Thermochemistry of 3D and 2D Rare Earth Oxychlorides (REOCls)

Yang, Shuhao; Anderko, Andrzej; Riman, Richard E.; Navrotsky, Alexandra

doi:10.1021/acs.inorgchem.2c00763

Thermochemistry of 3D and 2D Rare Earth Oxychlorides (REOCls)

Journal Article · 29 April 2022 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.2c00763· OSTI ID:1981863

^[1]; ^[2]; ^[3]; ^[4]

Navrotsky Eyring Center for Materials of the Universe, School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, United States; Department of Chemistry, University of California, Davis, California 95616, United States
OLI Systems, Inc., Parsippany, New Jersey 07054, United States
Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, United States
Navrotsky Eyring Center for Materials of the Universe, School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, United States

Not provided.

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States). Critical Materials Institute (CMI)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-07CH11358

OSTI ID:: 1981863

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 19 Vol. 61; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (53)

Thermochemistry of stoichiometric rare earth oxyfluorides REOF Yang, Shuhao; Anderko, Andre; Riman, Richard E. Journal of the American Ceramic Society, Vol. 105, Issue 2 https://doi.org/10.1111/jace.18126	journal	September 2021
Oxychloride–Hydroxychloride–Trihydroxide Phase Relationships of Rare Earths in Aqueous Solution Lee, Byung-Il; Jeong, Heejin; Byeon, Song-Ho Inorganic Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/ic500403v	journal	April 2014
Electrospinning Derived One-Dimensional LaOCl: Ln3+ (Ln = Eu/Sm, Tb, Tm) Nanofibers, Nanotubes and Microbelts with Multicolor-Tunable Emission Properties Li, Guogang; Hou, Zhiyao; Peng, Chong Advanced Functional Materials, Vol. 20, Issue 20 https://doi.org/10.1002/adfm.201001114	journal	August 2010
Thermochemical Investigation of the Stability and Conversion of Nanocrystalline and High-Temperature Phases in Sodium Neodymium Fluorides Yang, Shuhao; Jayanthi, K.; Anderko, Andrzej Chemistry of Materials, Vol. 33, Issue 24 https://doi.org/10.1021/acs.chemmater.1c02829	journal	December 2021
Chemical and structural stability of 2D layered materials Wang, Xuewen; Sun, Yinghui; Liu, Kai 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab20d6	journal	July 2019
A comparison of methods for the estimation of the enthalpy of formation of rare earth compounds Sanchez-Segado, Sergio; Lectez, Sebastien; Jha, Animesh Physical Chemistry Chemical Physics, Vol. 23, Issue 42 https://doi.org/10.1039/D1CP03280A	journal	January 2021
Stability of Rare-Earth Oxychloride Phases: Bond Valence Study Hölsä, Jorma; Lahtinen, Manu; Lastusaari, Mika Journal of Solid State Chemistry, Vol. 165, Issue 1 https://doi.org/10.1006/jssc.2001.9491	journal	April 2002
Progress and new directions in high temperature calorimetry Navrotsky, Alexandra Physics and Chemistry of Minerals, Vol. 2, Issue 1-2 https://doi.org/10.1007/BF00307526	journal	January 1977
The Thermodynamic Properties of the f -Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides Konings, Rudy J. M.; Beneš, Ondrej; Kovács, Attila Journal of Physical and Chemical Reference Data, Vol. 43, Issue 1 https://doi.org/10.1063/1.4825256	journal	March 2014
Progress and New Directions in Calorimetry: A 2014 Perspective Navrotsky, Alexandra Journal of the American Ceramic Society, Vol. 97, Issue 11 https://doi.org/10.1111/jace.13278	journal	October 2014
