An Exploration of Sulfur Redox in Lithium Battery Cathodes

Zak, Joshua J.; Kim, Seong Shik; Laskowski, Forrest A.  L.; See, Kimberly A.

doi:10.1021/jacs.2c02668

An Exploration of Sulfur Redox in Lithium Battery Cathodes

Journal Article · 02 June 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.2c02668· OSTI ID:1978480

^[1]; ^[1]; ^[1]; ^[1]

Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States

Not provided.

Research Organization:: Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019381

OSTI ID:: 1978480

Journal Information:: Journal of the American Chemical Society, Vol. 144, Issue 23; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (96)

Promises and Challenges of Next-Generation “Beyond Li-ion” Batteries for Electric Vehicles and Grid Decarbonization Tian, Yaosen; Zeng, Guobo; Rutt, Ann Chemical Reviews, Vol. 121, Issue 3 https://doi.org/10.1021/acs.chemrev.0c00767	journal	December 2020
LixCoO2 (0<-1): A new cathode material for batteries of high energy density Mizushima, K.; Jones, P. C.; Wiseman, P. J. Materials Research Bulletin, Vol. 15, Issue 6 https://doi.org/10.1016/0025-5408(80)90012-4	journal	June 1980
Macroporous Li(Ni1/3Co1/3Mn1/3)O2: A High-Power and High-Energy Cathode for Rechargeable Lithium Batteries Shaju, K. M.; Bruce, P. G. Advanced Materials, Vol. 18, Issue 17 https://doi.org/10.1002/adma.200600958	journal	September 2006
Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries Chen, C. H.; Liu, J.; Stoll, M. E. Journal of Power Sources, Vol. 128, Issue 2 https://doi.org/10.1016/j.jpowsour.2003.10.009	journal	April 2004
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Optimized LiFePO[sub 4] for Lithium Battery Cathodes Yamada, A.; Chung, S. C.; Hinokuma, K. Journal of The Electrochemical Society, Vol. 148, Issue 3 https://doi.org/10.1149/1.1348257	journal	January 2001
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials Radin, Maxwell D.; Vinckeviciute, Julija; Seshadri, Ram Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0439-6	journal	July 2019
First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk House, Robert A.; Rees, Gregory J.; Pérez-Osorio, Miguel A. Nature Energy, Vol. 5, Issue 10 https://doi.org/10.1038/s41560-020-00697-2	journal	September 2020
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Direct Visualization of the Reversible O ²⁻ /O ⁻ Redox Process in Li-Rich Cathode Materials Li, Xiang; Qiao, Yu; Guo, Shaohua Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201705197	journal	February 2018
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries McCalla, E.; Abakumov, A. M.; Saubanere, M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aac8260	journal	December 2015
Surface Lithium Carbonate Influences Electrolyte Degradation via Reactive Oxygen Attack in Lithium-Excess Cathode Materials Kaufman, Lori A.; McCloskey, Bryan D. Chemistry of Materials, Vol. 33, Issue 11 https://doi.org/10.1021/acs.chemmater.1c00935	journal	May 2021
Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Electrodes Renfrew, Sara E.; McCloskey, Bryan D. ACS Applied Energy Materials, Vol. 2, Issue 5 https://doi.org/10.1021/acsaem.9b00459	journal	April 2019
Quantifying the Capacity Contributions during Activation of Li ₂ MnO ₃ Rana, Jatinkumar; Papp, Joseph K.; Lebens-Higgins, Zachary ACS Energy Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsenergylett.9b02799	journal	January 2020
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO ₂ and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides Renfrew, Sara E.; McCloskey, Bryan D. Journal of the American Chemical Society, Vol. 139, Issue 49 https://doi.org/10.1021/jacs.7b08461	journal	November 2017
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
