Excited State Magneto-Structural Correlations Related to Photoinduced Electron Spin Polarization

Kirk, Martin L.; Shultz, David A.; Hewitt, Patrick; Chen, Ju; van der Est, Art

doi:10.1021/jacs.2c03490

Excited State Magneto-Structural Correlations Related to Photoinduced Electron Spin Polarization

Journal Article · 08 July 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.2c03490· OSTI ID:1978484

^[1]; ^[2]; Hewitt, Patrick ^[2]; Chen, Ju ^[3]; van der Est, Art ^[4]

Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, New Mexico 87131-0001, United States; The Center for High Technology Materials, The University of New Mexico, Albuquerque, New Mexico 87106, United States; Center for Quantum Information and Control (CQuIC), The University of New Mexico, Albuquerque, New Mexico 87131-0001, United States; OSTI
Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States
Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, New Mexico 87131-0001, United States
Department of Chemistry, Brock University, St. Catharines, Ontario L2S 3A1, Canada

Not provided.

Research Organization:: North Carolina State University, Raleigh, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0020199;

OSTI ID:: 1978484

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 28 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (47)

Exploring the Organometallic Route to Molecular Spin Qubits: The [CpTi(cot)] Case Camargo, Luana C.; Briganti, Matteo; Santana, Francielli S. Angewandte Chemie International Edition, Vol. 60, Issue 5 https://doi.org/10.1002/anie.202009634	journal	November 2020
Excited States and Optical Spectroscopy of Nitronyl Nitroxides and their Lanthanide and Transition Metal Complexes Bussiere, Guillaume; Beaulac, Remi; B??lisle, Hugo Transition Metal and Rare Earth Compounds https://doi.org/10.1007/b96861	book	January 2012
Transient ESR nutation signals in excited aromatic triplet states Furrer, R.; Fujara, P.; Lange, C. Chemical Physics Letters, Vol. 75, Issue 2 https://doi.org/10.1016/0009-2614(80)80526-4	journal	October 1980
Platinum(II) diimine dithiolates. New solution luminescent complexes Zuleta, Juan A.; Burberry, Mitch S.; Eisenberg, Richard Coordination Chemistry Reviews, Vol. 97 https://doi.org/10.1016/0010-8545(90)80079-9	journal	January 1990
Platinum diimine complexes: towards a molecular photochemical device Hissler, Muriel; McGarrah, James E.; Connick, William B. Coordination Chemistry Reviews, Vol. 208, Issue 1 https://doi.org/10.1016/S0010-8545(00)00254-X	journal	October 2000
Luminescent platinum complexes: tuning and using the excited state Paw, Witold; Cummings, Scott D.; Adnan Mansour, M. Coordination Chemistry Reviews, Vol. 171 https://doi.org/10.1016/S0010-8545(98)90023-6	journal	April 1998
Transition metal complexes of donor–acceptor biradicals Kirk, Martin L.; Shultz, David A. Coordination Chemistry Reviews, Vol. 257, Issue 1 https://doi.org/10.1016/j.ccr.2012.07.007	journal	January 2013
Light-induced electron spin polarization in rigidly linked, strongly coupled triplet–doublet spin pairs Kandrashkin, Yuri; van der Est, Art Chemical Physics Letters, Vol. 379, Issue 5-6 https://doi.org/10.1016/j.cplett.2003.08.073	journal	October 2003
Towards quantum sensing with molecular spins Troiani, F.; Ghirri, A.; Paris, M. G. A. Journal of Magnetism and Magnetic Materials, Vol. 491 https://doi.org/10.1016/j.jmmm.2019.165534	journal	December 2019
Ground State Nuclear Magnetic Resonance Chemical Shifts Predict Charge-Separated Excited State Lifetimes Yang, Jing; Kersi, Dominic K.; Richers, Casseday P. Inorganic Chemistry, Vol. 57, Issue 21 https://doi.org/10.1021/acs.inorgchem.8b02087	journal	October 2018
Excited State Exchange Control of Photoinduced Electron Spin Polarization in Electronic Ground States Kirk, Martin L.; Shultz, David A.; Hewitt, Patrick The Journal of Physical Chemistry Letters, Vol. 13, Issue 3 https://doi.org/10.1021/acs.jpclett.1c03491	journal	January 2022
A Molecular Approach to Quantum Sensing Yu, Chung-Jui; von Kugelgen, Stephen; Laorenza, Daniel W. ACS Central Science, Vol. 7, Issue 5 https://doi.org/10.1021/acscentsci.0c00737	journal	April 2021
Spectroscopic and theoretical studies on the excited state in diimine dithiolate complexes of platinum(II) Zuleta, Juan A.; Bevilacqua, Joanne M.; Proserpio, Davide M. Inorganic Chemistry, Vol. 31, Issue 12 https://doi.org/10.1021/ic00038a019	journal	June 1992
