Fire-extinguishing, recyclable liquefied gas electrolytes for temperature-resilient lithium-metal batteries

Yin, Yijie; Yang, Yangyuchen; Cheng, Diyi; Mayer, Matthew; Holoubek, John; Li, Weikang; Raghavendran, Ganesh; Liu, Alex; Lu, Bingyu; Davies, Daniel M.; Chen, Zheng; Borodin, Oleg; Meng, Y. Shirley

doi:10.1038/s41560-022-01051-4

Fire-extinguishing, recyclable liquefied gas electrolytes for temperature-resilient lithium-metal batteries

Journal Article · 01 June 2022 · Nature Energy

DOI:https://doi.org/10.1038/s41560-022-01051-4· OSTI ID:1978633

^[1]; ; Cheng, Diyi; Mayer, Matthew; ; Li, Weikang; ; Liu, Alex; Lu, Bingyu; Davies, Daniel M.; ; ;

OSTI

Not provided.

Research Organization:: Army Research Lab., Adelphi, MD (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: 89243319SEE000004; SC0012704

OSTI ID:: 1978633

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 6 Vol. 7; ISSN 2058-7546

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

References (50)

Emerging trends in sustainable battery chemistries Xu, Panpan; Tan, Darren H. S.; Chen, Zheng Trends in Chemistry, Vol. 3, Issue 8 https://doi.org/10.1016/j.trechm.2021.04.007	journal	August 2021
A Safer, Wide-Temperature Liquefied Gas Electrolyte Based on Difluoromethane Davies, Daniel M.; Yang, Yangyuchen; Sablina, Ekaterina S. Journal of Power Sources, Vol. 493 https://doi.org/10.1016/j.jpowsour.2021.229668	journal	May 2021
Liquefied gas electrolytes for electrochemical energy storage devices Rustomji, Cyrus S.; Yang, Yangyuchen; Kim, Tae Kyoung Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aal4263	journal	June 2017
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Fire-extinguishing organic electrolytes for safe batteries Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0033-8	journal	November 2017
Viscosity of Difluoromethane and Pentafluoroethane along the Saturation Line Sun, Li-Qun; Zhu, Ming-Shan; Han, Li-Zhong Journal of Chemical & Engineering Data, Vol. 41, Issue 2 https://doi.org/10.1021/je9502096	journal	January 1996
A short reaction mechanism for the combustion of dimethyl-ether Prince, Juan C.; Williams, Forman A. Combustion and Flame, Vol. 162, Issue 10 https://doi.org/10.1016/j.combustflame.2015.06.016	journal	October 2015
Making Li-metal electrodes rechargeable by controlling the dendrite growth direction Liu, Yadong; Liu, Qi; Xin, Le Nature Energy, Vol. 2, Issue 7 https://doi.org/10.1038/nenergy.2017.83	journal	June 2017
Viscosity of Saturated Liquid Dimethyl Ether from (227 to 343) K Wu, Jiangtao; Liu, Zhigang; Bi, Shengshan Journal of Chemical & Engineering Data, Vol. 48, Issue 2 https://doi.org/10.1021/je0256232	journal	January 2003
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.002	journal	August 2018
Liquefied gas electrolytes for wide-temperature lithium metal batteries Yang, Yangyuchen; Yin, Yijie; Davies, Daniel M. Energy & Environmental Science, Vol. 13, Issue 7 https://doi.org/10.1039/D0EE01446J	journal	January 2020
The Role of Sub- and Supercritical CO2 as “Processing Solvent” for the Recycling and Sample Preparation of Lithium Ion Battery Electrolytes Nowak, Sascha; Winter, Martin Molecules, Vol. 22, Issue 3 https://doi.org/10.3390/molecules22030403	journal	March 2017
A general purpose exchange‐correlation energy functional Laming, Gregory J.; Termath, Volker; Handy, Nicholas C. The Journal of Chemical Physics, Vol. 99, Issue 11 https://doi.org/10.1063/1.465598	journal	December 1993
High‐Safety and High‐Energy‐Density Lithium Metal Batteries in a Novel Ionic‐Liquid Electrolyte Sun, Hao; Zhu, Guanzhou; Zhu, Yuanmin Advanced Materials, Vol. 32, Issue 26 https://doi.org/10.1002/adma.202001741	journal	May 2020
