Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

Zhang, Minghao; Kitchaev, Daniil A.; Lebens-Higgins, Zachary; Vinckeviciute, Julija; Zuba, Mateusz; Reeves, Philip J.; Grey, Clare P.; Whittingham, M. Stanley; Piper, Louis F.  J.; Van der Ven, Anton; Meng, Y. Shirley

doi:10.1038/s41578-022-00416-1

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

Journal Article · 08 February 2022 · Nature Reviews. Materials

DOI:https://doi.org/10.1038/s41578-022-00416-1· OSTI ID:1978679

Zhang, Minghao; Kitchaev, Daniil A.; Lebens-Higgins, Zachary; ; Zuba, Mateusz; ; ; Whittingham, M. Stanley; ; ;

Not provided.

Research Organization:: State Univ. of New York (SUNY), Albany, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012583

OSTI ID:: 1978679

Journal Information:: Nature Reviews. Materials, Vol. 7, Issue 7; ISSN 2058-8437

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

References (192)

Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
Narrowing the Gap between Theoretical and Practical Capacities in Li-Ion Layered Oxide Cathode Materials Radin, Maxwell D.; Hy, Sunny; Sina, Mahsa Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201602888	journal	July 2017
CoO₂, The End Member of the Li_xCoO₂ Solid Solution Amatucci, G. G.; Tarascon, J. M.; Klein, L. C. Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123 https://doi.org/10.1149/1.1836594	journal	January 1996
Identifying the chemical and structural irreversibility in LiNi _0.8 Co _0.15 Al _0.05 O ₂ – a model compound for classical layered intercalation Liu, Haodong; Liu, Hao; Seymour, Ieuan D. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/C7TA10829J	journal	January 2018
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R. Electrochemical and Solid-State Letters, Vol. 4, Issue 11 https://doi.org/10.1149/1.1407994	journal	January 2001
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries Hy, Sunny; Liu, Haodong; Zhang, Minghao Energy & Environmental Science, Vol. 9, Issue 6 https://doi.org/10.1039/C5EE03573B	journal	January 2016
Anionic redox processes for electrochemical devices Grimaud, A.; Hong, W. T.; Shao-Horn, Y. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4551	journal	January 2016
Molecular Orbital Principles of Oxygen-Redox Battery Electrodes Okubo, Masashi; Yamada, Atsuo ACS Applied Materials & Interfaces, Vol. 9, Issue 42 https://doi.org/10.1021/acsami.7b09835	journal	October 2017
Anionic Redox in Rechargeable Lithium Batteries Li, Biao; Xia, Dingguo Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201701054	journal	June 2017
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2524	journal	May 2016
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen Luo, Kun; Roberts, Matthew R.; Hao, Rong Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2471	journal	March 2016
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries Qiu, Bao; Zhang, Minghao; Wu, Lijun Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12108	journal	July 2016
Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials Radin, Maxwell D.; Vinckeviciute, Julija; Seshadri, Ram Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0439-6	journal	July 2019
Delocalized Metal–Oxygen π-Redox Is the Origin of Anomalous Nonhysteretic Capacity in Li-Ion and Na-Ion Cathode Materials Kitchaev, Daniil A.; Vinckeviciute, Julija; Van der Ven, Anton Journal of the American Chemical Society, Vol. 143, Issue 4 https://doi.org/10.1021/jacs.0c10704	journal	January 2021
Structural classification and properties of the layered oxides Delmas, C.; Fouassier, C.; Hagenmuller, P. Physica B+C, Vol. 99, Issue 1-4 https://doi.org/10.1016/0378-4363(80)90214-4	journal	January 1980
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Local Structure and Cation Ordering in O3 Lithium Nickel Manganese Oxides with Stoichiometry Li[Ni[sub x]Mn[sub (2−x)/3]Li[sub (1−2x)/3]]O[sub 2] Yoon, Won-Sub; Iannopollo, Steven; Grey, Clare P. Electrochemical and Solid-State Letters, Vol. 7, Issue 7 https://doi.org/10.1149/1.1737711	journal	January 2004
High-resolution X-ray diffraction, DIFFaX, NMR and first principles study of disorder in the Li₂MnO₃–Li[Ni_1/2Mn_1/2]O₂ solid solution Bréger, Julien; Jiang, Meng; Dupré, Nicolas Journal of Solid State Chemistry, Vol. 178, Issue 9, p. 2575-2585 https://doi.org/10.1016/j.jssc.2005.05.027	journal	September 2005
Highly Reversible Oxygen-Redox Chemistry at 4.1 V in Na _4/7− _x [□ _1/7 Mn _6/7 ]O ₂ (□: Mn Vacancy) Mortemard de Boisse, Benoit; Nishimura, Shin-ichi; Watanabe, Eriko Advanced Energy Materials, Vol. 8, Issue 20 https://doi.org/10.1002/aenm.201800409	journal	April 2018
Unified picture of anionic redox in Li/Na-ion batteries Ben Yahia, Mouna; Vergnet, Jean; Saubanère, Matthieu Nature Materials, Vol. 18, Issue 5 https://doi.org/10.1038/s41563-019-0318-3	journal	March 2019
Rechargeable Alkali-Ion Battery Materials: Theory and Computation Van der Ven, Anton; Deng, Zhi; Banerjee, Swastika Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.9b00601	journal	February 2020
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides Gent, William E.; Lim, Kipil; Liang, Yufeng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02041-x	journal	December 2017
Regeneration of degraded Li-rich layered oxide materials through heat treatment-induced transition metal reordering Li, Yixuan; Zuba, Mateusz J.; Bai, Shuang Energy Storage Materials, Vol. 35 https://doi.org/10.1016/j.ensm.2020.11.013	journal	March 2021
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes Croy, Jason R.; Balasubramanian, Mahalingam; Gallagher, Kevin G. Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00277	journal	October 2015
