Copper(I)–Pyrazolate Complexes as Solid-State Phosphors: Deep-Blue Emission through a Remote Steric Effect

Watanabe, Yuichiro; Washer, Benjamin M.; Zeller, Matthias; Savikhin, Sergei; Slipchenko, Lyudmila V.; Wei, Alexander

doi:10.1021/jacs.1c13462

Copper(I)–Pyrazolate Complexes as Solid-State Phosphors: Deep-Blue Emission through a Remote Steric Effect

Journal Article · 20 May 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.1c13462· OSTI ID:1978461

^[1]; Washer, Benjamin M. ^[2]; ^[2]; Savikhin, Sergei ^[3]; ^[2]; ^[4]

Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States; OSTI
Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States
Department of Physics and Astronomy, Purdue University, 525 Northwestern Avenue, West Lafayette, Indiana 47907, United States
Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States; School of Materials Engineering, Purdue University, 701 W. Stadium Avenue, West Lafayette, Indiana 47907, United States

Not provided.

Research Organization:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0018239

OSTI ID:: 1978461

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 23 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (42)

Cu(I) hybrid inorganic–organic materials with intriguing stimuli responsive and optoelectronic properties Cariati, Elena; Lucenti, Elena; Botta, Chiara Coordination Chemistry Reviews, Vol. 306 https://doi.org/10.1016/j.ccr.2015.03.004	journal	January 2016
Temperature dependence of luminescence from Cu(NN)2+ systems in fluid solution. Evidence for the participation of two excited states Kirchhoff, Jon R.; Gamache, Roland E.; Blaskie, Marcus W. Inorganic Chemistry, Vol. 22, Issue 17 https://doi.org/10.1021/ic00159a008	journal	August 1983
Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design Czerwieniec, Rafał; Leitl, Markus J.; Homeier, Herbert H. H. Coordination Chemistry Reviews, Vol. 325 https://doi.org/10.1016/j.ccr.2016.06.016	journal	October 2016
Intramolecular rearrangements guided by adaptive coordination-driven reactions toward highly luminescent polynuclear Cu(i) assemblies El Sayed Moussa, Mehdi; Khalil, Ali Moustafa; Evariste, Sloane Inorganic Chemistry Frontiers, Vol. 7, Issue 6 https://doi.org/10.1039/C9QI01595G	journal	January 2020
Recent Advances in Metal Triplet Emitters with d6, d8, and d10 Electronic Configurations To, Wai-Pong; Wan, Qingyun; Tong, Glenna So Ming Trends in Chemistry, Vol. 2, Issue 9 https://doi.org/10.1016/j.trechm.2020.06.004	journal	September 2020
Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies Evariste, Sloane; Khalil, Ali Moustafa; Moussa, Mehdi Elsayed Journal of the American Chemical Society, Vol. 140, Issue 39 https://doi.org/10.1021/jacs.8b06901	journal	July 2018
Multifunctional Materials in High-Performance OLEDs: Challenges for Solid-State Lighting ^† Sasabe, Hisahiro; Kido, Junji Chemistry of Materials, Vol. 23, Issue 3 https://doi.org/10.1021/cm1024052	journal	February 2011
Luminescent polynuclear d10 metal complexes Yam, Vivian Wing-Wah; Lo, Kenneth Kam-Wing Chemical Society Reviews, Vol. 28, Issue 5 https://doi.org/10.1039/a804249g	journal	January 1999
Light-Emitting Self-Assembled Materials Based on d ⁸ and d ¹⁰ Transition Metal Complexes Yam, Vivian Wing-Wah; Au, Vonika Ka-Man; Leung, Sammual Yu-Lut Chemical Reviews, Vol. 115, Issue 15 https://doi.org/10.1021/acs.chemrev.5b00074	journal	July 2015
Synthesis and characterisation of new polynuclear copper(I) pyrazolate complexes and their catalytic activity in the cyclopropanation of olefins Maspero, A. Journal of Organometallic Chemistry, Vol. 672, Issue 1-2 https://doi.org/10.1016/S0022-328X(03)00132-3	journal	April 2003
Highly efficient organic light-emitting diodes from delayed fluorescence Uoyama, Hiroki; Goushi, Kenichi; Shizu, Katsuyuki Nature, Vol. 492, Issue 7428 https://doi.org/10.1038/nature11687	journal	December 2012
Highly efficient phosphorescent emission from organic electroluminescent devices Baldo, M. A.; O'Brien, D. F.; You, Y. Nature, Vol. 395, Issue 6698, p. 151-154 https://doi.org/10.1038/25954	journal	September 1998
How the Quantum Efficiency of a Highly Emissive Binuclear Copper Complex Is Enhanced by Changing the Processing Solvent Volz, Daniel; Nieger, Martin; Friedrichs, Jana Langmuir, Vol. 29, Issue 9 https://doi.org/10.1021/la3039522	journal	February 2013
