Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Investigating anode off-gas under spark-ignition combustion for SOFC-ICE hybrid systems

Journal Article · · International Journal of Engine Research

Solid oxide fuel cell – internal combustion engine (SOFC-ICE) hybrid systems are an attractive solution for electricity generation. The system can achieve up to 70% theoretical electric power conversion efficiency through energy cascading enabled by utilizing the anode off-gas from the SOFC as the fuel source for the ICE. Experimental investigations were conducted with a single cylinder Cooperative Fuel Research (CFR) engine by altering fuel-air equivalence ratio (φ), and compression ratio (CR) to study the engine load, combustion characteristics, and emissions levels of dry SOFC anode off-gas consisting of 33.9% H2, 15.6% CO, and 50.5% CO2. The combustion efficiency of the anode off-gas was directly evaluated by measuring the engine-out CO emissions. The highest net-indicated fuel conversion efficiency of 31.3% occurred at φ = 0.90 and CR = 13:1. These results demonstrate that the anode off-gas can be successfully oxidized using a spark ignition combustion mode. The fuel conversion efficiency of the anode tail gas is expected to further increase in a more modern engine architecture that can achieve increased burn rates in comparison to the CFR engine. NOxemissions from the combustion of anode off-gas were minimal as the cylinder peak temperatures never exceeded 1800 K. This experimental study ultimately demonstrates the viability of an ICE to operate using an anode off-gas, thus creating a complementary role for an ICE to be paired with a SOFC in a hybrid power generation plant.

Research Organization:
State Univ. of New York (SUNY), Albany, NY (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
AR0000959
OSTI ID:
1980947
Journal Information:
International Journal of Engine Research, Vol. 23, Issue 5; ISSN 1468-0874
Publisher:
SAGE
Country of Publication:
United States
Language:
English

References (24)

Solid oxide fuel cell and advanced combustion engine combined cycle: A pathway to 70% electrical efficiency February 2019
Fuel economy using the global optimization of the Fuel Cell Hybrid Power Systems October 2018
Experimental Study of Spark-Ignition Combustion Using the Anode Off-Gas from a Solid Oxide Fuel Cell April 2020
Thermo-economic optimization of an indirectly coupled solid oxide fuel cell/gas turbine hybrid power plant January 2011
Multi-level modeling of SOFC–gas turbine hybrid system August 2003
An experimental and detailed chemical kinetic modeling study of hydrogen and syngas mixture oxidation at elevated pressures June 2013
Gas Turbine Cycles With Solid Oxide Fuel Cells—Part II: A Detailed Study of a Gas Turbine Cycle With an Integrated Internal Reforming Solid Oxide Fuel Cell December 1994
High-efficiency conversion of natural gas fuel to power by an integrated system of SOFC, HCCI engine, and waste heat recovery: Thermodynamic and thermo-economic analyses September 2020
A comprehensive evaluation framework to evaluate energy management strategies of fuel cell electric vehicles December 2018
High performance SOFC/GT combined power generation system with CO2 recovery by oxygen combustion method July 2005
Exergetic and exergoeconomic evaluation of an SOFC-Engine hybrid power generation system February 2018
Analysis on the operating performance of 5-kW class solid oxide fuel cell-internal combustion engine hybrid system using spark-assisted ignition February 2020
Coal: Energy for the future January 1995
Performance analysis of an SOFC/HCCI engine hybrid system: System simulation and thermo-economic comparison January 2014
A fuel cell free piston gas turbine hybrid architecture for high-efficiency, load-flexible power generation February 2021
Design and partial load exergy analysis of hybrid SOFC–GT power plant July 2006
Optimization of energy management system for fuel-cell hybrid electric vehicles: Issues and recommendations October 2018
Experimental study of homogeneous charge compression ignition engine operation fuelled by emulated solid oxide fuel cell anode off-gas November 2018
Environmental impact assessment of a solid-oxide fuel-cell-based combined-heat-and-power-generation system January 2015
Combinations of solid oxide fuel cell and several enhanced gas turbine cycles October 2003
Computational Development of a Dual Pre-Chamber Engine Concept for Lean Burn Combustion October 2016
Experimental study of lean spark ignition combustion using gasoline, ethanol, natural gas, and syngas January 2019
Mixed combustion–electrochemical energy conversion for high-efficiency, transportation-scale engines September 2016
A Review of Pre-Chamber Initiated Jet Ignition Combustion Systems October 2010