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
A Two-Step Oxidation Mechanism Controlled by Mn Migration Explains the First-Cycle Activation Behavior of Li2MnO3-Based Li-Excess Materials Vinckeviciute, Julija; Kitchaev, Daniil A.; Van der Ven, Anton Chemistry of Materials, Vol. 33, Issue 5 https://doi.org/10.1021/acs.chemmater.0c03734	journal	February 2021
Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes Dogan, Fulya; Long, Brandon R.; Croy, Jason R. Journal of the American Chemical Society, Vol. 137, Issue 6 https://doi.org/10.1021/ja511299y	journal	February 2015
Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes Eum, Donggun; Kim, Byunghoon; Kim, Sung Joo Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-019-0572-4	journal	January 2020
Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides Aydinol, M. K.; Kohan, A. F.; Ceder, G. Physical Review B, Vol. 56, Issue 3 https://doi.org/10.1103/PhysRevB.56.1354	journal	July 1997
First-Principles Prediction of Vacancy Order-Disorder and Intercalation Battery Voltages in Li x CoO 2 Wolverton, C.; Zunger, Alex Physical Review Letters, Vol. 81, Issue 3 https://doi.org/10.1103/PhysRevLett.81.606	journal	July 1998
First-principles investigation of phase stability in Li x CoO 2 Van der Ven, A.; Aydinol, M. K.; Ceder, G. Physical Review B, Vol. 58, Issue 6 https://doi.org/10.1103/PhysRevB.58.2975	journal	August 1998
Electronic Structure of Chemically-Delithiated LiCoO ₂ Studied by Electron Energy-Loss Spectrometry Graetz, J.; Hightower, A.; Ahn, C. C. The Journal of Physical Chemistry B, Vol. 106, Issue 6 https://doi.org/10.1021/jp0133283	journal	February 2002
Deciphering the oxygen absorption pre‐edge: a caveat on its application for probing oxygen redox reactions in batteries Roychoudhury, Subhayan; Qiao, Ruimin; Zhuo, Zengqing ENERGY & ENVIRONMENTAL MATERIALS https://doi.org/10.1002/eem2.12119	journal	August 2020
Layered-to-Rock-Salt Transformation in Desodiated Na _x CrO ₂ ( x 0.4) Bo, Shou-Hang; Li, Xin; Toumar, Alexandra J. Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b04626	journal	February 2016
New Insight into Structural Evolution in Layered NaCrO ₂ during Electrochemical Sodium Extraction Kubota, Kei; Ikeuchi, Issei; Nakayama, Tetsuri The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp5105888	journal	December 2014
Structure and electrochemistry of LixCryCo1−yO2 Jones, C.; Rossen, E.; Dahn, J. Solid State Ionics, Vol. 68, Issue 1-2 https://doi.org/10.1016/0167-2738(94)90235-6	journal	February 1994
Atomic insight into electrochemical inactivity of lithium chromate (LiCrO2): Irreversible migration of chromium into lithium layers in surface regions Lyu, Yingchun; Ben, Liubin; Sun, Yang Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.082	journal	January 2015
⁶ Li MAS NMR Studies of the Local Structure and Electrochemical Properties of Cr-doped Lithium Manganese and Lithium Cobalt Oxide Cathode Materials for Lithium-Ion Batteries Pan, Chanjuan; Lee, Young Joo; Ammundsen, Brett Chemistry of Materials, Vol. 14, Issue 5 https://doi.org/10.1021/cm011623u	journal	May 2002
Harbinger of hysteresis in lithium-rich oxides: Anionic activity or defect chemistry of cation migration Croy, Jason R.; Garcia, Juan C.; Iddir, Hakim Journal of Power Sources, Vol. 471 https://doi.org/10.1016/j.jpowsour.2020.228335	journal	September 2020
Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries Xie, Y.; Saubanère, M.; Doublet, M. -L. Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE02328B	journal	January 2017
Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides Hong, Jihyun; Gent, William E.; Xiao, Penghao Nature Materials, Vol. 18, Issue 3 https://doi.org/10.1038/s41563-018-0276-1	journal	February 2019
Oxygen activity and peroxide formation as charge compensation mechanisms in Li ₂ MnO ₃ Marusczyk, Anika; Albina, Jan-Michael; Hammerschmidt, Thomas Journal of Materials Chemistry A, Vol. 5, Issue 29 https://doi.org/10.1039/C7TA04164K	journal	January 2017
Lithium Extraction Mechanism in Li-Rich Li ₂ MnO ₃ Involving Oxygen Hole Formation and Dimerization Chen, Hungru; Islam, M. Saiful Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b02870	journal	September 2016
First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk House, Robert A.; Rees, Gregory J.; Pérez-Osorio, Miguel A. Nature Energy, Vol. 5, Issue 10 https://doi.org/10.1038/s41560-020-00697-2	journal	September 2020
Direct observation of reversible oxygen anion redox reaction in Li-rich manganese oxide, Li ₂ MnO ₃ , studied by soft X-ray absorption spectroscopy Oishi, Masatsugu; Yamanaka, Keisuke; Watanabe, Iwao Journal of Materials Chemistry A, Vol. 4, Issue 23 https://doi.org/10.1039/C6TA00174B	journal	January 2016
Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li _1/9 Ni _1/3 Mn _5/9 ]O ₂ Jiang, Meng; Key, Baris; Meng, Ying S. Chemistry of Materials, Vol. 21, Issue 13 https://doi.org/10.1021/cm900279u	journal	July 2009
Electrochemical Activity of Li in the Transition-Metal Sites of O3 Li[Li[sub (1−2x)/3]Mn[sub (2−x)/3]Ni[sub x]]O[sub 2] Grey, Clare P.; Yoon, Won-Sub; Reed, John Electrochemical and Solid-State Letters, Vol. 7, Issue 9 https://doi.org/10.1149/1.1783113	journal	January 2004
Operando Lithium Dynamics in the Li-Rich Layered Oxide Cathode Material via Neutron Diffraction Liu, Haodong; Chen, Yan; Hy, Sunny Advanced Energy Materials, Vol. 6, Issue 7 https://doi.org/10.1002/aenm.201502143	journal	January 2016
