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Synthesis and structural characterization of the new Zintl phases Eu 10 Mn 6 Bi 12 and Yb 10 Zn 6 Sb 12

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/d2dt02011d· OSTI ID:1978890
 [1];  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA
  2. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA; Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA

Two new ternary compounds, Eu10Mn6Bi12and Yb10Zn6Sb12, were synthesized and structurally characterized.

Research Organization:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0008885
OSTI ID:
1978890
Journal Information:
Dalton Transactions, Vol. 51, Issue 35; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (45)

Bonding Patterns in Intermetallic Compounds journal July 1991
Intermetallische Verbindungen journal January 1939
Einige Probleme aus der Physik und der Chemie der Halbmetalle und der Metametalle journal March 1950
Recent progresses on thermoelectric Zintl phases: Structures, materials and optimization journal February 2019
Recent advances in inorganic material thermoelectrics journal January 2018
Zintl phases for thermoelectric devices journal January 2007
Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2 journal November 2005
Zintl phases with group 15 elements and the transition metals: A brief overview of pnictides with diverse and complex structures journal February 2019
Defect-Controlled Electronic Properties in A Zn 2 Sb 2 Zintl Phases journal February 2014
Rare-Earth Metal Substitutions in Ca 9– x RE x Mn 4 Sb 9 ( RE = La–Nd, Sm; x ≈ 1). Synthesis and Characterization of a New Series of Narrow-Gap Semiconductors journal April 2018
Colossal Magnetoresistance in the Transition-Metal Zintl Compound Eu 14 MnSb 11 journal December 1997
Darstellung und Kristallstruktur von Ca9Mn4Bi9 und Ca9Zn4Bi9 /Preparation and Crystal Structure of Ca9Mn4Bi9 and Ca9Zn4Bi9 journal September 1979
Diverse Polyanions Based on MnBi 4 and MnSb 4 Tetrahedra:  Polymorphism, Structure, and Bonding in Ca 21 Mn 4 Bi 18 and Ca 21 Mn 4 Sb 18 journal February 2007
Preparation and structure of a new ternary transition metal Zintl compound containing high spin manganese-bismuth MnIIIBi4 tetrahedra journal September 1989
Unusual Mn−Mn Spin Coupling in the Polar Intermetallic Compounds CaMn 2 Sb 2 and SrMn 2 Sb 2 journal May 2006
The Ternary Alkaline-Earth Metal Manganese Bismuthides Sr 2 MnBi 2 and Ba 2 Mn 1– x Bi 2 ( x ≈ 0.15) journal October 2017
Synthesis, crystal structures, and physical properties of the new Zintl phases A21Zn4Pn18 (A=Ca, Eu; Pn=As, Sb)—Versatile arrangements of [ZnPn4] tetrahedra journal July 2015
Yb 14 ZnSb 11 : Charge Balance in Zintl Compounds as a Route to Intermediate Yb Valence journal July 2000
Ultralow Thermal Conductivity and High Thermopower in a New Family of Zintl Antimonides Ca 10 M Sb 9 ( M = Ga, In, Mn, Zn) with Complex Structures and Heavy Disorder journal April 2021
Probing the Limits of the Zintl Concept:  Structure and Bonding in Rare-Earth and Alkaline-Earth Zinc-Antimonides Yb 9 Zn 4+ x Sb 9 and Ca 9 Zn 4.5 Sb 9 journal August 2004
Properties of single crystalline A Zn 2 Sb 2 ( A  = Ca,Eu,Yb) journal February 2012
Synthesis, Structural Characterization, Electronic Structure, and Magnetic Properties of the Zintl Phase Eu10Cd6Bi12 journal May 2007
Effect of Eu magnetism on the electronic properties of the candidate Dirac material EuMnBi 2 journal August 2014
Synthesis, Structure, and Magnetic Properties of the Rare-Earth Zintl Compounds Eu 14 MnPn 11 and Eu 14 InPn 11 (Pn = Sb, Bi) journal October 1997
Growth of single crystals from metallic fluxes journal June 1992
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
Crystal structure refinement with SHELXL journal January 2015
STRUCTURE TIDY – a computer program to standardize crystal structure data journal April 1987
A local exchange-correlation potential for the spin polarized case. i journal July 1972
Crystal orbital Hamilton populations (COHP): energy-resolved visualization of chemical bonding in solids based on density-functional calculations journal August 1993
Metallic n‐Type Mg 3 Sb 2 Single Crystals Demonstrate the Absence of Ionized Impurity Scattering and Enhanced Thermoelectric Performance journal March 2020
Transport properties and thermal behavior of YbMnSb2 semimetal above room temperature journal November 2021
Growth and transport properties of Mg3X2 (X = Sb, Bi) single crystals journal December 2018
Complex Structural Disorder in the Zintl Phases Yb 10 MnSb 9 and Yb 21 Mn 4 Sb 18 journal April 2021
Eu 10 Mn 6 Sb 13 :  A New Ternary Rare-Earth Transition-Metal Zintl Phase journal July 2003
Synthesis, structure and physical properties of the new Zintl phases Eu11Zn6Sb12 and Eu11Cd6Sb12 journal October 2008
Are Ba 11 Cd 6 Sb 12 and Sr 11 Cd 6 Sb 12 Zintl phases or not? A density-functional theory study journal October 2008
Molecular Single-Bond Covalent Radii for Elements 1-118 journal January 2009
Ca14AlBi11—a new Zintl phase from earth-abundant elements with a great potential for thermoelectric energy conversion journal September 2020
Niobium-bearing arsenides and germanides from elemental mixtures not involving niobium: a new twist to an old problem in solid-state synthesis journal April 2018
Atomic Radii and Interatomic Distances in Metals journal March 1947
Bonding, moment formation, and magnetic interactions in Ca 14 MnBi 11 and Ba 14 MnBi 11 journal March 2002
Seebeck and Figure of Merit Enhancement by Rare Earth Doping in Yb14-xRExZnSb11 (x = 0.5) journal March 2019
Structure and physical properties of YbZn2Sb2 and YbCd2Sb2 journal January 2008