic interfaces journal January 2018
The Effect of Water and Confinement on Self-Assembly of Imidazolium Based Ionic Liquids at Mica Interfaces journal July 2016
Toward the Microscopic Identification of Anions and Cations at the Ionic Liquid|Ag(111) Interface: A Combined Experimental and Theoretical Investigation journal August 2013
Interaction of a Self-Assembled Ionic Liquid Layer with Graphite(0001): A Combined Experimental and Theoretical Study journal January 2016
Heats of Vaporization of Room Temperature Ionic Liquids by Tunable Vacuum Ultraviolet Photoionization journal January 2010
Structure in Confined Room-Temperature Ionic Liquids journal April 2007
Resolving Fine Structures of the Electric Double Layer of Electrochemical Interfaces in Ionic Liquids with an AFM Tip Modification Strategy journal October 2014
Insight into the Electrical Double Layer of Ionic Liquids Revealed through Its Temporal Evolution journal November 2020
Dynamic and Structural Properties of Room-Temperature Ionic Liquids near Silica and Carbon Surfaces journal July 2013
Effect of π–π+ Stacking on the Layering of Ionic Liquids Confined to an Amorphous Carbon Surface journal March 2015
Evidence of Extended Solidlike Layering in [Bmim][NTf2] Ionic Liquid Thin Films at Room-Temperature journal May 2009
Direct observation of layered structures at ionic liquid/solid interfaces by using frequency-modulation atomic force microscopy journal January 2010
Bias-Dependent Molecular-Level Structure of Electrical Double Layer in Ionic Liquid on Graphite journal November 2013
Fundamental aspects of electric double layer force-distance measurements at liquid-solid interfaces using atomic force microscopy journal September 2016
AFM and STM Studies on the Surface Interaction of [BMP]TFSA and [EMIm]TFSA Ionic Liquids with Au(111) journal July 2009
Double Layer Structure of Ionic Liquids at the Au(111) Electrode Interface: An Atomic Force Microscopy Investigation journal March 2011
Effect of alkyl chain length and anion species on the interfacial nanostructure of ionic liquids at the Au(111)–ionic liquid interface as a function of potential journal January 2013
Probing the neutral graphene–ionic liquid interface: insights from molecular dynamics simulations journal January 2012
Molecular dynamics simulation of the electrochemical interface between a graphite surface and the ionic liquid [BMIM][PF6] journal January 2009
Ordering layers of [bmim][PF6] ionic liquid on graphite surfaces: Molecular dynamics simulation journal April 2008
Temperature Effects on the Capacitance of an Imidazolium-based Ionic Liquid on a Graphite Electrode: A Molecular Dynamics Simulation journal July 2014
Structural Exploration of Multilayered Ionic Liquid/Ag Electrode Interfaces by Atomic Force Microscopy and Surface‐Enhanced Raman Spectroscopy journal December 2020
Characterization of the Interface Structure of 1-Ethyl-2,3-alkylimidazolium Bis(trifluoromethylsulfonyl)imide on a Au(111) Surface with Molecular Dynamics Simulations journal April 2021
Double Layer of Au(100)/Ionic Liquid Interface and Its Stability in Imidazolium-Based Ionic Liquids journal June 2009
Enhancing Pt/C Catalysts for the Oxygen Reduction Reaction with Protic Ionic Liquids: The Effect of Anion Structure journal January 2017
The Activity Enhancement Effect of Ionic Liquids on Oxygen Reduction Reaction Catalysts: From Rotating Disk Electrode to Membrane Electrode Assembly journal August 2021
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts journal October 2010
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces journal February 2014
Emerging Applications of Solid Catalysts with Ionic Liquid Layer Concept in Electrocatalysis journal May 2021
VMD: Visual molecular dynamics journal February 1996
Conductor-like Screening Model for Real Solvents: A New Approach to the Quantitative Calculation of Solvation Phenomena journal February 1995
The Influence of Anion Shape on the Electrical Double Layer Microstructure and Capacitance of Ionic Liquids-Based Supercapacitors by Molecular Simulations journal February 2017
Molecular Force Field for Ionic Liquids Composed of Triflate or Bistriflylimide Anions journal October 2004
A Second Generation Force Field for the Simulation of Proteins, Nucleic Acids, and Organic Molecules journal May 1995
Accurate Simulation of Surfaces and Interfaces of Face-Centered Cubic Metals Using 12−6 and 9−6 Lennard-Jones Potentials journal October 2008
GROMACS 4:  Algorithms for Highly Efficient, Load-Balanced, and Scalable Molecular Simulation journal February 2008
Canonical sampling through velocity rescaling journal January 2007
Self-consistent molecular dynamics formulation for electric-field-mediated electrolyte transport through nanochannels journal July 2007
Ewald summation for systems with slab geometry journal August 1999
Pronounced Structure in Confined Aprotic Room-Temperature Ionic Liquids journal May 2009
Self-assembly in the electrical double layer of ionic liquids journal January 2011
Characterizing the Influence of Water on Charging and Layering at Electrified Ionic-Liquid/Solid Interfaces journal July 2015
The Role of Adsorbed Ions during Electrocatalysis in Ionic Liquids journal March 2014
Oxygen Reduction Reaction at Three-Phase Interfaces journal July 2010