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Electrocatalytic, Homogeneous Ammonia Oxidation in Water to Nitrate and Nitrite with a Copper Complex

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c01788· OSTI ID:1978473
 [1];  [2];  [1];  [1];  [2];  [1];  [1]
  1. Department of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520, United States; Energy Sciences Institute, Yale University, 810 West Campus Drive, West Haven, Connecticut 06516, United States
  2. Department of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520, United States

Not provided.

Research Organization:
Yale Univ., New Haven, CT (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-07ER15909
OSTI ID:
1978473
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 19; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (22)

Electrocatalytic Nitrogen Fixation for Distributed Fertilizer Production? journal July 2016
Nitrogen Cycle Electrocatalysis journal June 2009
The role of adsorbates in the electrochemical oxidation of ammonia on noble and transition metal electrodes journal June 2001
Homogeneous electrocatalytic oxidation of ammonia to N 2 under mild conditions journal January 2019
Ruthenium-catalysed oxidative conversion of ammonia into dinitrogen journal July 2019
Electrocatalytic Ammonia Oxidation Mediated by a Polypyridyl Iron Catalyst journal September 2019
Oxidation of Ammonia with Molecular Complexes journal September 2020
Spontaneous N2 formation by a diruthenium complex enables electrocatalytic and aerobic oxidation of ammonia journal November 2021
Manganese‐Catalyzed Ammonia Oxidation into Dinitrogen under Chemical or Electrochemical Conditions** journal September 2021
Enhanced Ammonia Oxidation Catalysis by a Low-Spin Iron Complex Featuring Cis Coordination Sites journal May 2021
Synthesis, Structure, and Ammonia Oxidation Catalytic Activity of Ru-NH3 Complexes Containing Multidentate Polypyridyl Ligands journal September 2021
The catalytic oxidation of ammonia: influence of water and sulfur on selectivity to nitrogen over promoted copper oxide/alumina catalysts journal January 2000
Copper based catalysts for the selective ammonia oxidation into nitrogen and water vapour—Recent trends and open challenges journal February 2016
Copper‐Catalyzed Electrosynthesis of Nitrite and Nitrate from Ammonia: Tuning the Selectivity via an Interplay Between Homogeneous and Heterogeneous Catalysis journal September 2021
Oxidation of coordinated ammonia to nitrate journal September 1981
Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand journal October 2016
Molecular biology and biochemistry of ammonia oxidation by Nitrosomonas europaea journal October 2002
Crystal structure of a membrane-bound metalloenzyme that catalyses the biological oxidation of methane journal January 2005
A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis journal February 2017
Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand journal April 2017
Cp* versus Bis-carbonyl Iridium Precursors as CH Oxidation Precatalysts journal August 2016
Oxidation Potential-Free Energy Diagrams journal June 1951