Exploring the use of the pentaphenylcyclopentadienyl ligand in uranium chemistry: the crystal structure of (C

Wedal, Justin C.; Ziller, Joseph W.; Evans, William J.; Koutsantonis, George

doi:10.1071/ch21318

Exploring the use of the pentaphenylcyclopentadienyl ligand in uranium chemistry: the crystal structure of (C

Journal Article · 01 January 2022 · Australian Journal of Chemistry

DOI:https://doi.org/10.1071/ch21318· OSTI ID:1979156

; ; ; Koutsantonis, George

The reaction of UI3 with NaC5Ph5 in THF generated (η5-C5Ph5)UI2(THF)2 which was characterized by X-ray crystallography. The complex has a four-legged piano stool structure with a 2.539 Å U– (C5Ph5 ring centroid) distance that is slightly longer than the 2.504 Å distance in (η5-C5Me5)UI2(THF)3 which has a larger formal coordination number. Although the synthesis of the mono-cyclopentadienyl complex was facile, no bis-cyclopentadienyl complexes were isolated from reactions using two equivalents of the pentaphenylcyclopentadienyl ligand per uranium. In one UI3/2NaC5Ph5 synthesis, the X-ray crystal structure of (THF)3Na(η5-C5Ph5) was obtained. Attempts to reduce (η5-C5Ph5)UI2(THF)2 did not give evidence for a UII product. KC8 reductions of the in situ reaction of NdI3 and NaC5Ph5, analogous to the synthesis of (η5-C5Ph5)UI2(THF)2, yielded an X-ray crystal structure of a solvent-separated ion pair (SSIP), [K(18-crown-6)(THF)2][C5Ph5].

Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0004739

OSTI ID:: 1979156

Journal Information:: Australian Journal of Chemistry, Vol. 75, Issue 9; ISSN 0004-9425

Publisher:: CSIRO Publishing

Country of Publication:: United States

Language:: English

References (51)

Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties Kelly, Rory P.; Bell, Toby D. M.; Cox, Rosalind P. Organometallics, Vol. 34, Issue 23 https://doi.org/10.1021/acs.organomet.5b00842	journal	November 2015
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties Deacon, Glen B.; Forsyth, Craig M.; Jaroschik, Florian Organometallics, Vol. 27, Issue 18 https://doi.org/10.1021/om800501z	journal	August 2008
Dinuclear alkynyllanthanoid(ii) dications with pentaphenylcyclopentadienyl or tri-tert-butyldiphosphacyclopentadienyl counter ions Forsyth, Craig M.; Deacon, Glen B.; Field, Leslie D. Chemical Communications, Issue 9 https://doi.org/10.1039/b514358f	journal	January 2006
Decaphenylstannocene, [.eta.5-(C6H5)5C5]2SnII: the first synmetrical main-group sandwich compound Heeg, Mary Jane; Janiak, C.; Zuckerman, J. J. Journal of the American Chemical Society, Vol. 106, Issue 15 https://doi.org/10.1021/ja00327a030	journal	July 1984
Synthese und Struktur von Dicarbonyl(η⁵-pentaphenylcyclopentadienyl)rhodium, (η⁵-C₅Ph₅)Rh(CO)₂ Behrens, Ulrich; Edelmann, Frank Zeitschrift für Naturforschung B, Vol. 41, Issue 11 https://doi.org/10.1515/znb-1986-1117	journal	November 1986
Formation and molecular structures of (.eta.5-pentabenzylcyclopentadienyl)- and (.eta.5-pentaphenylcyclopentadienyl)dicarbonyl derivatives of cobalt and rhodium Chambers, John W.; Baskar, Andrew J.; Bott, Simon G. Organometallics, Vol. 5, Issue 8 https://doi.org/10.1021/om00139a020	journal	August 1986
Decaphenylgermanocene, -stannocene and -plumbocene, [gh5-(C6H5)5C5]2EII (E = Ge, Sn, Pb) and the X-ray crystal and molecular structure of pentaphenylstannocene, η5-(C6H5)5C5SnC5H5-η5 Heeg, Mary Jane; Herber, Rolfe H.; Janiak, Christoph Journal of Organometallic Chemistry, Vol. 346, Issue 3 https://doi.org/10.1016/0022-328X(88)80132-3	journal	June 1988
Reaktionen von Pentaphenylcyclopentadienylnickel-Komplexen mit Thiuramen und Dithiocarbamat: Nickel in den Oxidationsstufen I, II and III Huhn, Michael; Kläui, Wolfgang; Ramacher, Ludwig Journal of Organometallic Chemistry, Vol. 398, Issue 3 https://doi.org/10.1016/0022-328X(90)85519-5	journal	November 1990
Titan(IV)-Verbindungen mit hochphenylierten π-Cyclopentadienylliganden. Die Struktur von (π-C5H5)(π-C5Ph5)TiCl2 Thewalt, Ulf; Schmid, Günter Journal of Organometallic Chemistry, Vol. 412, Issue 3 https://doi.org/10.1016/0022-328X(91)86078-5	journal	July 1991
Synthesis and characterization of binuclear palladium(I) complexes of isocyanides with phenyl-substituted cyclopentadienyl and tris(pyrazol-1-yl)borate ligands Tanase, Tomoaki; Fukushima, Toshihiro; Nomura, Takahito Inorganic Chemistry, Vol. 33, Issue 1 https://doi.org/10.1021/ic00079a008	journal	January 1994
The preparation, crystal structure and some reaction chemistry of Bromo (η5-penta- phenylcyclopentadienyl) dicarbonylosmium (II) , [Os (η5-C5Ph5) (CO) 2Br] Field, L. D.; Hambley, T. W.; Humphrey, P. A. Polyhedron, Vol. 17, Issue 16 https://doi.org/10.1016/S0277-5387(97)00448-8	journal	June 1998
Zirconocene complexes of the sterically demanding pentaphenylcyclopentadienyl ligand, CpPRO. Synthesis and characterization of CpPROZrCl3 and CpCpPROZrCl2 (Cp=η5-C5H5; CpPRO=η5-C5(C6H5)5) Greene, Deborah L.; Villalta, Oscar A.; Macias, Doreen M. Inorganic Chemistry Communications, Vol. 2, Issue 7 https://doi.org/10.1016/S1387-7003(99)00077-5	journal	July 1999
Combined Ruthenium(II) and Lipase Catalysis for Efficient Dynamic Kinetic Resolution of Secondary Alcohols. Insight into the Racemization Mechanism Martín-Matute, Belén; Edin, Michaela; Bogár, Krisztián Journal of the American Chemical Society, Vol. 127, Issue 24 https://doi.org/10.1021/ja051576x	journal	June 2005
Synthesis and characterization of the first metallacyclooctane Sivaramakrishna, Akella; Su, Hong; Moss, John R. Dalton Transactions, Issue 17 https://doi.org/10.1039/b800843b	journal	January 2008
Size Does Matter. Sterically Demanding Metallocene-Substituted 3-Methylidene-Oxindoles Exhibit Poor Kinase Inhibitory Action Spencer, John; Amin, Jahangir; Coxhead, Peter Organometallics, Vol. 30, Issue 11 https://doi.org/10.1021/om200278j	journal	May 2011
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds Fagan, Paul J.; Manriquez, Juan M.; Maatta, Eric A. Journal of the American Chemical Society, Vol. 103, Issue 22 https://doi.org/10.1021/ja00412a021	journal	November 1981
Actinide Organometallic Chemistry Marks, T. J. Science, Vol. 217, Issue 4564 https://doi.org/10.1126/science.217.4564.989	journal	September 1982
