skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Advances in MINLP to Identify Energy-Efficient Distillation Configurations

Journal Article · · Operations Research

Separation of mixtures of chemicals, ubiquitous in chemical and petrochemical industries, by distillation is energy intensive. Nearly 3% of the overall energy is used for distillation in the United States. Improving the distillation process is crucial for making chemical industries more sustainable. However, designing distillation sequences is challenging because the choice set is vast, and the equations governing the physical process are highly nonconvex. Traditional design practices rely on heuristics and often result in suboptimal solutions. Tumbalam Gooty et al. present the first approach that reliably identifies the distillation sequence that requires the least energy for a given separation. By embedding convex hulls of substructures and adapting the reformulation-linearization technique to fractions of polynomials, they demonstrated that their approach outperforms the state-of-the-art. Their work will help the chemical industry reduce greenhouse gas emissions associated with distillation.

Research Organization:
Purdue Univ., West Lafayette, IN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0005768
OSTI ID:
1980964
Journal Information:
Operations Research, Journal Name: Operations Research; ISSN 0030-364X
Publisher:
INFORMS
Country of Publication:
United States
Language:
English

References (24)

Thermally coupled distillation with reduced number of intercolumn vapor transfers journal November 2000
Efficient cryogenic nitrogen generators: An exergy analysis journal September 1991
Design of distillation sequences: from conventional to fully thermally coupled distillation systems journal October 2004
Structural Considerations and Modeling in the Synthesis of Heat-Integrated−Thermally Coupled Distillation Sequences journal December 2006
Simultaneous Convexification of Bilinear Functions over Polytopes with Application to Network Interdiction journal January 2017
CONOPT—A Large-Scale GRG Code journal May 1994
Multicomponent thermally coupled systems of distillation columns at minimum reflux journal December 2001
Thermally coupled system of distillation columns: Optimization procedure journal April 1986
Minimum energy requirements of thermally coupled distillation systems journal April 1987
Synthesis of distillation configurations: I. Characteristics of a good search space journal January 2010
Synthesis of distillation configurations. II: A search formulation for basic configurations journal January 2010
Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements journal February 2003
Global minimization of total exergy loss of multicomponent distillation configurations journal August 2019
Global optimization of multicomponent distillation configurations: Global minimization of total cost for multicomponent mixture separations journal July 2019
Exploiting integrality in the global optimization of mixed-integer nonlinear programming problems with BARON journal July 2017
Global optimization of multicomponent distillation configurations: 1. Need for a reliable global optimization algorithm journal July 2012
Global optimization of multicomponent distillation configurations: 2. Enumeration based global minimization algorithm journal February 2016
A matrix method for multicomponent distillation sequences journal November 2009
A new reformulation-linearization technique for bilinear programming problems journal January 1992
The impact of shale gas in the chemical industry journal January 2014
A polyhedral branch-and-cut approach to global optimization journal May 2005
An MINLP formulation for the optimization of multicomponent distillation configurations journal June 2019
Mixed-Integer Models for Nonseparable Piecewise-Linear Optimization: Unifying Framework and Extensions journal April 2010
On the implementation of an interior-point filter line-search algorithm for large-scale nonlinear programming journal April 2005