Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures

Handy, Joseph V.; Zaheer, Wasif; Rothfuss, Arianna R.  M.; McGranahan, Caitlin R.; Agbeworvi, George; Andrews, Justin L.; García-Pedraza, Karoline E.; Ponis, John D.; Ayala, Jaime R.; Ding, Yu; Watson, David F.; Banerjee, Sarbajit

doi:10.1021/acs.chemmater.1c03762

Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures

Journal Article · 31 January 2022 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.1c03762· OSTI ID:1981826

Handy, Joseph V. ^[1]; Zaheer, Wasif ^[1]; Rothfuss, Arianna R. M. ^[2]; ^[2]; Agbeworvi, George ^[1]; Andrews, Justin L. ^[1]; ^[2]; Ponis, John D. ^[1]; Ayala, Jaime R. ^[1]; Ding, Yu ^[3]; ^[2]; ^[1]

Department of Chemistry, Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77843, United States
Department of Chemistry, University at Buffalo, Buffalo, New York 14260, United States
Department of Industrial and Systems Engineering, Texas A&M University, College Station, Texas 77843, United States

Not provided.

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231

OSTI ID:: 1981826

Journal Information:: Chemistry of Materials, Vol. 34, Issue 4; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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Selective Photocatalytic CO ₂ Reduction in Water by Electrostatic Assembly of CdS Nanocrystals with a Dinuclear Cobalt Catalyst Bi, Qian-Qian; Wang, Jia-Wei; Lv, Jia-Xin ACS Catalysis, Vol. 8, Issue 12 https://doi.org/10.1021/acscatal.8b03457	journal	October 2018
Powering a CO ₂ Reduction Catalyst with Visible Light through Multiple Sub-picosecond Electron Transfers from a Quantum Dot Lian, Shichen; Kodaimati, Mohamad S.; Dolzhnikov, Dmitriy S. Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b03134	journal	June 2017
Photocatalytically Active Superstructures of Quantum Dots and Iron Porphyrins for Reduction of CO ₂ to CO in Water Lian, Shichen; Kodaimati, Mohamad S.; Weiss, Emily A. ACS Nano, Vol. 12, Issue 1 https://doi.org/10.1021/acsnano.7b07377	journal	January 2018
Robust carbon dioxide reduction on molybdenum disulphide edges Asadi, Mohammad; Kumar, Bijandra; Behranginia, Amirhossein Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5470	journal	July 2014
Nanostructured transition metal dichalcogenide electrocatalysts for CO ₂ reduction in ionic liquid Asadi, Mohammad; Kim, Kibum; Liu, Cong Science, Vol. 353, Issue 6298 https://doi.org/10.1126/science.aaf4767	journal	July 2016
Carbon Dioxide Electroreduction into Syngas Boosted by a Partially Delocalized Charge in Molybdenum Sulfide Selenide Alloy Monolayers Xu, Jiaqi; Li, Xiaodong; Liu, Wei Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201704928	journal	June 2017
Adjusting the Reduction Potential of Electrons by Quantum Confinement for Selective Photoreduction of CO ₂ to Methanol Li, Ang; Wang, Tuo; Li, Chengcheng Angewandte Chemie International Edition, Vol. 58, Issue 12 https://doi.org/10.1002/anie.201812773	journal	March 2019
Quantum Confinement Controls Photocatalysis: A Free Energy Analysis for Photocatalytic Proton Reduction at CdSe Nanocrystals Zhao, Jing; Holmes, Michael A.; Osterloh, Frank E. ACS Nano, Vol. 7, Issue 5 https://doi.org/10.1021/nn400826h	journal	April 2013
Chemo- and stereoselective intermolecular [2 + 2] photocycloaddition of conjugated dienes using colloidal nanocrystal photocatalysts Jiang, Yishu; Yang, Muwen; Wu, Yue Chem Catalysis, Vol. 1, Issue 1 https://doi.org/10.1016/j.checat.2021.02.001	journal	June 2021
Semiconductor Quantum Dots Are Efficient and Recyclable Photocatalysts for Aqueous PET-RAFT Polymerization McClelland, Kevin P.; Clemons, Tristan D.; Stupp, Samuel I. ACS Macro Letters, Vol. 9, Issue 1 https://doi.org/10.1021/acsmacrolett.9b00891	journal	December 2019
General and Efficient C–C Bond Forming Photoredox Catalysis with Semiconductor Quantum Dots Caputo, Jill A.; Frenette, Leah C.; Zhao, Norman Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.6b13379	journal	March 2017
Designing the Surfaces of Semiconductor Quantum Dots for Colloidal Photocatalysis Weiss, Emily A. ACS Energy Letters, Vol. 2, Issue 5 https://doi.org/10.1021/acsenergylett.7b00061	journal	April 2017

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