Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Bifunctional hydroformylation on heterogeneous Rh-WOx pair site catalysts

Journal Article · · Nature (London)
Not provided.
Research Organization:
Univ. of Delaware, Newark, DE (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001004; SC0012704;
OSTI ID:
1978706
Journal Information:
Nature (London), Journal Name: Nature (London) Journal Issue: 7926 Vol. 609; ISSN 0028-0836
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English

References (48)

Carbonylation of Methanol on Metal–Acid Zeolites: Evidence for a Mechanism Involving a Multisite Active Center journal May 2007
Analyzing the Case for Bifunctional Catalysis journal March 2016
CO 2 Hydrogenation on Cu/Al 2 O 3 : Role of the Metal/Support Interface in Driving Activity and Selectivity of a Bifunctional Catalyst journal September 2019
Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins journal April 2013
MgO-Supported Platinum–Tungsten Catalysts Prepared from Organometallic Precursors: Platinum Clusters Isolated on Dispersed Tungsten journal November 1996
Experimental and Modeling Study of Hydrogenation Using Deuterium Step Transient Response during Ethylene Hydroformylation journal November 1996
A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts journal September 2017
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Hydroxyl Groups on γ-Alumina Surfaces: A DFT Study journal October 2002
Experimental investigation of ethylene hydroformylation to propanal on Rh and Co based catalysts journal January 2014
A Python Multiscale Thermochemistry Toolbox (pMuTT) for thermochemical and kinetic parameter estimation journal February 2020
Importance of metal-oxide interfaces in heterogeneous catalysis: A combined DFT, microkinetic, and experimental study of water-gas shift on Au/MgO journal January 2017
The role of Pt-FexOy interfacial sites for CO oxidation journal February 2018
Understanding the interplay of bifunctional and electronic effects: Microkinetic modeling of the CO electro-oxidation reaction journal April 2020
Industrial applications of olefin metathesis journal April 2004
Quantitative Analysis of Adsorbate Concentrations by Diffuse Reflectance FT-IR journal May 2007
Theoretical and Experimental Characterization of Adsorbed CO and NO on γ-Al 2 O 3 -Supported Rh Nanoparticles journal September 2021
Lonely Atoms with Special Gifts: Breaking Linear Scaling Relationships in Heterogeneous Catalysis with Single-Atom Alloys journal September 2018
Theoretical Study of Ethylene Hydroformylation on Atomically Dispersed Rh/Al 2 O 3 Catalysts: Reaction Mechanism and Influence of the ReO x Promoter journal July 2021
Nature of WO x Sites on SiO 2 and Their Molecular Structure–Reactivity/Selectivity Relationships for Propylene Metathesis journal April 2016
Multicomponent Catalysts: Limitations and Prospects journal March 2018
Synthesis of Heteroatom Rh–ReO x Atomically Dispersed Species on Al 2 O 3 and Their Tunable Catalytic Reactivity in Ethylene Hydroformylation journal October 2019
In Situ Formation of Wilkinson-Type Hydroformylation Catalysts: Insights into the Structure, Stability, and Kinetics of Triphenylphosphine- and Xantphos-Modified Rh/SiO 2 journal February 2013
Surface ReO x Sites on Al 2 O 3 and Their Molecular Structure–Reactivity Relationships for Olefin Metathesis journal January 2015
Activity of Rhodium-Catalyzed Hydroformylation:  Added Insight and Predictions from Theory journal June 2007
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al 2 O 3 and TiO 2 journal February 2012
Isolated Metal Active Site Concentration and Stability Control Catalytic CO 2 Reduction Selectivity journal February 2015
Isostructural Atomically Dispersed Rhodium Catalysts Supported on SAPO-37 and on HY Zeolite journal June 2020
Selective Methanol Carbonylation to Acetic Acid on Heterogeneous Atomically Dispersed ReO 4 /SiO 2 Catalysts journal July 2020
Reverse Water–Gas Shift on Interfacial Sites Formed by Deposition of Oxidized Molybdenum Moieties onto Gold Nanoparticles journal August 2015
Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface journal July 2017
H 2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H 2 Activation at the Metal–Support Interface journal September 2018
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy journal September 2007
Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures journal January 1999
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts journal September 2016
Bimetallic cooperation across the periodic table journal October 2020
Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2 journal January 2019
Performance metrics for sustainable catalysis in industry journal March 2021
Optimization methods for finding minimum energy paths journal April 2008
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
A generalized solid-state nudged elastic band method journal February 2012
The oxidation state of dispersed Rh on Al 2 O 3 journal June 1981
Projector augmented-wave method journal December 1994
Generalized Gradient Approximation Made Simple journal October 1996
A versatile sample-environment cell for non-ambient X-ray scattering experiments journal July 2008
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
The critical role of water at the gold-titania interface in catalytic CO oxidation journal September 2014
SURFACE CHEMKIN-III: A Fortran package for analyzing heterogeneous chemical kinetics at a solid-surface - gas-phase interface journal May 1996

Similar Records

Kinetics and dynamics of heterogeneous hydroformylation Rh catalyst
Journal Article · 1995 · Preprints of Papers, American Chemical Society, Division of Fuel Chemistry · OSTI ID:433263

Heterogeneous hydroformylation of alkenes by Rh-based catalysts
Journal Article · 2022 · Chem · OSTI ID:2425529

Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts
Conference · 1995 · OSTI ID:126454