Understanding the Anomalous Capacity of Li / Li [ Ni_xLi _{( 1 / 3 − 2x / 3 )} Mn_{( 2 / 3 − x / 3 )} ] O₂ Cells Using In Situ X-Ray Diffraction and Electrochemical Studies Lu, Zhonghua; Dahn, J. R. Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A815-A822 https://doi.org/10.1149/1.1480014	journal	January 2002
Quantifying the Capacity Contributions during Activation of Li ₂ MnO ₃ Rana, Jatinkumar; Papp, Joseph K.; Lebens-Higgins, Zachary ACS Energy Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsenergylett.9b02799	journal	January 2020
A high-energy-density and long-life lithium-ion battery via reversible oxide–peroxide conversion Qiao, Yu; Jiang, Kezhu; Deng, Han Nature Catalysis, Vol. 2, Issue 11 https://doi.org/10.1038/s41929-019-0362-z	journal	October 2019
Anion-redox nanolithia cathodes for Li-ion batteries Zhu, Zhi; Kushima, Akihiro; Yin, Zongyou Nature Energy, Vol. 1, Issue 8 https://doi.org/10.1038/nenergy.2016.111	journal	July 2016
A 500 Wh/kg Lithium-Metal Cell Based on Anionic Redox Qiao, Yu; Deng, Han; He, Ping Joule, Vol. 4, Issue 7 https://doi.org/10.1016/j.joule.2020.05.012	journal	July 2020
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0184-2	journal	July 2018
Metastability and Reversibility of Anionic Redox-Based Cathode for High-Energy Rechargeable Batteries Qiu, Bao; Zhang, Minghao; Lee, Seung-Yong Cell Reports Physical Science, Vol. 1, Issue 3 https://doi.org/10.1016/j.xcrp.2020.100028	journal	March 2020
Electrochemical kinetics of the 0.5Li2MnO3·0.5LiMn0.42Ni0.42Co0.16O2 ‘composite’ layered cathode material for lithium-ion batteries Yu, Haijun; Wang, Yarong; Asakura, Daisuke RSC Advances, Vol. 2, Issue 23 https://doi.org/10.1039/c2ra20772a	journal	January 2012
Dynamic imaging of crystalline defects in lithium-manganese oxide electrodes during electrochemical activation to high voltage Li, Qianqian; Yao, Zhenpeng; Lee, Eungje Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09408-2	journal	April 2019
Continuous monitoring of the bulk oxidation states in Li x Ni 1 / 3 Mn 1 / 3 Co 1 / 3 O 2 during charging and discharging Klinser, G.; Topolovec, S.; Kren, H. Applied Physics Letters, Vol. 109, Issue 21 https://doi.org/10.1063/1.4968547	journal	November 2016
Charging of lithium cobalt oxide battery cathodes studied by means of magnetometry Klinser, G.; Topolovec, S.; Kren, H. Solid State Ionics, Vol. 293 https://doi.org/10.1016/j.ssi.2016.06.004	journal	October 2016
In Situ X-Ray Absorption Studies of a High-Rate LiNi[sub 0.85]Co[sub 0.15]O[sub 2] Cathode Material Balasubramanian, M.; Sun, X.; Yang, X. Q. Journal of The Electrochemical Society, Vol. 147, Issue 8 https://doi.org/10.1149/1.1393624	journal	January 2000
Oxygen and transition metal involvement in the charge compensation mechanism of LiNi1/3Mn1/3Co1/3O2 cathodes Petersburg, Cole F.; Li, Zheng; Chernova, Natasha A. Journal of Materials Chemistry, Vol. 22, Issue 37 https://doi.org/10.1039/c2jm33392a	journal	January 2012
Collapse of LiNi _{1– x – y} Co _x Mn _y O ₂ Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries Li, Wangda; Asl, Hooman Yaghoobnejad; Xie, Qiang Journal of the American Chemical Society, Vol. 141, Issue 13 https://doi.org/10.1021/jacs.8b13798	journal	March 2019
Revisiting the charge compensation mechanisms in LiNi _0.8 Co _0.2−y Al _y O ₂ systems Lebens-Higgins, Zachary W.; Faenza, Nicholas V.; Radin, Maxwell D. Materials Horizons, Vol. 6, Issue 10 https://doi.org/10.1039/C9MH00765B	journal	January 2019
Why LiFePO ₄ is a safe battery electrode: Coulomb repulsion induced electron-state reshuffling upon lithiation Liu, Xiaosong; Wang, Yung Jui; Barbiellini, Bernardo Physical Chemistry Chemical Physics, Vol. 17, Issue 39 https://doi.org/10.1039/C5CP04739K	journal	January 2015
Transition-metal redox evolution in LiNi0.5Mn0.3Co0.2O2 electrodes at high potentials Qiao, Ruimin; Liu, Jun; Kourtakis, Kostantinos Journal of Power Sources, Vol. 360 https://doi.org/10.1016/j.jpowsour.2017.06.009	journal	August 2017
Effect of excess lithium in LiMn ₂ O ₄ and Li _1.15 Mn _1.85 O ₄ electrodes revealed by quantitative analysis of soft X-ray absorption spectroscopy Zhuo, Zengqing; Olalde-Velasco, Paul.; Chin, Timothy Applied Physics Letters, Vol. 110, Issue 9 https://doi.org/10.1063/1.4977502	journal	February 2017
Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO ₂ Lebens-Higgins, Zachary W.; Vinckeviciute, Julija; Wu, Jinpeng The Journal of Physical Chemistry C, Vol. 123, Issue 21 https://doi.org/10.1021/acs.jpcc.9b01298	journal	May 2019
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li _1.20 Mn _0.54 Co _0.13 Ni _0.13 O ₂ in Li Ion Batteries Koga, H.; Croguennec, L.; Ménétrier, M. The Journal of Physical Chemistry C, Vol. 118, Issue 11 https://doi.org/10.1021/jp412197z	journal	March 2014
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 Ito, Atsushi; Sato, Yuichi; Sanada, Takashi Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.09.105	journal	August 2011
Charge compensation mechanisms in Li1.16Ni0.15Co0.19Mn0.50O2 positive electrode material for Li-ion batteries analyzed by a combination of hard and soft X-ray absorption near edge structure Oishi, Masatsugu; Fujimoto, Takahiro; Takanashi, Yu Journal of Power Sources, Vol. 222 https://doi.org/10.1016/j.jpowsour.2012.08.023	journal	January 2013
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO ₂ and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides Renfrew, Sara E.; McCloskey, Bryan D. Journal of the American Chemical Society, Vol. 139, Issue 49 https://doi.org/10.1021/jacs.7b08461	journal	November 2017
Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Electrodes Renfrew, Sara E.; McCloskey, Bryan D. ACS Applied Energy Materials, Vol. 2, Issue 5 https://doi.org/10.1021/acsaem.9b00459	journal	April 2019