From nanoscale interface characterization to sustainable energy storage using all-solid-state batteries Tan, Darren H. S.; Banerjee, Abhik; Chen, Zheng Nature Nanotechnology, Vol. 15, Issue 3 https://doi.org/10.1038/s41565-020-0657-x	journal	March 2020
Cryogenic Electron Microscopy for Characterizing and Diagnosing Batteries Wang, Xuefeng; Li, Yejing; Meng, Ying Shirley Joule, Vol. 2, Issue 11 https://doi.org/10.1016/j.joule.2018.10.005	journal	November 2018
Fluoromethane chemistry and its role in flame suppression Westmoreland, Phillip R.; Burgess, Donald R. F.; Zachariah, Michael R. Symposium (International) on Combustion, Vol. 25, Issue 1 https://doi.org/10.1016/S0082-0784(06)80795-2	journal	January 1994
Effect of cyclic phosphate additive in non-flammable electrolyte Ota, Hitoshi; Kominato, Asao; Chun, Wang-Jae Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00259-3	journal	June 2003
Suspension electrolyte with modified Li+ solvation environment for lithium metal batteries Kim, Mun Sek; Zhang, Zewen; Rudnicki, Paul E. Nature Materials, Vol. 21, Issue 4 https://doi.org/10.1038/s41563-021-01172-3	journal	January 2022
All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents Fan, Xiulin; Ji, Xiao; Chen, Long Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0474-3	journal	October 2019
Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature Holoubek, John; Liu, Haodong; Wu, Zhaohui Nature Energy, Vol. 6, Issue 3 https://doi.org/10.1038/s41560-021-00783-z	journal	February 2021
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Safer lithium ion batteries based on nonflammable electrolyte Zeng, Ziqi; Wu, Bingbin; Xiao, Lifen Journal of Power Sources, Vol. 279 https://doi.org/10.1016/j.jpowsour.2014.12.150	journal	April 2015
Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases Cao, Xia; Xu, Yaobin; Zhang, Linchao ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01926	journal	September 2019
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes Chen, Shuru; Zheng, Jianming; Yu, Lu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.002	journal	August 2018
Flammability of Li-Ion Battery Electrolytes: Flash Point and Self-Extinguishing Time Measurements Hess, Steffen; Wohlfahrt-Mehrens, Margret; Wachtler, Mario Journal of The Electrochemical Society, Vol. 162, Issue 2 https://doi.org/10.1149/2.0121502jes	journal	January 2015
Efficient Direct Recycling of Lithium-Ion Battery Cathodes by Targeted Healing Xu, Panpan; Dai, Qiang; Gao, Hongpeng Joule, Vol. 4, Issue 12 https://doi.org/10.1016/j.joule.2020.10.008	journal	December 2020
Polarizable Force Field Development and Molecular Dynamics Simulations of Ionic Liquids Borodin, Oleg The Journal of Physical Chemistry B, Vol. 113, Issue 33 https://doi.org/10.1021/jp905220k	journal	August 2009
Lithium-Ion Battery Storage for the Grid—A Review of Stationary Battery Storage System Design Tailored for Applications in Modern Power Grids Hesse, Holger; Schimpe, Michael; Kucevic, Daniel Energies, Vol. 10, Issue 12 https://doi.org/10.3390/en10122107	journal	December 2017
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes Yang, Yangyuchen; Davies, Daniel M.; Yin, Yijie Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.008	journal	August 2019
Moving beyond 99.9% Coulombic efficiency for lithium anodes in liquid electrolytes Hobold, Gustavo M.; Lopez, Jeffrey; Guo, Rui Nature Energy, Vol. 6, Issue 10 https://doi.org/10.1038/s41560-021-00910-w	journal	October 2021
High‐Energy Rechargeable Metallic Lithium Battery at −70 °C Enabled by a Cosolvent Electrolyte Dong, Xiaoli; Lin, Yuxiao; Li, Panlong Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201900266	journal	March 2019