Methyl Chloride Production from Methane over Lanthanum-Based Catalysts Podkolzin, Simon G.; Stangland, Eric E.; Jones, Mark E. Journal of the American Chemical Society, Vol. 129, Issue 9 https://doi.org/10.1021/ja066913w	journal	March 2007
New Intercalation Compounds of Layered Lanthanide Oxychlorides LnOCl (Ln = Ho, Er, Tm, and Yb) with Pyridine and Substituted Pyridines Song, Kang; Kauzlarich, Susan M. Chemistry of Materials, Vol. 6, Issue 4 https://doi.org/10.1021/cm00040a010	journal	April 1994
Chloride ion conduction in rare earth oxychlorides Okamoto, K. Solid State Ionics, Vol. 154-155 https://doi.org/10.1016/S0167-2738(02)00496-4	journal	December 2002
Tm3+ and/or Dy3+ doped LaOCl nanocrystalline phosphors for field emission displays Li, Guogang; Li, Chunxia; Zhang, Cuimiao Journal of Materials Chemistry, Vol. 19, Issue 47 https://doi.org/10.1039/b912115c	journal	January 2009
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Shape-Controlled Synthesis of Well-Defined Matlockite LnOCl (Ln: La, Ce, Gd, Dy) Nanocrystals by a Novel Non-Hydrolytic Approach Kort, Kenneth R.; Banerjee, Sarbajit Inorganic Chemistry, Vol. 50, Issue 12 https://doi.org/10.1021/ic200114s	journal	June 2011
Structural, magnetic and spectroscopic investigations of europium oxychloride, EuOCl Aitasalo, T.; Hölsä, J.; Lastusaari, M. Journal of Alloys and Compounds, Vol. 380, Issue 1-2 https://doi.org/10.1016/j.jallcom.2004.03.057	journal	October 2004
Standard enthalpies of formation for europium, gadolinium, and lutetium oxychlorides, calculated from measured enthalpies of solution Burns, J. B.; Peterson, J. R.; Haire, R. G. Journal of Alloys and Compounds, Vol. 265, Issue 1-2 https://doi.org/10.1016/S0925-8388(97)00435-0	journal	January 1998
Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites Qi, Jianqi; Guo, Xiaofeng; Mielewczyk-Gryn, Aleksandra Journal of Solid State Chemistry, Vol. 227 https://doi.org/10.1016/j.jssc.2015.03.026	journal	July 2015
Nd³⁺-Doped Lanthanum Oxychloride Nanocrystals as Nanothermometers Renero-Lecuna, Carlos; Herrero, Ada; Jimenez de Aberasturi, Dorleta The Journal of Physical Chemistry C, Vol. 125, Issue 36 https://doi.org/10.1021/acs.jpcc.1c05828	journal	September 2021
Recent Advances in 2D Rare Earth Materials Chen, Ping; Han, Wei; Zhao, Mei Advanced Functional Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adfm.202008790	journal	December 2020
Lanthanide compounds as catalysts for the one-step synthesis of vinyl chloride from ethylene Scharfe, Matthias; Lira-Parada, Pedro A.; Amrute, Amol P. Journal of Catalysis, Vol. 344 https://doi.org/10.1016/j.jcat.2016.10.026	journal	December 2016
The Vapor Phase Hydrolysis of Rare Earth Halides. I. Heat and Free Energy of the Reaction: LaCl₃(s) + H₂O(g) = LaOCl(s) + 2HCl(g)¹ Koch, C. W.; Broido, A.; Cunningham, B. B. Journal of the American Chemical Society, Vol. 74, Issue 9 https://doi.org/10.1021/ja01129a049	journal	May 1952
van der Waals Layered Materials: Opportunities and Challenges Duong, Dinh Loc; Yun, Seok Joon; Lee, Young Hee ACS Nano, Vol. 11, Issue 12 https://doi.org/10.1021/acsnano.7b07436	journal	October 2016
The Vapor Phase Hydrolysis of the Rare Earth Halides.¹ III. Heat and Free Energy of the Reactions PrCl₃(s) + H₂O(g) = PrOCl(s) + 2HCl(g) and NdCl₃(s) + H₂O(g) = NdOCl(s) + 2HCl(g) Koch, C. W.; Cunningham, B. B. Journal of the American Chemical Society, Vol. 76, Issue 6 https://doi.org/10.1021/ja01635a003	journal	March 1954
Preparation, powder data and crystal structure of YbOCl Brandt, G.; Diehl, R. Materials Research Bulletin, Vol. 9, Issue 4 https://doi.org/10.1016/0025-5408(74)90208-6	journal	April 1974