Electrolyte Oxidation Pathways in Lithium-Ion Batteries Rinkel, Bernardine L. D.; Hall, David S.; Temprano, Israel Journal of the American Chemical Society, Vol. 142, Issue 35 https://doi.org/10.1021/jacs.0c06363	journal	July 2020
Origin of Carbon Dioxide Evolved during Cycling of Nickel-Rich Layered NCM Cathodes Hatsukade, Toru; Schiele, Alexander; Hartmann, Pascal ACS Applied Materials & Interfaces, Vol. 10, Issue 45 https://doi.org/10.1021/acsami.8b13158	journal	October 2018
Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries Wandt, Johannes; Freiberg, Anna T. S.; Ogrodnik, Alexander Materials Today, Vol. 21, Issue 8 https://doi.org/10.1016/j.mattod.2018.03.037	journal	October 2018
Charging Mechanism of Li ₂ MnO ₃ Guerrini, Niccoló; Jin, Liyu; Lozano, Juan G. Chemistry of Materials, Vol. 32, Issue 9 https://doi.org/10.1021/acs.chemmater.9b04459	journal	April 2020
Excess Lithium in Transition Metal Layers of Epitaxially Grown Thin Film Cathodes of Li ₂ MnO ₃ Leads to Rapid Loss of Covalency during First Battery Cycle Massel, Felix; Hikima, Kazuhiro; Rensmo, Håkan The Journal of Physical Chemistry C, Vol. 123, Issue 47 https://doi.org/10.1021/acs.jpcc.9b06246	journal	November 2019
Extended Interfacial Stability through Simple Acid Rinsing in a Li-Rich Oxide Cathode Material Ramakrishnan, Srinivasan; Park, Byungchun; Wu, Jue Journal of the American Chemical Society, Vol. 142, Issue 18 https://doi.org/10.1021/jacs.0c02859	journal	April 2020
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
Design Rules for High-Valent Redox in Intercalation Electrodes Gent, William E.; Abate, Iwnetim Iwnetu; Yang, Wanli Joule, Vol. 4, Issue 7 https://doi.org/10.1016/j.joule.2020.05.004	journal	July 2020
Oxygen K-edge X-ray Absorption Spectra Frati, Federica; Hunault, Myrtille O. J. Y.; de Groot, Frank M. F. Chemical Reviews, Vol. 120, Issue 9 https://doi.org/10.1021/acs.chemrev.9b00439	journal	April 2020
Advances in soft X-ray RIXS for studying redox reaction states in batteries Wu, Jue; Yang, Yong; Yang, Wanli Dalton Transactions, Vol. 49, Issue 39 https://doi.org/10.1039/D0DT01782E	journal	January 2020
Full Energy Range Resonant Inelastic X-ray Scattering of O ₂ and CO ₂ : Direct Comparison with Oxygen Redox State in Batteries Zhuo, Zengqing; Liu, Yi-sheng; Guo, Jinghua The Journal of Physical Chemistry Letters, Vol. 11, Issue 7 https://doi.org/10.1021/acs.jpclett.0c00423	journal	March 2020
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 Maitra, Urmimala; House, Robert A.; Somerville, James W. Nature Chemistry, Vol. 10, Issue 3 https://doi.org/10.1038/nchem.2923	journal	January 2018
High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions Dai, Kehua; Wu, Jinpeng; Zhuo, Zengqing Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.11.014	journal	February 2019
Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes Wu, Jinpeng; Zhuo, Zengqing; Rong, Xiaohui Science Advances, Vol. 6, Issue 6 https://doi.org/10.1126/sciadv.aaw3871	journal	February 2020
Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox House, Robert A.; Jin, Liyu; Maitra, Urmimala Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/C7EE03195E	journal	January 2018
Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V Zhang, Jie-Nan; Li, Qinghao; Ouyang, Chuying Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0409-z	journal	June 2019
Unraveling the Cationic and Anionic Redox Reactions in a Conventional Layered Oxide Cathode Li, Ning; Sallis, Shawn; Papp, Joseph K. ACS Energy Letters, Vol. 4, Issue 12 https://doi.org/10.1021/acsenergylett.9b02147	journal	October 2019
Reversible Anionic Redox Activities in Conventional LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathodes Lee, Gi-Hyeok; Wu, Jinpeng; Kim, Duho Angewandte Chemie International Edition https://doi.org/10.1002/anie.202001349	journal	March 2020
Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes Assat, Gaurav; Foix, Dominique; Delacourt, Charles Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02291-9	journal	December 2017
Oxidation behaviour of lattice oxygen in Li-rich manganese-based layered oxide studied by hard X-ray photoelectron spectroscopy Shimoda, Keiji; Minato, Taketoshi; Nakanishi, Koji Journal of Materials Chemistry A, Vol. 4, Issue 16 https://doi.org/10.1039/C6TA01152G	journal	January 2016
How Bulk Sensitive is Hard X-ray Photoelectron Spectroscopy: Accounting for the Cathode–Electrolyte Interface when Addressing Oxygen Redox Lebens-Higgins, Zachary W.; Chung, Hyeseung; Zuba, Mateusz J. The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00229	journal	February 2020
Combining Accurate O ₂ and Li ₂ O ₂ Assays to Separate Discharge and Charge Stability Limitations in Nonaqueous Li–O ₂ Batteries McCloskey, Bryan D.; Valery, Alexia; Luntz, Alan C. The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401659f	journal	August 2013
Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries Sathiya, M.; Leriche, J. -B.; Salager, E. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7276	journal	February 2015
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Local structure adaptability through multi cations for oxygen redox accommodation in Li-Rich layered oxides Zhao, Enyue; Zhang, Minghao; Wang, Xuelong Energy Storage Materials, Vol. 24 https://doi.org/10.1016/j.ensm.2019.07.032	journal	January 2020
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode Rong, Xiaohui; Liu, Jue; Hu, Enyuan Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.10.008	journal	January 2018
Direct Visualization of the Reversible O ²⁻ /O ⁻ Redox Process in Li-Rich Cathode Materials Li, Xiang; Qiao, Yu; Guo, Shaohua Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201705197	journal	February 2018