Study on thermal decomposition properties and its decomposition mechanism of pentafluoroethane (HFC-125) fire extinguishing agent Wang, Ting; Hu, Ying-jie; Zhang, Pin Journal of Fluorine Chemistry, Vol. 190 https://doi.org/10.1016/j.jfluchem.2016.08.006	journal	October 2016
High-energy lithium metal pouch cells with limited anode swelling and long stable cycles Niu, Chaojiang; Lee, Hongkyung; Chen, Shuru Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0390-6	journal	May 2019
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization Cao, Xia; Ren, Xiaodi; Zou, Lianfeng Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0464-5	journal	September 2019
Recycling of lithium ion cells and batteries Lain, Michael J. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00600-0	journal	July 2001
Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes Banerjee, Abhik; Wang, Xuefeng; Fang, Chengcheng Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.0c00101	journal	June 2020
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201901381	journal	November 2019
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode Chen, Hao; Pei, Allen; Lin, Dingchang Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900858	journal	April 2019
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries Shiga, Tohru; Kato, Yuichi; Kondo, Hiroki Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA09915G	journal	January 2017
A new phosphate-based nonflammable electrolyte solvent for Li-ion batteries Wu, Lei; Song, Zhiping; Liu, Lishan Journal of Power Sources, Vol. 188, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.12.070	journal	March 2009
Sub-nanometer confinement enables facile condensation of gas electrolyte for low-temperature batteries Cai, Guorui; Yin, Yijie; Xia, Dawei Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23603-0	journal	June 2021
Evaluation of Fluorinated Alkyl Phosphates as Flame Retardants in Electrolytes for Li-Ion Batteries: II. Performance in Cell Xu, Kang; Zhang, Shengshui; Allen, Jan L. Journal of The Electrochemical Society, Vol. 150, Issue 2 https://doi.org/10.1149/1.1533041	journal	January 2003
Development of a recycling process for Li-ion batteries Georgi-Maschler, T.; Friedrich, B.; Weyhe, R. Journal of Power Sources, Vol. 207 https://doi.org/10.1016/j.jpowsour.2012.01.152	journal	June 2012
A review of lithium ion battery failure mechanisms and fire prevention strategies Wang, Qingsong; Mao, Binbin; Stoliarov, Stanislav I. Progress in Energy and Combustion Science, Vol. 73 https://doi.org/10.1016/j.pecs.2019.03.002	journal	July 2019
Vapor Pressure Measurements of Dimethyl Ether from (213 to 393) K Wu, Jiangtao; Yin, Jianguo Journal of Chemical & Engineering Data, Vol. 53, Issue 9 https://doi.org/10.1021/je800375t	journal	August 2008
Quantifying inactive lithium in lithium metal batteries Fang, Chengcheng; Li, Jinxing; Zhang, Minghao Nature, Vol. 572, Issue 7770 https://doi.org/10.1038/s41586-019-1481-z	journal	August 2019
Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy Wang, Jiangyan; Huang, William; Pei, Allen Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0413-3	journal	July 2019

Similar Records

Liquefied gas electrolytes for wide-temperature lithium metal batteries

Journal Article · 2020 · Energy & Environmental Science · OSTI ID:1635138

High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes

Journal Article · 2019 · Joule · OSTI ID:1614050

Related Subjects

Energy & Fuels
Materials Science

Fire-extinguishing, recyclable liquefied gas electrolytes for temperature-resilient lithium-metal batteries

Citation Formats

References (50)

Similar Records

Related Subjects