Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Actinide–Oxygen Multiple Bonds from Air: Synthesis and Characterization of a Thorium Oxo Supported by Redox-Active Ligands

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c04947· OSTI ID:1978494
 [1];  [1];  [2];  [1];  [2];  [1];  [1];  [2];  [1]
  1. H. C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States
  2. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Florida State Univ., Tallahassee, FL (United States); Univ. of Pennsylvania, Philadelphia, PA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016568; SC0017259
OSTI ID:
1978494
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 38; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (47)

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O 2 ] 2+ journal August 2019
Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures journal August 2012
Chemistry of Actinide Centers in Heterogeneous Catalytic Transformations of Small Molecules journal April 2019
Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes journal October 2012
CO 2 conversion to phenyl isocyanates by uranium( vi ) bis(imido) complexes journal January 2020
The Effect of Guest Metal Ions on the Reduction Potentials of Uranium(VI) Complexes: Experimental and Theoretical Investigations journal January 2020
CO2 Activation with Formation of Uranium Carbonate Complexes in a Closed Synthetic Cycle journal January 2020
Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions journal July 2020
Two-Electron Oxidative Atom Transfer at a Homoleptic, Tetravalent Uranium Complex journal April 2020
Rare-earth metal and actinide organoimide chemistry journal January 2019
Metathesis of a U V imido complex: a route to a terminal U V sulfide journal January 2017
Synthesis and X-ray crystal structure of [Na(18-crown-6)][U(Cp*)2(SBut)(S)], the first f-element compound containing a metal–sulfur double bond journal January 1999
Synthesis of Uranium–Ligand Multiple Bonds by Cleavage of a Trityl Protecting Group journal December 2013
Systematic Investigation of Thorium(IV)– and Uranium(IV)–Ligand Bonding in Dithiophosphonate, Thioselenophosphinate, and Diselenophosphonate Complexes journal August 2013
A Complete Family of Terminal Uranium Chalcogenides, [U(E)(N{SiMe 3 } 2 ) 3 ] − (E = O, S, Se, Te) journal September 2012
Thorium–ligand multiple bonds via reductive deprotection of a trityl group journal January 2015
Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies journal August 2011
Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride journal January 2019
Reactivity of a Lewis Base Supported Thorium Terminal Imido Metallocene toward Small Organic Molecules journal May 2017
A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes journal August 2016
An Alkali-Metal Halide-Bridged Actinide Phosphinidiide Complex journal January 2019
Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides journal August 2015
Organoactinide-Catalyzed Intermolecular Hydroamination of Terminal Alkynes journal January 1996
A Base-Free Terminal Actinide Phosphinidene Metallocene: Synthesis, Structure, Reactivity, and Computational Studies journal October 2018
Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics journal August 2016
Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand journal January 2012
Use of 77 Se and 125 Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(E n ){N(SiMe 3 ) 2 } 3 ] − (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners journal January 2016
Thorium journal September 2003
Reintroducing Thorium journal November 2009
Properties of Thorium Oxide Ceramics journal February 1957
Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination journal September 2017
Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11 journal June 2013
Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O2 at an Iron(II)-Cyclam Center journal March 2020
Crystalline amidocerium(iv) oxides and a side-on bridging dioxygen complex journal January 2010
{HB(3,5-Me2pz)3}2Sm(.eta.2-O2): First Example of a Lanthanide Superoxo Complex journal July 1995
Elucidation of Thorium Redox-Active Ligand Complexes: Evidence for a Thorium-Tri(radical) Species journal September 2021
Expanding the Chemistry of Molecular U 2+ Complexes: Synthesis, Characterization, and Reactivity of the {[C 5 H 3 (SiMe 3 ) 2 ] 3 U} − Anion journal December 2015
An improved method for the computation of ligand steric effects based on solid angles journal January 2006
Dimethylsilyl bis(amidinate)actinide complexes: synthesis and reactivity towards oxygen containing substrates journal January 2014
Trimethylphosphine oxide complexes of thorium and uranium tetra-nitrates; crystal structures of ten- and twelve-co-ordinate complex ions, bis[trinitratotetrakis(trimethylphosphine oxide)thorium( IV )] hexa-nitratothorate( IV ) and tetraphenylphosphonium pentanitratobis(tri-methylphosphine oxide)thorate( IV ) journal January 1978
Complexes of diamagnetic cations with radical anion ligands journal November 2020
EasySpin, a comprehensive software package for spectral simulation and analysis in EPR journal January 2006
Triplet Ground State Derivative of Aza- m -xylylene Diradical with Large Singlet−Triplet Energy Gap journal April 2011
In-Plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes journal October 2019
Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives journal December 2012
A bipyridyl thorium metallocene: synthesis, structure and reactivity journal January 2012
Formation of Inclusion Organoactinide Complexes with Boron-Containing Macrocycles journal March 2004

Similar Records

Related Subjects

Chemistry