Atomically Efficient Synthesis of Self-assembled Monodisperse and Ultrathin Lanthanide Oxychloride Nanoplates Du, Ya-Ping; Zhang, Ya-Wen; Sun, Ling-Dong Journal of the American Chemical Society, Vol. 131, Issue 9 https://doi.org/10.1021/ja8095416	journal	February 2009
Enthalpies of formation of rare earth niobates, RE ₃ NbO ₇ Mielewczyk-Gryn, Aleksandra; Navrotsky, Alexandra American Mineralogist, Vol. 100, Issue 7 https://doi.org/10.2138/am-2015-5210	journal	July 2015
Blue-Emitting Eu ²⁺ -Activated LaOX (X = Cl, Br, and I) Materials: Crystal Field Effect Kim, Donghyeon; Park, Sangha; Kim, Sungyun Inorganic Chemistry, Vol. 53, Issue 22 https://doi.org/10.1021/ic5015576	journal	October 2014
Thermochemistry of rare earth oxyhydroxides, REOOH (RE = Eu to Lu) Yang, Shuhao; Powell, Matthew; Kolis, Joseph W. Journal of Solid State Chemistry, Vol. 287 https://doi.org/10.1016/j.jssc.2020.121344	journal	July 2020
Stability field diagrams for Ln–O–Cl systems Jacob, K. T.; Dixit, Apoorva; Rajput, Arneet Bulletin of Materials Science, Vol. 39, Issue 3 https://doi.org/10.1007/s12034-016-1219-6	journal	June 2016
Zur Kenntnis der schweren Seltenerdoxidchloride. Beck, H. P. Zeitschrift für Naturforschung B, Vol. 31, Issue 12 https://doi.org/10.1515/znb-1976-1202	journal	December 1976
The Vapor Phase Hydrolysis of the Rare Earth Halides. II. Heat and Free Energy of the Reactions: SmCl₃(s) + H₂O(g) = SmOCl(s) + 2HCl(g) and GdCl₃(s) + H₂O(g) = GdOCl(s) + 2HCl(g) Koch, C. W.; Cunningham, B. B. Journal of the American Chemical Society, Vol. 75, Issue 4 https://doi.org/10.1021/ja01100a010	journal	February 1953
Estimates for the enthalpy of formation of rare-earth oxyhalides with the P4/nmm structure Struck, C. W.; Baglio, J. A. Thermochimica Acta, Vol. 216 https://doi.org/10.1016/0040-6031(93)80380-S	journal	March 1993
Growth and Raman Scattering Investigation of a New 2D MOX Material: YbOCl Yao, Yuyu; Zhang, Yu; Xiong, Wenqi Advanced Functional Materials, Vol. 29, Issue 43 https://doi.org/10.1002/adfm.201903017	journal	August 2019
Thermoanalytical study on the reactions of selected rare earth oxides with ammonium halides Hölsä, Jorma; Niinistö, Lauri Thermochimica Acta, Vol. 37, Issue 2 https://doi.org/10.1016/0040-6031(80)80036-0	journal	April 1980
The thermal decomposition of yttrium, scandium, and some rare-earth chloride hydrates Wendlandt, Wesley W. Journal of Inorganic and Nuclear Chemistry, Vol. 5, Issue 2 https://doi.org/10.1016/0022-1902(57)80052-9	journal	January 1957
Influence of antimony substitution on spontaneous strain and thermodynamic stability of lanthanum orthoniobate Mielewczyk-Gryn, A.; Wachowski, S.; Lilova, K. I. Ceramics International, Vol. 41, Issue 2 https://doi.org/10.1016/j.ceramint.2014.10.010	journal	March 2015
Lattice Energies and Unit Cell Volumes of Complex Ionic Solids Glasser, Leslie; Jenkins, H. Donald Brooke Journal of the American Chemical Society, Vol. 122, Issue 4 https://doi.org/10.1021/ja992375u	journal	January 2000
Hidden Nature of the Conversion Reaction from Rare Earth Chloride to Oxychloride and the Application to Novel Separation Yamamoto, Hiroki; Miyata, Motoyuki; Murakami, Hajime ChemistrySelect, Vol. 3, Issue 11 https://doi.org/10.1002/slct.201702581	journal	March 2018
Progress and new directions in high temperature calorimetry revisited Navrotsky, Alexandra Physics and Chemistry of Minerals, Vol. 24, Issue 3 https://doi.org/10.1007/s002690050035	journal	April 1997