Infrared study of lithium intercalated phases in the LixFeS2 system (0 ⩽ x ⩽ 2). Characterization of a new iron disulfide Gard, P.; Sourisseau, C.; Ouvrard, G. Solid State Ionics, Vol. 20, Issue 3 https://doi.org/10.1016/0167-2738(86)90221-3	journal	May 1986
Anion–Cation Redox Competition and the Formation of New Compounds in Highly Covalent Systems Rouxel, Jean Chemistry - A European Journal, Vol. 2, Issue 9 https://doi.org/10.1002/chem.19960020904	journal	September 1996
Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping Liu, Qi; Su, Xin; Lei, Dan Nature Energy, Vol. 3, Issue 11 https://doi.org/10.1038/s41560-018-0180-6	journal	June 2018
Electrointercalation in transition-metal disulphides Whittingham, M. Stanley Journal of the Chemical Society, Chemical Communications, Issue 9 https://doi.org/10.1039/c39740000328	journal	January 1974
Electrical Energy Storage and Intercalation Chemistry Whittingham, M. S. Science, Vol. 192, Issue 4244 https://doi.org/10.1126/science.192.4244.1126	journal	June 1976
Chemistry of intercalation compounds: Metal guests in chalcogenide hosts Whittingham, M. Stanley Progress in Solid State Chemistry, Vol. 12, Issue 1 https://doi.org/10.1016/0079-6786(78)90003-1	journal	January 1978
Tracking the Chemical and Structural Evolution of the TiS ₂ Electrode in the Lithium-Ion Cell Using Operando X-ray Absorption Spectroscopy Zhang, Liang; Sun, Dan; Kang, Jun Nano Letters, Vol. 18, Issue 7 https://doi.org/10.1021/acs.nanolett.8b01680	journal	June 2018
Electronic structures and charge transfer in lithium and mercury intercalated titanium disulfides Moreau, P.; Ouvrard, G.; Gressier, P. Journal of Physics and Chemistry of Solids, Vol. 57, Issue 6-8 https://doi.org/10.1016/0022-3697(95)00408-4	journal	June 1996
K- and L-edge X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) determination of differential orbital covalency (DOC) of transition metal sites Baker, Michael L.; Mara, Michael W.; Yan, James J. Coordination Chemistry Reviews, Vol. 345 https://doi.org/10.1016/j.ccr.2017.02.004	journal	August 2017
Experimental and theoretical studies of the electronic structure of Ti S 2 Wu, Z. Y.; Lemoigno, F.; Gressier, P. Physical Review B, Vol. 54, Issue 16 https://doi.org/10.1103/PhysRevB.54.R11009	journal	October 1996
Sulfur K -Edge X-Ray-Absorption Study of the Charge Transfer upon Lithium Intercalation into Titanium Disulfide Wu, Z. Y.; Ouvrard, G.; Lemaux, S. Physical Review Letters, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevLett.77.2101	journal	September 1996
In situ studies of electrode reactions: The mechanism of lithium intercalation in TiS2 Chianelli, R. R.; Scanlon, J. C.; Rao, B. M. L. Journal of Solid State Chemistry, Vol. 29, Issue 3 https://doi.org/10.1016/0022-4596(79)90189-0	journal	September 1979
In situ X-ray diffraction experiments on lithium intercalation compounds Dahn, J. R.; Py, M. A.; Haering, R. R. Canadian Journal of Physics, Vol. 60, Issue 3 https://doi.org/10.1139/p82-040	journal	March 1982
Dynamic Hosts for High-Performance Li–S Batteries Studied by Cryogenic Transmission Electron Microscopy and in Situ X-ray Diffraction Liu, Xiao-Chen; Yang, Yao; Wu, Jingjie ACS Energy Letters, Vol. 3, Issue 6 https://doi.org/10.1021/acsenergylett.8b00561	journal	May 2018
Operando Synchrotron X-ray Diffraction Studies on TiS₂: The Effect of Propylene Carbonate on Reduction Mechanism Houdeville, Raphaëlle G.; Black, Ashley P.; Ponrouch, Alexandre Journal of The Electrochemical Society, Vol. 168, Issue 3 https://doi.org/10.1149/1945-7111/abe983	journal	March 2021
Lithium intercalation in cubic TiS2 Sinha, S.; Murphy, D. Solid State Ionics, Vol. 20, Issue 1 https://doi.org/10.1016/0167-2738(86)90038-X	journal	February 1986