Synthesis of a bis(pentamethylcyclopentadienyl) derivative of neodymium Wayda, Andrea L.; Evans, W. J. Inorganic Chemistry, Vol. 19, Issue 7 https://doi.org/10.1021/ic50209a077	journal	July 1980
(Pentamethylcyclopentadienyl)ytterbium and -lutetium complexes by metal oxidation and metathesis Watson, Patricia L.; Whitney, John F.; Harlow, Richard L. Inorganic Chemistry, Vol. 20, Issue 10 https://doi.org/10.1021/ic50224a026	journal	October 1981
Pentamethylcyclopentadienyl derivatives of the trivalent lanthanide elements neodymium, samarium, and ytterbium Tilley, T. Don; Andersen, Richard A. Inorganic Chemistry, Vol. 20, Issue 10 https://doi.org/10.1021/ic50224a025	journal	October 1981
Synthesis, Structure, and Reactivity of Organometallic .pi.-Complexes of the Rare Earths in the Oxidation State Ln3+ with Aromatic Ligands Schumann, Herbert; Meese-Marktscheffel, Juliane A.; Esser, Lothar Chemical Reviews, Vol. 95, Issue 4 https://doi.org/10.1021/cr00036a004	journal	June 1995
Synthesis and Structure of Tris(alkyl- and silyl-tetramethylcyclopentadienyl) Complexes of Lanthanum Evans, William J.; Davis, Benjamin L.; Ziller, Joseph W. Inorganic Chemistry, Vol. 40, Issue 25 https://doi.org/10.1021/ic010554i	journal	December 2001
Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of “(C ₅ Me ₄ SiMe ₃ )LnH ₂ ” Units. Unique Reactivities toward Unsaturated C−C, C−N, and C−O Bonds Cui, Dongmei; Tardif, Olivier; Hou, Zhaomin Journal of the American Chemical Society, Vol. 126, Issue 5 https://doi.org/10.1021/ja039324o	journal	February 2004
Neutral and Monocationic Half‐Sandwich Methyl Rare‐Earth Metal Complexes: Synthesis, Structure, and 1,3‐Butadiene Polymerization Catalysis Robert, Dominique; Spaniol, Thomas P.; Okuda, Jun European Journal of Inorganic Chemistry, Vol. 2008, Issue 18 https://doi.org/10.1002/ejic.200800040	journal	June 2008
Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes Tsoureas, Nikolaos; Summerscales, Owen T.; Cloke, F. Geoffrey N. Organometallics, Vol. 32, Issue 5 https://doi.org/10.1021/om301045k	journal	December 2012
Half-Sandwich Complexes of Dy^III: A Janus-Motif with Facile Tunability of Magnetism Liu, Shan-Shan; Xu, Ling; Jiang, Shang-Da Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/ic502734z	journal	May 2015
Synthesis and Insertion Chemistry of Mixed Tether Uranium Metallocene Complexes Siladke, Nathan A.; LeDuc, Jennifer; Ziller, Joseph W. Chemistry - A European Journal, Vol. 18, Issue 46 https://doi.org/10.1002/chem.201201908	journal	October 2012
Synthesis and Reactivity of a Silylalkyl Double Tuck-in Uranium Metallocene [(η ⁵ :η ¹ -C ₅ Me ₄ SiMe ₂ CH ₂ ) ₂ U] and its Conversion to Bis(tethered) Metallocenes Evans, William J.; Siladke, Nathan A.; Ziller, Joseph W. Chemistry - A European Journal, Vol. 16, Issue 3 https://doi.org/10.1002/chem.200902428	journal	December 2009
Reactivity of the tethered alkyl uranium bonds of (η5:κ1-C5Me4SiMe2CH2)2U Evans, William J.; Siladke, Nathan A.; Ziller, Joseph W. Comptes Rendus Chimie, Vol. 13, Issue 6-7 https://doi.org/10.1016/j.crci.2010.02.003	journal	June 2010
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium( iii ) metallocenium single-molecule magnets Randall McClain, K.; Gould, Colin A.; Chakarawet, Khetpakorn Chemical Science, Vol. 9, Issue 45 https://doi.org/10.1039/C8SC03907K	journal	January 2018
Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II) Gould, Colin A.; McClain, K. Randall; Yu, Jason M. Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b05816	journal	August 2019
Isolation of a Perfectly Linear Uranium(II) Metallocene Guo, Fu‐Sheng; Tsoureas, Nikolaos; Huang, Guo‐Zhang Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201912663	journal	February 2020
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C ₅ H ₄ SiMe ₃ ) ₃ U] MacDonald, Matthew R.; Fieser, Megan E.; Bates, Jefferson E. Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja406791t	journal	August 2013
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding La Pierre, Henry S.; Scheurer, Andreas; Heinemann, Frank W. Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201402050	journal	May 2014
Expanding the Chemistry of Molecular U ²⁺ Complexes: Synthesis, Characterization, and Reactivity of the {[C ₅ H ₃ (SiMe ₃ ) ₂ ] ₃ U} ⁻ Anion Windorff, Cory J.; MacDonald, Matthew R.; Meihaus, Katie R. Chemistry - A European Journal, Vol. 22, Issue 2 https://doi.org/10.1002/chem.201503583	journal	December 2015
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex Billow, Brennan S.; Livesay, Brooke N.; Mokhtarzadeh, Charles C. Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b10888	journal	November 2018
