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Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol

Journal Article · · Nature Catalysis

Not provided.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012577
OSTI ID:
1978725
Journal Information:
Nature Catalysis, Vol. 5, Issue 2; ISSN 2520-1158
Publisher:
Springer Nature
Country of Publication:
United States
Language:
English

References (63)

In Situ Studies of Chemistry and Structure of Materials in Reactive Environments journal January 2011
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis journal March 2016
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts journal March 2017
Recent Progresses on Structural Reconstruction of Nanosized Metal Catalysts via Controlled-Atmosphere Transmission Electron Microscopy: A Review journal November 2020
Reshaping of Metal Nanoparticles Under Reaction Conditions journal February 2020
Promotion Mechanisms of Iron Oxide-Based High Temperature Water–Gas Shift Catalysts by Chromium and Copper journal June 2016
Stepwise Sulfurization from MoO 3 to MoS 2 via Chemical Vapor Deposition journal August 2018
The renaissance of iron-based Fischer–Tropsch synthesis: on the multifaceted catalyst deactivation behaviour journal January 2008
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals journal March 2002
Catalyst deactivation journal September 1999
Towards stable catalysts by controlling collective properties of supported metal nanoparticles journal November 2012
Catalyst deactivation via decomposition into single atoms and the role of metal loading journal August 2019
Heterogeneous Catalyst Deactivation and Regeneration: A Review journal February 2015
Design and preparation of high-surface-area Cu/ZnO/Al2O3 catalysts using a modified co-precipitation method for the water-gas shift reaction journal July 2013
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts journal April 2012
Chemical Activity of Thin Oxide Layers: Strong Interactions with the Support Yield a New Thin-Film Phase of ZnO journal September 2013
Quantification of Zinc Atoms in a Surface Alloy on Copper in an Industrial-Type Methanol Synthesis Catalyst journal April 2014
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions journal February 2015
Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis journal October 2016
Methanol Steam Reforming for Hydrogen Production journal October 2007
Support Functionalization To Retard Ostwald Ripening in Copper Methanol Synthesis Catalysts journal June 2015
Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction journal May 2019
A model of metal-oxide support interaction for Rh on TiO2 journal August 1983
Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity journal February 2016
Hydrogen production from methanol using a SiC fiber-containing paper composite impregnated with Cu/ZnO catalyst journal August 2006
Flame Synthesis of Cu/ZnO–CeO 2 Catalysts: Synergistic Metal–Support Interactions Promote CH 3 OH Selectivity in CO 2 Hydrogenation journal April 2021
The kinetics and mechanism of methanol synthesis by hydrogenation of CO2 over a Zn-deposited Cu(111) surface journal July 1997
In Situ Investigations of Structural Changes in Cu/ZnO Catalysts journal September 2000
Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction journal March 2021
Evidence for the migration of ZnOx in a Cu/ZnO methanol synthesis catalyst journal January 1994
Activation of a Cu/ZnO catalyst for methanol synthesis journal March 2006
In Situ Observations of Free-Standing Graphene-like Mono- and Bilayer ZnO Membranes journal October 2015
Correlation between microstructure and mechanical spectroscopy of a Cu-Cu 2 O alloy between 290 K and 873 K journal November 2004
Structure of the catalytically active copper–ceria interfacial perimeter journal February 2019
Role of Cu + on ZnS:Cu p-type semiconductor films grown by sputtering: influence of substitutional Cu in the structural, optical and electronic properties journal January 2016
Electronic structures of C u 2 O , C u 4 O 3 , and CuO: A joint experimental and theoretical study journal December 2016
Recommended Auger parameters for 42 elemental solids journal March 2012
Kinetics of the Higher Alcohol Synthesis over a K-promoted CuO/ZnO/Al2O3 Catalyst journal September 1994
High-Pressure CO Adsorption on Cu-Based Catalysts: Zn-Induced Formation of Strongly Bound CO Monitored by ATR-IR Spectroscopy journal April 2011
IR spectroscopic investigations of chemical and photochemical reactions on metal oxides: bridging the materials gap journal January 2017
Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier’s principle journal May 2021
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts journal September 2016
Catalysts for methanol steam reforming—A review journal August 2010
Pathways for methanol steam reforming involving adsorbed formaldehyde and hydroxyl intermediates on Cu(111): density functional theory studies journal January 2011
The mechanism of steam reforming of methanol over a copper-silica catalyst journal May 1982
Steam reforming and dehydrogenation of methanol: Difference in the catalytic functions of copper and group VIII metals journal April 1997
Steam reforming of methanol over copper-containing catalysts: Influence of support material on microkinetics journal February 2007
Mechanistic insights into the catalytic methanol steam reforming performance of Cu/ZrO2 catalysts by in situ and operando studies journal November 2020
NiAl2O4 Spinel Supported Pt Catalyst: High Performance and Origin in Aqueous-Phase Reforming of Methanol journal September 2019
Ab initio study of CO2 hydrogenation mechanisms on inverse ZnO/Cu catalysts journal April 2018
Effects of Gas-Phase Conditions and Particle Size on the Properties of Cu(111)-Supported ZnyOx Particles Revealed by Global Optimization and Ab Initio Thermodynamics journal November 2019
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity journal November 2019
Reaction-Induced Strong Metal–Support Interactions between Metals and Inert Boron Nitride Nanosheets journal September 2020
Strong Evidence of the Role of H2O in Affecting Methanol Selectivity from CO2 Hydrogenation over Cu-ZnO-ZrO2 journal February 2020
Phase-Pure Cu,Zn,Al Hydrotalcite-like Materials as Precursors for Copper rich Cu/ZnO/Al2O3 Catalysts journal December 2009
Non-syngas direct steam reforming of methanol to hydrogen and carbon dioxide at low temperature journal January 2012
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Generalized Gradient Approximation Made Simple journal October 1996
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points journal December 2000
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
VASPKIT: A user-friendly interface facilitating high-throughput computing and analysis using VASP code journal October 2021
The influence of the support composition on the physicochemical and catalytic properties of Cu catalysts supported on Zirconia-Alumina for methanol steam reforming journal November 2020