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Intramolecular frustrated Lewis pair mediated approach to the C✔O bond activation and cleavage of carbon dioxide

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/d2cc03413a· OSTI ID:1978856
 [1];  [1];  [1];  [2];  [1]
  1. Department of Chemistry and Biochemistry, Texas Tech University, Memorial Dr & Boston, Lubbock, TX, 79409, USA
  2. Department of Mechanical Engineering, Texas Tech University, Lubbock, TX, 79409, USA
+ Show Author Affiliations

A remarkably stable FLP-CO2adduct smoothly reacts with Tf2O to undergo C–O bond cleavage with the formation of the formal FLP adduct of the elusive dication C2O32+.

Research Organization:
Texas Tech Univ., Lubbock, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019094
OSTI ID:
1978856
Journal Information:
ChemComm, Vol. 58, Issue 67; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (47)

Activation of Carbon Dioxide by Silyl Triflate-Based Frustrated Lewis Pairs journal July 2015
Catalysis Research of Relevance to Carbon Management:  Progress, Challenges, and Opportunities journal April 2001
The Chemistry of a Non-Interacting Vicinal Frustrated Phosphane/Borane Lewis Pair journal December 2016
A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair journal January 2020
Design principles in frustrated Lewis pair catalysis for the functionalization of carbon dioxide and heterocycles journal March 2017
Charge, bond order and valence in the AB initio SCF theory journal May 1983
Reversible, Metal-Free Hydrogen Activation journal November 2006
Recent advances in catalytic hydrogenation of carbon dioxide journal January 2011
Phosphinimine–borane combinations in frustrated Lewis pair chemistry journal January 2013
Noninteracting, Vicinal Frustrated P/B-Lewis Pair at the Norbornane Framework: Synthesis, Characterization, and Reactions journal June 2013
Small Molecule Activation with Intramolecular “Inverse” Frustrated Lewis Pairs journal March 2021
The Mayer bond order as a tool in inorganic chemistry† journal January 2001
Stoichiometric CO2 reductions using a bis-borane-based frustrated Lewis pair journal January 2012
Homogeneous and heterogeneous catalysts for hydrogenation of CO 2 to methanol under mild conditions journal January 2021
Bis-boranes in the frustrated Lewis pair activation of carbon dioxide journal January 2011
Preorganized Frustrated Lewis Pairs journal December 2011
Bond Formation with Maintenance of Twofold Charge: Generation of C2O32+ in the Reaction of CO22+ with CO2 journal December 2007
Bond order and valence: Relations to Mulliken's population analysis journal July 1984
CO2 and Formate Complexes of Phosphine/Borane Frustrated Lewis Pairs journal July 2011
Accessing Frustrated Lewis Pair Chemistry from a Spectroscopically Stable and Classical Lewis Acid-Base Adduct journal April 2018
A Tris(triphenylphosphine)aluminum Ambiphilic Precatalyst for the Reduction of Carbon Dioxide with Catecholborane journal July 2013
The acceptor number ? A quantitative empirical parameter for the electrophilic properties of solvents journal January 1975
Reactivity of Lewis pairs (R2PCH2AlMe2)2 with carbon dioxide journal January 2011
Catalysis for the Valorization of Exhaust Carbon: from CO 2 to Chemicals, Materials, and Fuels. Technological Use of CO 2 journal November 2013
Carbon monoxide bond cleavage mediated by an intramolecular frustrated Lewis pair: access to new B/N heterocycles via selective incorporation of single carbon atoms journal January 2021
Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes journal February 2007
Metal-Free Reduction of CO 2 with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO 2 to Methanol journal April 2014
Triphenyl phosphine ditriflate: A general oxygen activator journal January 1975
Cooperative carbon monoxide to formyl reduction at a trifunctional PBB frustrated Lewis pair journal January 2017
Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts journal January 2018
Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C 6 F 5 ) 3 Pairs journal March 2012
Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide journal January 2011
Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs journal August 2009
Transformation of Carbon Dioxide journal June 2007
Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct journal January 2007
Recent advances in the homogeneous hydrogenation of carbon dioxide journal December 2004
Cycloaddition Reactions of an Active Cyclic Phosphane/Borane Pair with Alkenes, Alkynes, and Carbon Dioxide journal January 2020
Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs journal July 2011
Implications of CO 2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO 2 : A View Using N/Si + Frustrated Lewis Pairs journal June 2016
Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium–sodium carbamato-anhydride via lithium–sodium bis-hexamethyldisilazide journal January 2019
Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More journal December 2009
Using carbon dioxide as a building block in organic synthesis journal January 2015
A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C−X (X=Cl, Br) Bond Activation journal February 2016
A convenient n.m.r. method for the measurement of Lewis acidity at boron centres: correlation of reaction rates of Lewis acid initiated epoxide polymerizations with Lewis acidity journal September 1996
Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: CH versus CC Activation and CO 2 Fixation journal March 2011
Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation journal January 2018
Reactivity of Dimeric P/Al-Based Lewis Pairs toward Carbon Dioxide and tert-Butyl Isocyanate journal June 2013

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