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Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d 6 Charge-Transfer Chromophores

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c04945· OSTI ID:1978493

Not provided.

Research Organization:
Michigan State Univ., East Lansing, MI (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-01ER15282
OSTI ID:
1978493
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 27; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (57)

Is Iron the New Ruthenium? journal February 2019
Luminescent First-Row Transition Metal Complexes journal September 2021
Multi‐Photon Excitation in Photoredox Catalysis: Concepts, Applications, Methods journal April 2020
Acid−Base Equilibria of (2,2‘-Bipyridyl-4,4‘-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania journal December 1999
Strongly Coupled Cyclometalated Ruthenium Triarylamine Chromophores as Sensitizers for DSSCs journal May 2016
Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis journal November 2021
Mechanistic Origin of Photoredox Catalysis Involving Iron(II) Polypyridyl Chromophores journal September 2020
Organocatalytic Enantioselective Alkylation of Aldehydes with [Fe(bpy) 3 ]Br 2 Catalyst and Visible Light journal September 2015
Photochemical Synthesis of Carbazoles Using an [Fe(phen) 3 ](NTf 2 ) 2 /O 2 Catalyst System: Catalysis toward Sustainability journal September 2016
Electronic structure in the transition metal block and its implications for light harvesting journal January 2019
Towards longer-lived metal-to-ligand charge transfer states of iron(ii) complexes: an N-heterocyclic carbene approach journal January 2013
Long-Lived, Strongly Emissive, and Highly Reducing Excited States in Mo(0) Complexes with Chelating Isocyanides journal August 2019
Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex journal June 2019
When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands journal June 2020
In Pursuit of Panchromatic Absorption in Metal Coordination Complexes: Experimental Delineation of the HOMO Inversion Model Using Pseudo-Octahedral Complexes of Diarylamido Ligands journal November 2020
Iron(ii) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes journal November 2019
Bidentate Pyridyl‐NHC Ligands: Synthesis, Ground and Excited State Properties of Their Iron(II) Complexes and the Role of the fac/mer Isomerism journal December 2021
A new record excited state 3 MLCT lifetime for metalorganic iron( ii ) complexes journal January 2016
Leveraging excited-state coherence for synthetic control of ultrafast dynamics journal June 2020
A Modular Approach to Light Capture and Synthetic Tuning of the Excited-State Properties of Fe(II)-Based Chromophores journal May 2021
Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1−xFex(ptz)6(BF4)2 spin-crossover systems journal March 1986
Intersystem crossing in the [Fe(ptz) 6 ](BF 4 ) 2 spin crossover system (ptz=1‐propyltetrazole) journal February 1991
Spin-crossover cobalt(III) complexes: steric and electronic control of spin state journal December 1987
An Efficient Preparation of 4, 4′-Dicarboxy-2, 2′-Bipyridine journal December 1995
Syntheses, Characterizations, and Properties of Electronically Perturbed 1,1‘-Dimethyl-2,2‘-bipyridinium Tetrafluoroborates journal November 2005
A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalyst journal January 2001
Direct light-induced polymerization of cobalt-based redox shuttles: an ultrafast way towards stable dye-sensitized solar cells journal January 2015
Mononuclear cobalt(III) and iron(II) complexes with diimine ligands: Synthesis, structure, DNA binding and cleavage activities, and oxidation of 2-aminophenol journal August 2012
Turning {M(tpy)2}n+ embraces and CH⋯π interactions on and off in homoleptic cobalt(ii) and cobalt(iii) bis(2,2′:6′,2″-terpyridine) complexes journal January 2010
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
Crystal structure refinement with SHELXL journal January 2015
An empirical correction for absorption anisotropy journal January 1995
Termaufspaltung in Kristallen journal January 1929
The Theory of Complex Spectra II journal May 1931
Theory of Complex Spectra. II journal November 1942
Studies of Absorption Spectra VIII. Three and More d-Electrons in Cubic Crystal Fields. journal January 1955
Ligand-field theory journal January 1957
On the Absorption Spectra of Complex Ions. I journal September 1954
On the Absorption Spectra of Complex Ions II journal September 1954
Electronic structures of hexacyanometalate complexes journal July 1968
Position of the 3T1g .rarw. 1A1g transition in hexacyanocobaltate(III). Analysis of absorption and emission results journal May 1979
383. The oxidation–reduction potentials of some copper complexes journal January 1961
Charge-transfer luminescence from ruthenium(II) complexes containing tridentate ligands journal January 1981
Electron transfer quenching of nonemitting excited states of Ru(TPP)(py)2 and Ru(trpy)22+ journal July 1978
Photochemistry and photophysics of bis(terpyridyl) complexes of ruthenium(II) in fluid solution. Evidence for the formation of an .eta.2-diphenylterpyridine complex journal March 1985
Experimental and Computational Exploration of Ground and Excited State Properties of Highly Strained Ruthenium Terpyridine Complexes journal July 2013
Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by iron(III), chromium(III), and europium(III) ions journal October 1976
Direct observation of metal-to-ligand charge-transfer (MLCT) excited states of pentaammineruthenium(II) complexes journal April 1987
Dynamics of the 3 MLCT in Ru(II) Terpyridyl Complexes Probed by Ultrafast Spectroscopy: Evidence of Excited-State Equilibration and Interligand Electron Transfer journal November 2012
The triplet excited state of ruthenium(ii) bis(2,2′:6′,2″-terpyridine): Comparison between experiment and theory journal January 2004
Nonradiative Transition of Phosphorescent Charge-Transfer States of Ruthenium(II)-to-2,2‘-Biquinoline and Ruthenium(II)-to-2,2‘:6‘,2‘‘-Terpyridine in the Solid State journal May 1998
CCDC 2104359: Experimental Crystal Structure Determination dataset January 2021
Tuning the Redox Potentials and Ligand Field Strength of Fe(II) Polypyridines: The Dual π-Donor and π-Acceptor Character of Bipyridine journal April 2018
MO-Berechnungen an Heterocyclen, 24. Mitt.: Eine Interpretation der UPS der 2,2?-und 4,4?-Bipyridyle und deren N-Monoxide journal January 1981
2,2'-Bipyridine Complexes. I. Polarized Crystal Spectra of Tris (2,2'-bipyridine)copper(II), -nickel(II), -cobalt(II), -iron(II), and -ruthenium(II) journal May 1966
Insights into the excited state dynamics of Fe( ii ) polypyridyl complexes from variable-temperature ultrafast spectroscopy journal January 2019