Growth of well-developed LaOCl microplates by chloride salt-assisted method Huang, Zhong; Zhang, Haijun; Zhang, Shaowei CrystEngComm, Vol. 19, Issue 22 https://doi.org/10.1039/C7CE00549K	journal	January 2017
Thermodynamics of lanthanide elements IV. Molar enthalpies of formation of Y3+(aq), YCl3(cr), YBr3(cr), and YI3(cr) Xiang-Yun, Wang; Zhu, Jin Tian; Goudiakas, J. The Journal of Chemical Thermodynamics, Vol. 20, Issue 10 https://doi.org/10.1016/0021-9614(88)90103-6	journal	October 1988
Structural environment of chloride ion‐conducting solids based on lanthanum oxychloride Nunotani, Naoyoshi; Misran, Muhammad Radzi Iqbal Bin; Inada, Miki Journal of the American Ceramic Society, Vol. 103, Issue 1 https://doi.org/10.1111/jace.16727	journal	August 2019
A full palette: Crystal chemistry, polymorphism, synthetic strategies, and functional applications of lanthanide oxyhalides Udayakantha, Malsha; Schofield, Parker; Waetzig, Gregory R. Journal of Solid State Chemistry, Vol. 270 https://doi.org/10.1016/j.jssc.2018.12.017	journal	February 2019
The thermal decomposition of the heavier rare earth metal chloride hydrates Wendlandt, W. W. Journal of Inorganic and Nuclear Chemistry, Vol. 9, Issue 2 https://doi.org/10.1016/0022-1902(59)80072-5	journal	February 1959
Ordered Arrays of Nanorods Obtained by Solid−Liquid Reactions of LaOCl Crystals Afanasiev, P.; Aouine, M.; Deranlot, C. Chemistry of Materials, Vol. 22, Issue 19 https://doi.org/10.1021/cm100090e	journal	September 2010
Thermochemistry of sodium rare earth ternary fluorides, NaREF4 Yang, Shuhao; Anderko, Andre; Riman, Richard E. Acta Materialia, Vol. 220 https://doi.org/10.1016/j.actamat.2021.117289	journal	November 2021
Standard molar enthalpies of formation of Y2O3, Ho2O3, and Er2O3 at the temperature 298.15 K Morss, Lester R.; Day, Paul P.; Felinto, Claudia The Journal of Chemical Thermodynamics, Vol. 25, Issue 3 https://doi.org/10.1006/jcht.1993.1045	journal	March 1993
Surface Acidity and Basicity of La ₂ O ₃ , LaOCl, and LaCl ₃ Characterized by IR Spectroscopy, TPD, and DFT Calculations Manoilova, Olga V.; Podkolzin, Simon G.; Tope, Balarishna The Journal of Physical Chemistry B, Vol. 108, Issue 40 https://doi.org/10.1021/jp040311m	journal	October 2004
Crystal Structures of Rare Earth Oxychlorides Templeton, D. H.; Dauben, Carol H. Journal of the American Chemical Society, Vol. 75, Issue 23 https://doi.org/10.1021/ja01119a535	journal	December 1953
Low-temperature routes to new structures for yttrium, holmium, erbium, and thulium oxychlorides Garcia, Eduardo; Corbett, John D.; Ford, Jeff E. Inorganic Chemistry, Vol. 24, Issue 4 https://doi.org/10.1021/ic00198a013	journal	February 1985
Thermochemistry of inorganic solids. 3. Enthalpies of formation of solid metal oxyhalide compounds Hisham, Mohamed W. M.; Benson, Sidney W. The Journal of Physical Chemistry, Vol. 90, Issue 5 https://doi.org/10.1021/j100277a035	journal	February 1986

Similar Records

Thermochemistry of stoichiometric rare earth oxyfluorides REOF

Journal Article · 2021 · Journal of the American Ceramic Society · OSTI ID:1982912

THERMODYNAMIC INVESTIGATION OF RARE EARTH OXYCHLORIDES

Journal Article · 1964 · Zhurnal Neorganicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Inorg. Chem. (Engl. Transl.) · OSTI ID:4519881

Thermochemistry of Rare Earth Orthophosphates

Journal Article · 2001 · Journal of Physical Chemistry · OSTI ID:859617

Related Subjects

Chemistry

Thermochemistry of 3D and 2D Rare Earth Oxychlorides (REOCls)

Citation Formats

References (53)

Similar Records

Related Subjects