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes House, Robert A.; Maitra, Urmimala; Pérez-Osorio, Miguel A. Nature, Vol. 577, Issue 7791 https://doi.org/10.1038/s41586-019-1854-3	journal	December 2019
Decoupling Cationic–Anionic Redox Processes in a Model Li-Rich Cathode via Operando X-ray Absorption Spectroscopy Assat, Gaurav; Iadecola, Antonella; Delacourt, Charles Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b03434	journal	November 2017
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries McCalla, E.; Abakumov, A. M.; Saubanere, M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aac8260	journal	December 2015
Short O–O separation in layered oxide Na _0.67 CoO ₂ enables an ultrafast oxygen evolution reaction Wang, Hao; Wu, Jinpeng; Dolocan, Andrei Proceedings of the National Academy of Sciences, Vol. 116, Issue 47 https://doi.org/10.1073/pnas.1901046116	journal	November 2019
Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li _0.2 Ni _0.2 Mn _0.6 ]O ₂ Luo, Kun; Roberts, Matthew R.; Guerrini, Niccoló Journal of the American Chemical Society, Vol. 138, Issue 35 https://doi.org/10.1021/jacs.6b05111	journal	August 2016
Raman Microscopy of Lithium-Manganese-Rich Transition Metal Oxide Cathodes Ruther, Rose E.; Callender, Andrew F.; Zhou, Hui Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0361501jes	journal	November 2014
Unveiling the complex electronic structure of amorphous metal oxides Arhammar, C.; Pietzsch, A.; Bock, N. Proceedings of the National Academy of Sciences, Vol. 108, Issue 16 https://doi.org/10.1073/pnas.1019698108	journal	April 2011
Both Cationic and Anionic Co-(de)intercalation into a Metal-Oxide Material Li, Qi; Qiao, Yu; Guo, Shaohua Joule, Vol. 2, Issue 6 https://doi.org/10.1016/j.joule.2018.03.010	journal	June 2018
Manganese‐Based Na‐Rich Materials Boost Anionic Redox in High‐Performance Layered Cathodes for Sodium‐Ion Batteries Zhang, Xiaoyu; Qiao, Yu; Guo, Shaohua Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201807770	journal	May 2019
Stabilizing Reversible Oxygen Redox Chemistry in Layered Oxides for Sodium‐Ion Batteries Cao, Xin; Li, Haifeng; Qiao, Yu Advanced Energy Materials, Vol. 10, Issue 15 https://doi.org/10.1002/aenm.201903785	journal	February 2020
Shell-isolated nanoparticle-enhanced Raman spectroscopy Li, Jian Feng; Huang, Yi Fan; Ding, Yong Nature, Vol. 464, Issue 7287, p. 392-395 https://doi.org/10.1038/nature08907	journal	March 2010
NMR, PDF and RMC study of the positive electrode material Li(Ni0.5Mn0.5)O2 synthesized by ion-exchange methods Bréger, Julien; Kang, Kisuk; Cabana, Jordi Journal of Materials Chemistry, Vol. 17, Issue 30 https://doi.org/10.1039/b702745a	journal	January 2007
Li-Rich Mn/Ni Layered Oxide as Electrode Material for Lithium Batteries: A ⁷Li MAS NMR Study Revealing Segregation into (Nanoscale) Domains with Highly Different Electrochemical Behaviors Buzlukov, Anton; Mouesca, Jean-Marie; Buannic, Lucienne The Journal of Physical Chemistry C, Vol. 120, Issue 34 https://doi.org/10.1021/acs.jpcc.6b07532	journal	August 2016
Pristine-state structure of lithium-ion-battery cathode material Li _1.2 Mn _0.4 Co _0.4 O ₂ derived from NMR bond pathway analysis Iddir, Hakim; Key, Baris; Dogan, Fulya Journal of Materials Chemistry A, Vol. 3, Issue 21 https://doi.org/10.1039/C5TA01510C	journal	January 2015
Short- and Long-Range Order in the Positive Electrode Material, Li(NiMn) _0.5 O ₂ : A Joint X-ray and Neutron Diffraction, Pair Distribution Function Analysis and NMR Study Bréger, Julien; Dupré, Nicolas; Chupas, Peter J. Journal of the American Chemical Society, Vol. 127, Issue 20 https://doi.org/10.1021/ja050697u	journal	May 2005
Characterizing Oxygen Local Environments in Paramagnetic Battery Materials via ¹⁷ O NMR and DFT Calculations Seymour, Ieuan D.; Middlemiss, Derek S.; Halat, David M. Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b05747	journal	July 2016
Characterizing the Structure and Phase Transition of Li ₂ RuO ₃ Using Variable-Temperature ¹⁷ O and ⁷ Li NMR Spectroscopy Reeves, Philip J.; Seymour, Ieuan D.; Griffith, Kent J. Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.8b05178	journal	March 2019
¹⁷ O NMR in liquid O ₂ Dundon, Jeffrey M. The Journal of Chemical Physics, Vol. 76, Issue 5 https://doi.org/10.1063/1.443233	journal	March 1982
Crystalline Grain Interior Configuration Affects Lithium Migration Kinetics in Li-Rich Layered Oxide Yu, Haijun; So, Yeong-Gi; Kuwabara, Akihide Nano Letters, Vol. 16, Issue 5 https://doi.org/10.1021/acs.nanolett.5b03933	journal	April 2016
Probing the electrode/electrolyte interface in the lithium excess layered oxide Li1.2Ni0.2Mn0.6O2 Carroll, Kyler J.; Qian, Danna; Fell, Chris Physical Chemistry Chemical Physics, Vol. 15, Issue 26 https://doi.org/10.1039/c3cp51927a	journal	January 2013
Structural evolution at the oxidative and reductive limits in the first electrochemical cycle of Li1.2Ni0.13Mn0.54Co0.13O2 Yin, Wei; Grimaud, Alexis; Rousse, Gwenaelle Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14927-4	journal	March 2020
Correlations between Transition-Metal Chemistry, Local Structure, and Global Structure in Li ₂ Ru _0.5 Mn _0.5 O ₃ Investigated in a Wide Voltage Window Lyu, Yingchun; Hu, Enyuan; Xiao, Dongdong Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b02299	journal	November 2017
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
Injection of oxygen vacancies in the bulk lattice of layered cathodes Yan, Pengfei; Zheng, Jianming; Tang, Zhen-Kun Nature Nanotechnology, Vol. 14, Issue 6 https://doi.org/10.1038/s41565-019-0428-8	journal	April 2019