Ligand Control of Donor–Acceptor Excited-State Lifetimes Yang, Jing; Kersi, Dominic K.; Giles, Logan J. Inorganic Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/ic500217y	journal	April 2014
Donor–Acceptor Ligand-to-Ligand Charge-Transfer Coordination Complexes of Nickel(II) Kramer, Wesley W.; Cameron, Lindsay A.; Zarkesh, Ryan A. Inorganic Chemistry, Vol. 53, Issue 16 https://doi.org/10.1021/ic5017214	journal	August 2014
Electron Donor−Bridge−Acceptor Molecules with Bridging Nitronyl Nitroxide Radicals: Influence of a Third Spin on Charge- and Spin-Transfer Dynamics Chernick, Erin T.; Mi, Qixi; Kelley, Richard F. Journal of the American Chemical Society, Vol. 128, Issue 13 https://doi.org/10.1021/ja0576435	journal	March 2006
Donor−Acceptor Biradicals as Ground State Analogues of Photoinduced Charge Separated States Kirk, Martin L.; Shultz, David A.; Depperman, Ezra C. Journal of the American Chemical Society, Vol. 129, Issue 7 https://doi.org/10.1021/ja065384t	journal	February 2007
Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System Kirk, Martin L.; Shultz, David A.; Depperman, Ezra C. Journal of the American Chemical Society, Vol. 134, Issue 18 https://doi.org/10.1021/ja300233a	journal	April 2012
Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects Kirk, Martin L.; Shultz, David A.; Stasiw, Daniel E. Journal of the American Chemical Society, Vol. 135, Issue 39 https://doi.org/10.1021/ja405354x	journal	September 2013
Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes Kirk, Martin L.; Shultz, David A.; Stasiw, Daniel E. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja4081887	journal	November 2013
Spectroscopic Signatures of Resonance Inhibition Reveal Differences in Donor–Bridge and Bridge–Acceptor Couplings Shultz, David A.; Kirk, Martin L.; Zhang, Jinyuan Journal of the American Chemical Society, Vol. 142, Issue 10 https://doi.org/10.1021/jacs.0c00326	journal	February 2020
Interaction of Photogenerated Spin Qubit Pairs with a Third Electron Spin in DNA Hairpins Lorenzo, Emmaline R.; Olshansky, Jacob H.; Abia, Daniel S. D. Journal of the American Chemical Society, Vol. 143, Issue 12 https://doi.org/10.1021/jacs.0c12645	journal	March 2021
Exploring Photogenerated Molecular Quartet States as Spin Qubits and Qudits Mayländer, Maximilian; Chen, Su; Lorenzo, Emmaline R. Journal of the American Chemical Society, Vol. 143, Issue 18 https://doi.org/10.1021/jacs.1c01620	journal	April 2021
Metal Ion Control of Photoinduced Electron Spin Polarization in Electronic Ground States Kirk, Martin L.; Shultz, David A.; Chen, Ju Journal of the American Chemical Society, Vol. 143, Issue 28 https://doi.org/10.1021/jacs.1c04149	journal	July 2021
Photogenerated Spin-Correlated Radical Pairs: From Photosynthetic Energy Transduction to Quantum Information Science Harvey, Samantha M.; Wasielewski, Michael R. Journal of the American Chemical Society, Vol. 143, Issue 38 https://doi.org/10.1021/jacs.1c07706	journal	September 2021
Determining the Conformational Landscape of σ and π Coupling Using para -Phenylene and “Aviram–Ratner” Bridges Stasiw, Daniel E.; Zhang, Jinyuan; Wang, Guangbin Journal of the American Chemical Society, Vol. 137, Issue 29 https://doi.org/10.1021/jacs.5b04629	journal	July 2015
Excited State Magnetic Exchange Interactions Enable Large Spin Polarization Effects Stein, Benjamin W.; Tichnell, Christopher R.; Chen, Ju Journal of the American Chemical Society, Vol. 140, Issue 6 https://doi.org/10.1021/jacs.7b11397	journal	February 2018
Scaling Up Electronic Spin Qubits into a Three-Dimensional Metal–Organic Framework Yamabayashi, Tsutomu; Atzori, Matteo; Tesi, Lorenzo Journal of the American Chemical Society, Vol. 140, Issue 38 https://doi.org/10.1021/jacs.8b06733	journal	August 2018
Covalent Radical Pairs as Spin Qubits: Influence of Rapid Electron Motion between Two Equivalent Sites on Spin Coherence Wu, Yilei; Zhou, Jiawang; Nelson, Jordan N. Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b08105	journal	September 2018
Wave Function Control of Charge-Separated Excited-State Lifetimes Tichnell, Christopher R.; Daley, David R.; Stein, Benjamin W. Journal of the American Chemical Society, Vol. 141, Issue 9 https://doi.org/10.1021/jacs.8b13011	journal	February 2019