The Effect of Crystal Face of Fe2O3 on the Electrochemical Performance for Lithium-ion Batteries Chen, Minmin; Zhao, Enyue; Yan, Qingbo Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep29381	journal	July 2016
Growth and characterization of thin oriented Co3O4 (111) films obtained by decomposition of layered cobaltates Na CoO2 Buršík, Josef; Soroka, Miroslav; Kužel, Radomír Journal of Solid State Chemistry, Vol. 227 https://doi.org/10.1016/j.jssc.2015.03.014	journal	July 2015
Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries Shi-Yu, Chen; Zhao-Xiang, Wang Acta Physico-Chimica Sinica, Vol. 27, Issue 01 https://doi.org/10.3866/PKU.WHXB20110134	journal	January 2011
TiS2–MWCNT hybrid as high performance anode in lithium-ion battery Kartick, B.; Srivastava, Suneel Kumar; Mahanty, Sourindra Journal of Nanoparticle Research, Vol. 15, Issue 9 https://doi.org/10.1007/s11051-013-1950-5	journal	August 2013
Understanding Li Diffusion in Li-Intercalation Compounds Van der Ven, Anton; Bhattacharya, Jishnu; Belak, Anna A. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar200329r	journal	May 2012
Lithium intercalation into TiS2 cathode material: phase equilibria in a Li–TiS2 system Suslov, Evgeny A.; Bushkova, Olga V.; Sherstobitova, Elena A. Ionics, Vol. 22, Issue 4 https://doi.org/10.1007/s11581-015-1566-0	journal	October 2015
The crystal and molecular structure of orthorhombic sulfur Abrahams, S. C. Acta Crystallographica, Vol. 8, Issue 11 https://doi.org/10.1107/S0365110X55002089	journal	November 1955
Refinement of the structure of orthorhombic sulfur, α-S8 Rettig, S. J.; Trotter, J. Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 12 https://doi.org/10.1107/S0108270187088152	journal	December 1987
Data-Driven Review of Thermoelectric Materials: Performance and Resource Considerations Gaultois, Michael W.; Sparks, Taylor D.; Borg, Christopher K. H. Chemistry of Materials, Vol. 25, Issue 15 https://doi.org/10.1021/cm400893e	journal	May 2013
Abundances of chemical elements in the Earth’s crust Yaroshevsky, A. A. Geochemistry International, Vol. 44, Issue 1 https://doi.org/10.1134/S001670290601006X	journal	January 2006
New Element-Carbon (p-p)? Bonds Jutzi, Peter Angewandte Chemie International Edition in English, Vol. 14, Issue 4 https://doi.org/10.1002/anie.197502321	journal	April 1975
High-Performance All-Solid-State Lithium–Sulfur Battery Enabled by a Mixed-Conductive Li ₂ S Nanocomposite Han, Fudong; Yue, Jie; Fan, Xiulin Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01754	journal	June 2016
Recent research trends in Li–S batteries Kumar, Rudra; Liu, Jie; Hwang, Jang-Yeon Journal of Materials Chemistry A, Vol. 6, Issue 25 https://doi.org/10.1039/C8TA01483C	journal	January 2018
Polysulfide Shuttle Study in the Li/S Battery System Mikhaylik, Yuriy V.; Akridge, James R. Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976 https://doi.org/10.1149/1.1806394	journal	January 2004
Recent Advances in Electrolytes for Lithium-Sulfur Batteries Zhang, Shiguo; Ueno, Kazuhide; Dokko, Kaoru Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201500117	journal	April 2015
Fabrication of favorable interface between sulfide solid electrolyte and Li metal electrode for bulk-type solid-state Li/S battery Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro Electrochemistry Communications, Vol. 22 https://doi.org/10.1016/j.elecom.2012.06.015	journal	August 2012
All Solid-State Lithium–Sulfur Battery Using a Glass-Type P ₂ S ₅ –Li ₂ S Electrolyte: Benefits on Anode Kinetics Yamada, Takanobu; Ito, Seitaro; Omoda, Ryo Journal of The Electrochemical Society, Vol. 162, Issue 4 https://doi.org/10.1149/2.0441504jes	journal	January 2015