Computational understanding of Li-ion batteries Urban, Alexander; Seo, Dong-Hwa; Ceder, Gerbrand npj Computational Materials, Vol. 2, Issue 1 https://doi.org/10.1038/npjcompumats.2016.2	journal	March 2016
Automated generation and ensemble-learned matching of X-ray absorption spectra Zheng, Chen; Mathew, Kiran; Chen, Chi npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0067-x	journal	March 2018
Short-Range Order and Unusual Modes of Nickel Redox in a Fluorine-Substituted Disordered Rocksalt Oxide Lithium-Ion Cathode Clément, Raphaële J.; Kitchaev, Daniil; Lee, Jinhyuk Chemistry of Materials, Vol. 30, Issue 19 https://doi.org/10.1021/acs.chemmater.8b03794	journal	September 2018
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries Ji, Huiwen; Urban, Alexander; Kitchaev, Daniil A. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08490-w	journal	February 2019
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries Yabuuchi, Naoaki; Nakayama, Masanobu; Takeuchi, Mitsue Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13814	journal	December 2016
Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials Lee, Jinhyuk; Kitchaev, Daniil A.; Kwon, Deok-Hwang Nature, Vol. 556, Issue 7700 https://doi.org/10.1038/s41586-018-0015-4	journal	April 2018
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Hybrid functionals based on a screened Coulomb potential Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias The Journal of Chemical Physics, Vol. 118, Issue 18 https://doi.org/10.1063/1.1564060	journal	May 2003
Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides Seo, Dong-Hwa; Urban, Alexander; Ceder, Gerbrand Physical Review B, Vol. 92, Issue 11 https://doi.org/10.1103/PhysRevB.92.115118	journal	September 2015
Formation enthalpies by mixing GGA and GGA + U calculations Jain, Anubhav; Hautier, Geoffroy; Ong, Shyue Ping Physical Review B, Vol. 84, Issue 4 https://doi.org/10.1103/PhysRevB.84.045115	journal	July 2011
Strongly Constrained and Appropriately Normed Semilocal Density Functional Sun, Jianwei; Ruzsinszky, Adrienn; Perdew, John P. Physical Review Letters, Vol. 115, Issue 3 https://doi.org/10.1103/PhysRevLett.115.036402	journal	July 2015
Efficient first-principles prediction of solid stability: Towards chemical accuracy Zhang, Yubo; Kitchaev, Daniil A.; Yang, Julia npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0065-z	journal	March 2018
Understanding the Role of NH ₄ F and Al ₂ O ₃ Surface Co-modification on Lithium-Excess Layered Oxide Li _1.2 Ni _0.2 Mn _0.6 O ₂ Liu, Haodong; Qian, Danna; Verde, Michael G. ACS Applied Materials & Interfaces, Vol. 7, Issue 34 https://doi.org/10.1021/acsami.5b04932	journal	August 2015
A Novel Surface Treatment Method and New Insight into Discharge Voltage Deterioration for High-Performance 0.4Li ₂ MnO _3- 0.6LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathode Materials Oh, Pilgun; Ko, Minseong; Myeong, Seungjun Advanced Energy Materials, Vol. 4, Issue 16 https://doi.org/10.1002/aenm.201400631	journal	June 2014
Nanoscale Surface Modification of Lithium-Rich Layered-Oxide Composite Cathodes for Suppressing Voltage Fade Zheng, Fenghua; Yang, Chenghao; Xiong, Xunhui Angewandte Chemie International Edition, Vol. 54, Issue 44 https://doi.org/10.1002/anie.201506408	journal	September 2015
Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment Zhu, Zhi; Yu, Daiwei; Yang, Yang Nature Energy, Vol. 4, Issue 12 https://doi.org/10.1038/s41560-019-0508-x	journal	December 2019
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Electrolyte Additive in Support of 5 V Li Ion Chemistry von Cresce, Arthur; Xu, Kang Journal of The Electrochemical Society, Vol. 158, Issue 3, p. A337-A342 https://doi.org/10.1149/1.3532047	journal	January 2011
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries Alvarado, Judith; Schroeder, Marshall A.; Zhang, Minghao Materials Today, Vol. 21, Issue 4 https://doi.org/10.1016/j.mattod.2018.02.005	journal	May 2018
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
A facile cathode design combining Ni-rich layered oxides with Li-rich layered oxides for lithium-ion batteries Song, Bohang; Li, Wangda; Yan, Pengfei Journal of Power Sources, Vol. 325 https://doi.org/10.1016/j.jpowsour.2016.06.056	journal	September 2016
High Pressure Effect on Structural and Electrochemical Properties of Anionic Redox-Based Lithium Transition Metal Oxides Zhang, Minghao; Qiu, Bao; Gallardo-Amores, Jose M. Matter, Vol. 4, Issue 1 https://doi.org/10.1016/j.matt.2020.10.026	journal	January 2021
In Situ X-ray Diffraction Study of Layered Li–Ni–Mn–Co Oxides: Effect of Particle Size and Structural Stability of Core–Shell Materials Li, Jing; Shunmugasundaram, Ramesh; Doig, Renny Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b03500	journal	December 2015
Origin of High Capacity and Poor Cycling Stability of Li-Rich Layered Oxides: A Long-Duration in Situ Synchrotron Powder Diffraction Study Kleiner, Karin; Strehle, Benjamin; Baker, Annabelle R. Chemistry of Materials, Vol. 30, Issue 11 https://doi.org/10.1021/acs.chemmater.8b00163	journal	May 2018
Quantifying Hysteresis and Voltage Fade in xLi ₂ MnO ₃ _^● (1-x)LiMn _0.5 Ni _0.5 O ₂ Electrodes as a Function of Li ₂ MnO ₃ Content Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam Journal of The Electrochemical Society, Vol. 161, Issue 3 https://doi.org/10.1149/2.049403jes	journal	December 2013
Hierarchically porous micro-rod lithium-rich cathode material Li1.2Ni0.13Mn0.54Co0.13O2 for high performance lithium-ion batteries Zhang, Linjing; Borong, Wu.; Ning, Li. Electrochimica Acta, Vol. 118 https://doi.org/10.1016/j.electacta.2013.11.186	journal	February 2014