C–H Bond Activation via U(II) in the Reduction of Heteroleptic Bis(trimethylsilyl)amide U(III) Complexes Wedal, Justin C.; Bekoe, Samuel; Ziller, Joseph W. Organometallics, Vol. 39, Issue 18 https://doi.org/10.1021/acs.organomet.0c00496	journal	September 2020
Methyl Displacements from Cyclopentadienyl Ring Planes in Sterically Crowded (C ₅ Me ₅ ) ₃ M Complexes Evans, William J.; Kozimor, Stosh A.; Ziller, Joseph W. Inorganic Chemistry, Vol. 44, Issue 22 https://doi.org/10.1021/ic051130h	journal	October 2005
Mono(pentamethylcyclopentadienyl)uranium(III) Complexes: Synthesis, Properties, and X-ray Structures of (η-C ₅ Me ₅ )UI ₂ (THF) ₃ , (η-C ₅ Me ₅ )UI ₂ (py) ₃ , and (η-C ₅ Me ₅ )U[N(SiMe ₃ ) ₂ ] ₂ Avens, Larry R.; Burns, Carol J.; Butcher, Raymond J. Organometallics, Vol. 19, Issue 4 https://doi.org/10.1021/om990718r	journal	February 2000
Multielectron C–O Bond Activation Mediated by a Family of Reduced Uranium Complexes Kiernicki, John J.; Newell, Brian S.; Matson, Ellen M. Inorganic Chemistry, Vol. 53, Issue 7 https://doi.org/10.1021/ic500012x	journal	March 2014
Accessing Mononuclear Triphenylcyclopentadienyl Lanthanide Complexes by Using Tridentate Nitrogen Ligands: Synthesis, Structure, Luminescence, and Catalysis Bardonov, Daniil A.; Komarov, Pavel D.; Ovchinnikova, Valeriya I. Organometallics, Vol. 40, Issue 9 https://doi.org/10.1021/acs.organomet.1c00022	journal	April 2021
Superbulky metallocene complexes of the heavier alkaline-earth metals strontium and barium Orzechowski, Lars; Piesik, Dirk F. -J.; Ruspic, Christian Dalton Transactions, Issue 35 https://doi.org/10.1039/b809872g	journal	January 2008
Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII Ruspic, Christian; Moss, John R.; Schürmann, Markus Angewandte Chemie International Edition, Vol. 47, Issue 11 https://doi.org/10.1002/anie.200705001	journal	February 2008
Synthesis, structure and solution dynamics of lithium salts of superbulky cyclopentadienyl ligands Giesbrecht, Garth R.; Gordon, John C.; Clark, David L. Dalton Transactions, Issue 13 https://doi.org/10.1039/b302258g	journal	January 2003
Super-Bulky Penta-arylcyclopentadienyl Ligands: Isolation of the Full Range of Half-Sandwich Heavy Alkaline-Earth Metal Hydrides Shi, Xianghui; Qin, Guorui; Wang, Yang Angewandte Chemie International Edition, Vol. 58, Issue 13 https://doi.org/10.1002/anie.201814733	journal	February 2019
Direct Synthesis of Pentaarylcyclopentadienyl Sandwich and Half-Sandwich Complexes of s-, p-, and d-Block Metals Schulte, Yannick; Weinert, Hanns; Wölper, Christoph Organometallics, Vol. 39, Issue 1 https://doi.org/10.1021/acs.organomet.9b00741	journal	December 2019
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of LnI ₃ (THF) ₄ [Ln = Pr] and LnI ₃ (THF) _3.5 [Ln = Nd, Gd, Y] Izod, Keith; Liddle, Stephen T.; Clegg, William Inorganic Chemistry, Vol. 43, Issue 1 https://doi.org/10.1021/ic034851u	journal	January 2004
Reactions of potassium-graphite Bergbreiter, David E.; Killough, James M. Journal of the American Chemical Society, Vol. 100, Issue 7 https://doi.org/10.1021/ja00475a025	journal	March 1978
Low-Valent Uranium Iodides: Straightforward Solution Syntheses of UI ₃ and UI ₄ Etherates Carmichael, Christopher D.; Jones, Natalie A.; Arnold, Polly L. Inorganic Chemistry, Vol. 47, Issue 19 https://doi.org/10.1021/ic801138e	journal	October 2008
Alkali metal salts of pentaphenylcyclopentadienide Zhang, Rongben; Tsutsui, Minoru; E. Bergbreiter, David Journal of Organometallic Chemistry, Vol. 229, Issue 2 https://doi.org/10.1016/S0022-328X(00)90273-0	journal	April 1982

Similar Records

Synthesis and structural characterization of (C sub 5 Me sub 5 )Zr(R) sub 2 (L) sub n sup + complexes

Journal Article · 1990 · Organometallics; (United States) · OSTI ID:6070054

Crowther, D J; Jordan, R F; Baenziger, N C; +1 more

A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes

Journal Article · 2020 · Inorganic Chemistry · OSTI ID:1680020

Windorff, Cory J.; Sperling, Joseph M.; Albrecht-Schönzart, Thomas E.; +11 more

Syntheses of monomeric (. eta. sup 5 -pentamethylcyclopentadienyl)platinum(IV) methyl and bromo complexes and of (hydrotris(3,5-dimethyl-1-pyrazolyl)borato)trimethylplatinum

Journal Article · 1990 · Inorganic Chemistry; (USA) · OSTI ID:6113621

Roth, S; Ramamoorthy, V; Sharp, P R

Related Subjects

Chemistry

Exploring the use of the pentaphenylcyclopentadienyl ligand in uranium chemistry: the crystal structure of (C

Citation Formats

References (51)

Similar Records

Related Subjects