High-Conductivity Argyrodite Li ₆ PS ₅ Cl Solid Electrolytes Prepared via Optimized Sintering Processes for All-Solid-State Lithium–Sulfur Batteries Wang, Shuo; Zhang, Yibo; Zhang, Xue ACS Applied Materials & Interfaces, Vol. 10, Issue 49 https://doi.org/10.1021/acsami.8b15121	journal	November 2018
CNTs@S composite as cathode for all-solid-state lithium-sulfur batteries with ultralong cycle life Zhang, Qiang; Huang, Ning; Huang, Zhen Journal of Energy Chemistry, Vol. 40 https://doi.org/10.1016/j.jechem.2019.03.006	journal	January 2020
Li2S nanocomposites underlying high-capacity and cycling stability in all-solid-state lithium–sulfur batteries Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Power Sources, Vol. 274 https://doi.org/10.1016/j.jpowsour.2014.10.043	journal	January 2015
All-Solid-State Lithium Secondary Battery with Li[sub 2]S–C Composite Positive Electrode Prepared by Spark-Plasma-Sintering Process Takeuchi, Tomonari; Kageyama, Hiroyuki; Nakanishi, Koji Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3486083	journal	January 2010
More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201606823	journal	April 2017
A Review of Solid-State Lithium–Sulfur Battery: Ion Transport and Polysulfide Chemistry Pan, Hui; Cheng, Zhu; He, Ping Energy & Fuels, Vol. 34, Issue 10 https://doi.org/10.1021/acs.energyfuels.0c02647	journal	September 2020
Ab Initio Structure Search and in Situ ⁷ Li NMR Studies of Discharge Products in the Li–S Battery System See, Kimberly A.; Leskes, Michal; Griffin, John M. Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508982p	journal	November 2014
Local Structure Evolution and Modes of Charge Storage in Secondary Li–FeS ₂ Cells Butala, Megan M.; Mayo, Martin; Doan-Nguyen, Vicky V. T. Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00070	journal	March 2017
Initial open circuit voltages and discharge reaction mechanisms in non-aqueous electrolyte Li/FeS2 cells Iwakura, Chiaki; Isobe, Noriyuki; Tamura, Hideo Electrochimica Acta, Vol. 28, Issue 3 https://doi.org/10.1016/0013-4686(83)85123-8	journal	March 1983
Electrochemistry of Pyrite-Based Cathodes for Ambient Temperature Lithium Batteries Fong, Rosamaría Journal of The Electrochemical Society, Vol. 136, Issue 11 https://doi.org/10.1149/1.2096426	journal	January 1989
Solid State Enabled Reversible Four Electron Storage Yersak, Thomas A.; Macpherson, H. Alex; Kim, Seul Cham Advanced Energy Materials, Vol. 3, Issue 1 https://doi.org/10.1002/aenm.201200267	journal	August 2012
Reinvestigation of Lithium Reaction Mechanisms in FeS[sub 2] Pyrite at Ambient Temperature Shao-Horn, Yang; Osmialowski, Steve; Horn, Quinn C. Journal of The Electrochemical Society, Vol. 149, Issue 12 https://doi.org/10.1149/1.1516772	journal	January 2002
The redox mechanism of FeS ₂ in non-aqueous electrolytes for lithium and sodium batteries Zhang, Sheng S. Journal of Materials Chemistry A, Vol. 3, Issue 15 https://doi.org/10.1039/C5TA00623F	journal	January 2015
Unraveling the Reaction Mechanism of FeS ₂ as a Li-Ion Battery Cathode Zou, Jian; Zhao, Jun; Wang, Bojun ACS Applied Materials & Interfaces, Vol. 12, Issue 40 https://doi.org/10.1021/acsami.0c14082	journal	September 2020
Biomass-Derived 3D Interconnected Porous Carbon-Encapsulated Nano-FeS₂ for High-Performance Lithium-Ion Batteries Xu, Xin; Ying, Hangjun; Zhang, Shunlong ACS Applied Energy Materials, Vol. 3, Issue 6 https://doi.org/10.1021/acsaem.0c00537	journal	May 2020
Interaction of FeS ₂ and Sulfur in Li-S Battery System Sun, Ke; Cama, Christina A.; DeMayo, Rachel A. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0041701jes	journal	September 2016