Photogenerated Spin-Entangled Qubit (Radical) Pairs in DNA Hairpins: Observation of Spin Delocalization and Coherence Olshansky, Jacob H.; Krzyaniak, Matthew D.; Young, Ryan M. Journal of the American Chemical Society, Vol. 141, Issue 5 https://doi.org/10.1021/jacs.8b13155	journal	January 2019
The Second Quantum Revolution: Role and Challenges of Molecular Chemistry Atzori, Matteo; Sessoli, Roberta Journal of the American Chemical Society, Vol. 141, Issue 29 https://doi.org/10.1021/jacs.9b00984	journal	June 2019
Selectively Addressable Photogenerated Spin Qubit Pairs in DNA Hairpins Olshansky, Jacob H.; Zhang, Jinyuan; Krzyaniak, Matthew D. Journal of the American Chemical Society, Vol. 142, Issue 7 https://doi.org/10.1021/jacs.9b13398	journal	February 2020
Electron Spin Polarization of Functionalized Fullerenes. Reversed Quartet Mechanism Rozenshtein, Vladimir; Berg, Alexander; Stavitski, Eli The Journal of Physical Chemistry A, Vol. 109, Issue 49 https://doi.org/10.1021/jp0540104	journal	November 2005
Hyperfine Interaction, Spin Polarization, and Spin Delocalization as Probes of Donor−Bridge−Acceptor Interactions in Exchange-Coupled Biradicals Kirk, Martin L.; Shultz, David A.; Habel-Rodriguez, Diana The Journal of Physical Chemistry B, Vol. 114, Issue 45 https://doi.org/10.1021/jp102955j	journal	June 2010
Exploiting chemistry and molecular systems for quantum information science Wasielewski, Michael R.; Forbes, Malcolm D. E.; Frank, Natia L. Nature Reviews Chemistry, Vol. 4, Issue 9 https://doi.org/10.1038/s41570-020-0200-5	journal	July 2020
Synthesis, structures and properties of a new series of platinum–diimine–dithiolate complexes Adams, Christopher J.; Fey, Natalie; Parfitt, Matthew Dalton Transactions, Issue 39 https://doi.org/10.1039/B709252K	journal	January 2007
Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization Kirk, Martin L.; Shultz, David A.; Hewitt, Patrick Chemical Science, Vol. 12, Issue 41 https://doi.org/10.1039/D1SC02965G	journal	January 2021
Phenol-substituted nitronyl nitroxide biradicals with a triplet (S = 1) ground state Hase, Syuichiro; Shiomi, Daisuke; Sato, Kazunobu Journal of Materials Chemistry, Vol. 11, Issue 3 https://doi.org/10.1039/b007316o	journal	January 2001
A slow relaxing species for molecular spin devices: EPR characterization of static and dynamic magnetic properties of a nitronyl nitroxide radical Collauto, A.; Mannini, M.; Sorace, L. Journal of Materials Chemistry, Vol. 22, Issue 41 https://doi.org/10.1039/c2jm35076a	journal	January 2012
Transferrable property relationships between magnetic exchange coupling and molecular conductance Kirk, Martin L.; Dangi, Ranjana; Habel-Rodriguez, Diana Chemical Science, Vol. 11, Issue 42 https://doi.org/10.1039/d0sc04350h	journal	January 2020
Electron spin polarization of the excited quartet state of strongly coupled triplet–doublet spin systems Kandrashkin, Yuri; van der Est, Art The Journal of Chemical Physics, Vol. 120, Issue 10 https://doi.org/10.1063/1.1645773	journal	March 2004
A phenomenological scheme for reversed quartet mechanism of electron spin polarization in covalently linked systems of chromophore and free radical: Determination of magnitude of polarization and application to pyrene–TEMPO linked molecules Tripathi, Alok Kumar; Rane, Vinayak; Kundu, Sushma The Journal of Chemical Physics, Vol. 151, Issue 15 https://doi.org/10.1063/1.5124731	journal	October 2019
Long-range spin dependent delocalization promoted by the pseudo Jahn-Teller effect Stein, Benjamin W.; Dickie, Diane A.; Nedungadi, Sachin The Journal of Chemical Physics, Vol. 151, Issue 20 https://doi.org/10.1063/1.5128117	journal	November 2019
CNOT gate operation on a photogenerated molecular electron spin-qubit pair Nelson, Jordan N.; Zhang, Jinyuan; Zhou, Jiawang The Journal of Chemical Physics, Vol. 152, Issue 1 https://doi.org/10.1063/1.5128132	journal	January 2020
Electron Transfer in Cyanobacterial Photosystem I Xu, Wu; Chitnis, Parag; Valieva, Alfia Journal of Biological Chemistry, Vol. 278, Issue 30 https://doi.org/10.1074/jbc.M302962200	journal	July 2003
Quantum sensing Degen, C. L.; Reinhard, F.; Cappellaro, P. Reviews of Modern Physics, Vol. 89, Issue 3 https://doi.org/10.1103/RevModPhys.89.035002	journal	July 2017

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