Synthesis, characterization and electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2cathode materials for lithium-ion batteries Jin, Xue; Xu, Qunjie; Yuan, Xiaolei Electrochimica Acta, Vol. 114 https://doi.org/10.1016/j.electacta.2013.10.091	journal	December 2013
Comments on stabilizing layered manganese oxide electrodes for Li batteries Kim, Donghan; Croy, Jason R.; Thackeray, Michael M. Electrochemistry Communications, Vol. 36 https://doi.org/10.1016/j.elecom.2013.08.022	journal	November 2013
Coprecipitation-Gel Synthesis and Degradation Mechanism of Octahedral Li _1.2 Mn _0.54 Ni _0.13 Co _0.13 O ₂ as High-Performance Cathode Materials for Lithium-Ion Batteries He, Wenxiang; Liu, Jianguo; Sun, Wei ACS Applied Materials & Interfaces, Vol. 10, Issue 27 https://doi.org/10.1021/acsami.8b04023	journal	June 2018
The effect of composite organic acid (citric acid & tartaric acid) on microstructure and electrochemical properties of Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 Li-rich layered oxides Zheng, Fenghua; Ou, Xing; Pan, Qichang Journal of Power Sources, Vol. 346 https://doi.org/10.1016/j.jpowsour.2017.02.036	journal	April 2017
Optimizing the Structural Evolution of Li-Rich Oxide Cathode Materials via Microwave-Assisted Pre-Activation Wang, Min-Jun; Yu, Fu-Da; Sun, Gang ACS Applied Energy Materials, Vol. 1, Issue 8 https://doi.org/10.1021/acsaem.8b00812	journal	August 2018
Preparation and electrochemical properties of Co-doped and none-doped Li[LixMn0.65(1−x)Ni0.35(1−x)]O2 cathode materials for lithium battery batteries Tang, Zhaohui; Wang, Zhixing; Li, Xinhai Journal of Power Sources, Vol. 204 https://doi.org/10.1016/j.jpowsour.2011.12.040	journal	April 2012
Influence of lithium content on the electrochemical performance of Li1+x(Mn0.533Ni0.233Co0.233)1−xO2 cathode materials Tang, Zhaohui; Wang, Zhixing; Li, Xinhai Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.085	journal	June 2012
Electrochemical and rate performance study of high-voltage lithium-rich composition: Li1.2Mn0.525Ni0.175Co0.1O2 Martha, Surendra K.; Nanda, Jagjit; Veith, Gabriel M. Journal of Power Sources, Vol. 199 https://doi.org/10.1016/j.jpowsour.2011.10.019	journal	February 2012
Direct observation of reversible charge compensation by oxygen ion in Li-rich manganese layered oxide positive electrode material, Li1.16Ni0.15Co0.19Mn0.50O2 Oishi, Masatsugu; Yogi, Chihiro; Watanabe, Iwao Journal of Power Sources, Vol. 276 https://doi.org/10.1016/j.jpowsour.2014.11.104	journal	February 2015
Facile synthesis of spherical xLi2MnO3·(1−x)Li(Mn0.33Co0.33Ni0.33)O2 as cathode materials for lithium-ion batteries with improved electrochemical performance Li, Bing; Yu, Yangyang; Zhao, Jinbao Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.018	journal	February 2015
Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: x Li ₂ MnO ₃ ·(1 − x )LiMn _0.333 Ni _0.333 Co _0.333 O ₂ (0 ≤ x ≤ 0.7) Johnson, Christopher S.; Li, Naichao; Lefief, Christina Chemistry of Materials, Vol. 20, Issue 19 https://doi.org/10.1021/cm801245r	journal	October 2008
Stabilization of xLi₂MnO₃ ⋅ ( 1 − x ) LiMO₂ Electrode Surfaces ( M = Mn , Ni , Co ) with Mildly Acidic, Fluorinated Solutions Kang, S.-H.; Thackeray, M. M. Journal of The Electrochemical Society, Vol. 155, Issue 4, p. A269-A275 https://doi.org/10.1149/1.2834904	journal	January 2008
Countering the Voltage Decay in High Capacity xLi ₂ MnO ₃ •(1–x)LiMO ₂ Electrodes (M=Mn, Ni, Co) for Li ⁺ -Ion Batteries Croy, Jason R.; Kim, Donghan; Balasubramanian, Mahalingam Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.080206jes	journal	January 2012
Degradation and Structural Evolution of x Li ₂ MnO ₃ ·(1– x )LiMn _1/3 Ni _1/3 Co _1/3 O ₂ during Cycling Liu, Jinlong; Liu, Jingyuan; Wang, Renhe Journal of The Electrochemical Society, Vol. 161, Issue 1 https://doi.org/10.1149/2.079401jes	journal	October 2013
Tuning of Ni, Mn, and Co (NMC) Content in 0.4(LiNi_xMn_yCo_zO₂)·0.4(Li₂MnO₃) toward Stable High-Capacity Lithium-Rich Cathode Materials R. N., Ramesha; Bosubabu, Dasari; M. G., Karthick Babu ACS Applied Energy Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsaem.0c01897	journal	November 2020
Tuning Electrochemical Properties of Li-Rich Layered Oxide Cathodes by Adjusting Co/Ni Ratios and Mechanism Investigation Using in situ X-ray Diffraction and Online Continuous Flow Differential Electrochemical Mass Spectrometry Shen, ShouYu; Hong, YuHao; Zhu, FuChun ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.8b00919	journal	December 2017
Local electronic structure modulation enhances operating voltage in Li-rich cathodes Sun, Gang; Yu, Fu-Da; Que, Lan-Fang Nano Energy, Vol. 66 https://doi.org/10.1016/j.nanoen.2019.104102	journal	December 2019
Effect of transition metal composition on electrochemical performance of nickel-manganese-based lithium-rich layer-structured cathode materials in lithium-ion batteries Konishi, Hiroaki; Gunji, Akira; Feng, Xiaoliang Journal of Solid State Chemistry, Vol. 249 https://doi.org/10.1016/j.jssc.2017.02.022	journal	May 2017
Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li _2/12 Ni _3/12 Mn _7/12 ]O ₂ Verde, Michael G.; Liu, Haodong; Carroll, Kyler J. ACS Applied Materials & Interfaces, Vol. 6, Issue 21 https://doi.org/10.1021/am504701s	journal	October 2014
Communication—Enhancing the Electrochemical Performance of Lithium-Excess Layered Oxide Li _1.13 Ni _0.3 Mn _0.57 O ₂ via a Facile Nanoscale Surface Modification Liu, Haodong; Huang, Jiajia; Qian, Danna Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0821606jes	journal	January 2016