ELECTRONIC STRUCTURES OF FeS AND FeS 2 : X-RAY ABSORPTION SPECTROSCOPY AND BAND STRUCTURE CALCULATIONS Womes, M.; Karnatak, R. C.; Esteva, J. M. Journal of Physics and Chemistry of Solids, Vol. 58, Issue 2 https://doi.org/10.1016/S0022-3697(96)00068-6	journal	February 1997
Increasing the Band Gap of Iron Pyrite by Alloying with Oxygen Hu, Jun; Zhang, Yanning; Law, Matt Journal of the American Chemical Society, Vol. 134, Issue 32 https://doi.org/10.1021/ja3053464	journal	August 2012
High-Performance All-Solid-State Lithium-Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes Yao, Xiayin; Huang, Ning; Han, Fudong Advanced Energy Materials, Vol. 7, Issue 17 https://doi.org/10.1002/aenm.201602923	journal	May 2017
Thermodynamic Activation of Charge Transfer in Anionic Redox Process for Li-Ion Batteries Li, Biao; Jiang, Ning; Huang, Weifeng Advanced Functional Materials, Vol. 28, Issue 4 https://doi.org/10.1002/adfm.201704864	journal	November 2017
Exploring the bottlenecks of anionic redox in Li-rich layered sulfides Saha, Sujoy; Assat, Gaurav; Sougrati, Moulay Tahar Nature Energy, Vol. 4, Issue 11 https://doi.org/10.1038/s41560-019-0493-0	journal	November 2019
Delocalized Metal–Oxygen π-Redox Is the Origin of Anomalous Nonhysteretic Capacity in Li-Ion and Na-Ion Cathode Materials Kitchaev, Daniil A.; Vinckeviciute, Julija; Van der Ven, Anton Journal of the American Chemical Society, Vol. 143, Issue 4 https://doi.org/10.1021/jacs.0c10704	journal	January 2021
Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S Wang, Tian; Ren, Guo-Xi; Shadike, Zulipiya Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12310-6	journal	October 2019
Multielectron, Cation and Anion Redox in Lithium-Rich Iron Sulfide Cathodes Hansen, Charles J.; Zak, Joshua J.; Martinolich, Andrew J. Journal of the American Chemical Society, Vol. 142, Issue 14 https://doi.org/10.1021/jacs.0c00909	journal	March 2020
Mixed Cationic and Anionic Redox in Ni and Co Free Chalcogen-Based Cathode Chemistry for Li-Ion Batteries Nagarajan, Sudhan; Hwang, Sooyeon; Balasubramanian, Mahalingam Journal of the American Chemical Society, Vol. 143, Issue 38 https://doi.org/10.1021/jacs.1c06828	journal	September 2021
Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries Flamary-Mespoulie, Florian; Boulineau, Adrien; Martinez, Hervé Energy Storage Materials, Vol. 26 https://doi.org/10.1016/j.ensm.2019.12.033	journal	April 2020
Rock-salt-type lithium metal sulphides as novel positive-electrode materials Sakuda, Atsushi; Takeuchi, Tomonari; Okamura, Kazuhiro Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04883	journal	May 2014
A Reversible Rocksalt to Amorphous Phase Transition Involving Anion Redox Sakuda, Atsushi; Ohara, Koji; Kawaguchi, Tomoya Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-33518-4	journal	October 2018
Phase Relationships in Positive Electrodes of High Temperature Li ‐ Al / LiCl ‐ KCl / FeS2 Cells Tomczuk, Z.; Tani, B.; Otto, N. C. Journal of The Electrochemical Society, Vol. 129, Issue 5 https://doi.org/10.1149/1.2124067	journal	May 1982
Multicomponent Phase Diagrams for Battery Applications: II . Oxygen Impurities in the Battery Cathode Aselage, T. L.; Hellstrom, E. E. Journal of The Electrochemical Society, Vol. 134, Issue 8 https://doi.org/10.1149/1.2100793	journal	August 1987
An iron-57 Moessbauer study of the intermediates formed in the reduction of iron disulfide in the lithium/iron disulfide battery system Jones, C. H. W.; Kovacs, P. E.; Sharma, R. D. The Journal of Physical Chemistry, Vol. 95, Issue 2 https://doi.org/10.1021/j100155a053	journal	January 1991
Chemical and electrochemical study of the LixFeS2 cathodic system (0 < x ⩽ 2) Brec, R.; Dugast, A.; Le Mehauté, A. Materials Research Bulletin, Vol. 15, Issue 5 https://doi.org/10.1016/0025-5408(80)90142-7	journal	May 1980
