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C–H Bond Activation by a Mononuclear Nickel(IV)-Nitrate Complex

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c02454· OSTI ID:1978476
 [1];  [2];  [1];  [2];  [1]
  1. Department of Chemistry and Biochemistry, Center for Biomolecular Structure and Dynamics, University of Montana, Missoula, Montana 59812, United States
  2. Department of Chemistry and Center for Environmentally Beneficial Catalysis, The University of Kansas, Lawrence, Kansas 66045, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Univ. of Kansas, Lawrence, KS (United States); Stanford Univ., CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016359; AC02-76SF00515
OSTI ID:
1978476
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 27; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (35)

Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation journal December 2016
Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes journal December 2017
The Electronic Structure of the Vanadyl Ion journal February 1962
Synthetic High-Valent M-O-X Oxidants: Synthetic High-Valent M-O-X Oxidants journal January 2018
Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex journal March 2017
Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions journal July 2014
Crystal Structure and C–H Bond-Cleaving Reactivity of a Mononuclear Co IV –Dinitrate Complex journal July 2020
M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt(III)-Oxyl and Cobalt(III)-Oxo Complexes journal June 2019
The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)–Oxo Complex journal October 2021
Enzyme-Like Hydroxylation of Aliphatic C–H Bonds From an Isolable Co-Oxo Complex journal December 2021
Fast Hydrocarbon Oxidation by a High‐Valent Nickel–Fluoride Complex journal June 2020
Hydrogen Atom Transfer by a High-Valent Nickel-Chloride Complex journal January 2018
Tuning the Reactivity of Terminal Nickel(III)–Oxygen Adducts for C–H Bond Activation journal October 2016
Characterization and Reactivity of a Terminal Nickel(III)-Oxygen Adduct journal January 2015
Rapid C–H Bond Activation by a Monocopper(III)–Hydroxide Complex journal November 2011
Perturbing the Copper(III)–Hydroxide Unit through Ligand Structural Variation journal December 2015
Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex journal January 2015
High-Valent d 7 Ni III versus d 8 Cu III Oxidants in PCET journal November 2019
C(sp3)–H Fluorination with a Copper(II)/(III) Redox Couple journal April 2020
Stabilizing Terminal Ni(III)–Hydroxide Complex Using NNN-Pincer Ligands: Synthesis and Characterization journal April 2019
Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel–Oxygen Species journal September 2016
Spectroscopically Characterized Synthetic Mononuclear Nickel-Oxygen Species journal August 2016
Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates journal March 2016
Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon–Carbon Bond Formation Reactions journal September 2016
Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes journal February 2015
Aryl–Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers journal August 2019
C−H Bond Trifluoromethylation of Arenes Enabled by a Robust, High-Valent Nickel(IV) Complex journal September 2017
Bivalent, Trivalent, and Tetravalent Nickel Complexes with a Common Tridentate Deprotonated Pyridine Bis-Amide Ligand. Molecular Structures of Nickel(II) and Nickel(IV) and Redox Activity journal April 1999
Synthesis and reactions of nickel(iii) complexes journal October 1981
X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases journal March 1991
Spectroscopic Evidence for a 3d 10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF 3 ) 4 ] 1– journal February 2016
The Myth of d 8 Copper(III) journal October 2019
Probing Physical Oxidation State by Resonant X‐ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase journal March 2021
Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes journal January 2022
From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields journal June 2016

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