Composition Optimization of Layered Lithium Nickel Manganese Cobalt Oxide Materials Synthesized via Ultrasonic Spray Pyrolysis Lengyel, Miklos; Zhang, Xiaofeng; Atlas, Gal Journal of The Electrochemical Society, Vol. 161, Issue 9 https://doi.org/10.1149/2.0681409jes	journal	January 2014
Synthesis–Structure–Property Relations in Layered, “Li-excess” Oxides Electrode Materials Li[Li[sub 1/3−2x/3]Ni[sub x]Mn[sub 2/3−x/3]]O[sub 2] (x=1/3, 1/4, and 1/5) Fell, Christopher R.; Carroll, Kyler J.; Chi, Miaofang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3473830	journal	January 2010
Modified Coprecipitation Synthesis of Mesostructure-Controlled Li-Rich Layered Oxides for Minimizing Voltage Degradation Zhang, Minghao; Liu, Haodong; Liu, Zhao ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00545	journal	June 2018
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries Kim, Donghan; Sandi, Giselle; Croy, Jason R. Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38 https://doi.org/10.1149/2.049301jes	journal	November 2012
General synthesis of xLi2MnO3·(1 − x)LiMn1/3Ni1/3Co1/3O2 nanomaterials by a molten-salt method: towards a high capacity and high power cathode for rechargeable lithium batteries Liu, Jinlong; Chen, Long; Hou, Mengyan Journal of Materials Chemistry, Vol. 22, Issue 48 https://doi.org/10.1039/c2jm35026b	journal	January 2012
Integrated Materials xLi[sub 2]MnO[sub 3]⋅(1−x)LiMn[sub 1/3]Ni[sub 1/3]Co[sub 1/3]O[sub 2] (x=0.3, 0.5, 0.7) Synthesized Amalraj, Francis; Kovacheva, Daniela; Talianker, Michael Journal of The Electrochemical Society, Vol. 157, Issue 10 https://doi.org/10.1149/1.3463782	journal	January 2010
Preparation and electrochemical performances of xLi2MnO3·(1-x) LiNi0.45Co0.2Mn0.35O2 (0 ≤ x ≤ 1) for high-power lithium-ion batteries Li, Xinlu; Long, Junjun; Su, Zelong Ceramics International, Vol. 44, Issue 14 https://doi.org/10.1016/j.ceramint.2018.06.150	journal	October 2018
The phase structure and electrochemical performance of xLi2MnO3·(1 − x)LiNi1/3Co1/3Mn1/3O2 during the synthesis and charge–discharge process Yuan, Ting; Liu, HongQuan; Gu, YiJie Applied Physics A, Vol. 122, Issue 9 https://doi.org/10.1007/s00339-016-0306-2	journal	August 2016
Effect of pristine nanostructure on first cycle electrochemical characteristics of lithium-rich lithium–nickel–cobalt–manganese-oxide cathode ceramics for lithium ion batteries Riekehr, Lars; Liu, Jinlong; Schwarz, Björn Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.11.082	journal	February 2016
General synthesis of xLi ₂ MnO ₃ ·(1 − x)LiNi _1/3 Co _1/3 Mn _1/3 O ₂ (x = 1/4, 1/3, and 1/2) hollow microspheres towards enhancing the performance of rechargeable lithium ion batteries Li, Jingfa; Li, Min; Zhang, Lei Journal of Materials Chemistry A, Vol. 4, Issue 32 https://doi.org/10.1039/C6TA04219H	journal	January 2016
A Search for the Optimum Lithium Rich Layered Metal Oxide Cathode Material for Li-Ion Batteries Ates, Mehmet Nurullah; Mukerjee, Sanjeev; Abraham, K. M. Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0481507jes	journal	January 2015
Li2MnO3 stabilized LiNi1/3Co1/3Mn1/3O2 cathode with improved performance for lithium ion batteries Li, Jiebin; Xu, Youlong; Li, Xifei Applied Surface Science, Vol. 285 https://doi.org/10.1016/j.apsusc.2013.08.042	journal	November 2013
Li1.2Mn0.54Ni0.13Co0.13O2-Encapsulated Carbon Nanofiber Network Cathodes with Improved Stability and Rate Capability for Li-ion Batteries Ma, Dingtao; Zhang, Peixin; Li, Yongliang Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep11257	journal	June 2015
Role of the composition of lithium-rich layered oxide materials on the voltage decay Peralta, David; Colin, Jean-François; Boulineau, Adrien Journal of Power Sources, Vol. 280 https://doi.org/10.1016/j.jpowsour.2015.01.146	journal	April 2015
Mechanochemical Synthesis of Li2MnO3 Shell/LiMO2 (M = Ni, Co, Mn) Core-Structured Nanocomposites for Lithium-Ion Batteries Noh, Jae-Kyo; Kim, Soo; Kim, Haesik Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04847	journal	May 2014
Performance of Wet Chemical Synthesized xLi₂MnO₃-(1-x)Li(Mn_0.375Ni_0.375Co_0.25)O₂(0.0 ≤ x ≤ 1.0) Integrated Cathode for Lithium Rechargeable Battery Ghanty, C.; Basu, R. N.; Majumder, S. B. Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.081207jes	journal	January 2012
Synthesis of Li-Rich NMC: A Comprehensive Study Pimenta, Vanessa; Sathiya, Mariyappan; Batuk, Dmitry Chemistry of Materials, Vol. 29, Issue 23 https://doi.org/10.1021/acs.chemmater.7b03230	journal	November 2017
Li-rich layered Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ derived from transition metal carbonate with a micro–nanostructure as a cathode material for high-performance Li-ion batteries Dai, Dongmei; Wang, Bao; Li, Bao RSC Advances, Vol. 6, Issue 99 https://doi.org/10.1039/C6RA21006F	journal	January 2016

Similar Records

Both cationic and anionic redox chemistry in a P2-type sodium layered oxide

Journal Article · 2020 · Nano Energy · OSTI ID:1593270

Wang, Peng-Fei; Xiao, Yao; Piao, Nan; +11 more

Both cationic and anionic redox chemistry in a P2-type sodium layered oxide

Journal Article · 2020 · Nano Energy · OSTI ID:1592180

Wang, Peng-Fei; Xiao, Yao; Piao, Nan; +11 more

Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries

Journal Article · 2018 · Energy & Environmental Science · OSTI ID:1757972

Kim, Un-Hyuck; Jun, Do-Wook; Park, Kang-Joon; +13 more

Related Subjects

Science & Technology - Other Topics
Materials Science

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

Citation Formats

References (192)

Similar Records

Related Subjects