Crystal structure of Li 2 FeS 2 Batchelor, R. J.; Einstein, F. W. B.; Jones, C. H. W. Physical Review B, Vol. 37, Issue 7 https://doi.org/10.1103/PhysRevB.37.3699	journal	March 1988
Transition-metal dichalcogenides from disintercalation processes. Crystal structure determination and Mossbauer study of Li ₂ FeS ₂ and its disintercalates Li _x FeS ₂ (0.2⩽x⩽2) Blandeau, L.; Ouvrard, G.; Calage, Y. Journal of Physics C: Solid State Physics, Vol. 20, Issue 27 https://doi.org/10.1088/0022-3719/20/27/007	journal	September 1987
Redox processes in the LixFeS2/Li electrochemical system studied through crystal, Mössbauer, and EXAFS analyses Brec, R.; Prouzet, E.; Ouvrard, G. Journal of Power Sources, Vol. 26, Issue 3-4 https://doi.org/10.1016/0378-7753(89)80142-9	journal	May 1989
Revealing Electronic Signatures of Lattice Oxygen Redox in Lithium Ruthenates and Implications for High-Energy Li-Ion Battery Material Designs Yu, Yang; Karayaylali, Pinar; Nowak, Stanisław H. Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b01821	journal	September 2019
High Performance Li ₂ Ru _{1– y} Mn _y O ₃ (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding Sathiya, M.; Ramesha, K.; Rousse, G. Chemistry of Materials, Vol. 25, Issue 7 https://doi.org/10.1021/cm400193m	journal	March 2013
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen Luo, Kun; Roberts, Matthew R.; Hao, Rong Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2471	journal	March 2016
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries Gu, Meng; Belharouak, Ilias; Zheng, Jianming ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn305065u	journal	December 2012
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
New developments in the Inorganic Crystal Structure Database (ICSD): accessibility in support of materials research and design Belsky, Alec; Hellenbrandt, Mariette; Karen, Vicky Lynn Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3 https://doi.org/10.1107/S0108768102006948	journal	May 2002
Competition between Metal Dissolution and Gas Release in Li-Rich Li ₃ Ru _y Ir _{1– y} O ₄ Model Compounds Showing Anionic Redox Jacquet, Quentin; Iadecola, Antonella; Saubanère, Matthieu Chemistry of Materials, Vol. 30, Issue 21 https://doi.org/10.1021/acs.chemmater.8b02955	journal	October 2018
Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3 Pearce, Paul E.; Perez, Arnaud J.; Rousse, Gwenaelle Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4864	journal	February 2017
How Bulk Sensitive is Hard X-ray Photoelectron Spectroscopy: Accounting for the Cathode–Electrolyte Interface when Addressing Oxygen Redox Lebens-Higgins, Zachary W.; Chung, Hyeseung; Zuba, Mateusz J. The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00229	journal	February 2020
CoO₂, The End Member of the Li_xCoO₂ Solid Solution Amatucci, G. G.; Tarascon, J. M.; Klein, L. C. Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123 https://doi.org/10.1149/1.1836594	journal	January 1996

Similar Records

Dihexyl-Substituted Poly(3,4-Propylenedioxythiophene) as a Dual Ionic and Electronic Conductive Cathode Binder for Lithium-Ion Batteries

Journal Article · 2020 · Chemistry of Materials · OSTI ID:1853164

Das, Pratyusha; Zayat, Billal; Wei, Qiulong; +15 more

Enhancing the Ionic Conductivity of Poly(3,4-propylenedioxythiophenes) with Oligoether Side Chains for Use as Conductive Cathode Binders in Lithium-Ion Batteries

Journal Article · 2022 · Chemistry of Materials · OSTI ID:1977794

Das, Pratyusha; Elizalde-Segovia, Rodrigo; Zayat, Billal; +9 more

Related Subjects

Chemistry

An Exploration of Sulfur Redox in Lithium Battery Cathodes

Citation Formats

References (96)

Similar Records

Related Subjects