Fluoreszenz und Fluoreszenz-Thermochromie bei Alkyl-pyridinokupfer(I)-Halogeniden De Ahna, H. D.; Hardt, H. D. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 387, Issue 1 https://doi.org/10.1002/zaac.19723870108	journal	January 1972
Investigation of Luminescent Triplet States in Tetranuclear Cu ^I Complexes: Thermochromism and Structural Characterization Boden, Pit; Di Martino‐Fumo, Patrick; Busch, Jasmin M. Chemistry – A European Journal, Vol. 27, Issue 17 https://doi.org/10.1002/chem.202004539	journal	January 2021
Brightly phosphorescent tetranuclear copper(i) pyrazolates Dias, H. V. Rasika; Diyabalanage, Himashinie V. K.; Ghimire, Mukunda M. Dalton Transactions, Vol. 48, Issue 40 https://doi.org/10.1039/C9DT03402A	journal	January 2019
Very high-efficiency green organic light-emitting devices based on electrophosphorescence Baldo, M. A.; Lamansky, S.; Burrows, P. E. Applied Physics Letters, Vol. 75, Issue 1, p. 4-6 https://doi.org/10.1063/1.124258	journal	July 1999
Atropisomerism, Biphenyls, and Fluorine: A Comparison of Rotational Barriers and Twist Angles Leroux, Frédéric ChemBioChem, Vol. 5, Issue 5 https://doi.org/10.1002/cbic.200300906	journal	April 2004
Exploiting synergy between ligand design and counterion interactions to boost room temperature phosphorescence from Cu(i) compounds Mondal, Rajarshi; Lozada, Issiah B.; Davis, Rebecca L. Journal of Materials Chemistry C, Vol. 7, Issue 13 https://doi.org/10.1039/C9TC00040B	journal	January 2019
Collisional Perturbation of Spin‐Orbital Coupling and the Mechanism of Fluorescence Quenching. A Visual Demonstration of the Perturbation Kasha, Michael The Journal of Chemical Physics, Vol. 20, Issue 1 https://doi.org/10.1063/1.1700199	journal	January 1952
Survey of short and long cuprophilic d ¹⁰ –d ¹⁰ contacts for tetranuclear copper clusters. Understanding of bonding and ligand role from a planar superatom perspective Claveria-Cadiz, Francisca; Arratia-Perez, Ramiro; Guajardo-Maturana, Raúl New Journal of Chemistry, Vol. 42, Issue 11 https://doi.org/10.1039/C8NJ00698A	journal	January 2018
Luminescence Ranging from Red to Blue: A Series of Copper(I)−Halide Complexes Having Rhombic {Cu ₂ (μ-X) ₂ } (X = Br and I) Units with N -Heteroaromatic Ligands Araki, Hiromi; Tsuge, Kiyoshi; Sasaki, Yoichi Inorganic Chemistry, Vol. 44, Issue 26 https://doi.org/10.1021/ic0510359	journal	December 2005
Electronic Contributions to the σ_p Parameter of the Hammett Equation Domingo, Luis R.; Pérez, Patricia; Contreras, Renato The Journal of Organic Chemistry, Vol. 68, Issue 15 https://doi.org/10.1021/jo030072j	journal	June 2003
Crystal Structure of Pyrazolato-bridged Copper(I) Polynuclear Complexes Fujisawa, Kiyoshi; Ishikawa, Yoko; Miyashita, Yoshitaro Chemistry Letters, Vol. 33, Issue 1 https://doi.org/10.1246/cl.2004.66	journal	January 2004
Luminescent mixed ligand copper(I) clusters (CuI)n(L)m (L=pyridine, piperidine): thermodynamic control of molecular and supramolecular species Vitale*, M. Coordination Chemistry Reviews, Vol. 219-221 https://doi.org/10.1016/S0010-8545(00)00414-8	journal	October 2001
Pyrazolate-bridged group 11 metal(I) complexes: Substituent effects on the supramolecular structures and physicochemical properties Fujisawa, Kiyoshi; Ishikawa, Yoko; Miyashita, Yoshitaro Inorganica Chimica Acta, Vol. 363, Issue 12 https://doi.org/10.1016/j.ica.2010.05.014	journal	October 2010
Multilayer White Light-Emitting Organic Electroluminescent Device Kido, J.; Kimura, M.; Nagai, K. Science, Vol. 267, Issue 5202 https://doi.org/10.1126/science.267.5202.1332	journal	March 1995
Fast Calculation of van der Waals Volume as a Sum of Atomic and Bond Contributions and Its Application to Drug Compounds Zhao, Yuan H.; Abraham, Michael H.; Zissimos, Andreas M. The Journal of Organic Chemistry, Vol. 68, Issue 19 https://doi.org/10.1021/jo034808o	journal	September 2003
Photoluminescence Properties of Multinuclear Copper(I) Compounds Ford, Peter C.; Cariati, Elena; Bourassa, James Chemical Reviews, Vol. 99, Issue 12 https://doi.org/10.1021/cr960109i	journal	December 1999
Cu ₄ I ₄ Clusters Supported by P ^∧ N-type Ligands: New Structures with Tunable Emission Colors Liu, Zhiwei; Djurovich, Peter I.; Whited, Matthew T. Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic2015226	journal	December 2011
Engineering Luminescence Lifetimes of Cu(I) Complexes for Optical Multiplexing Ma, Yun; Dong, Yafang; She, Pengfei Advanced Optical Materials, Vol. 6, Issue 23 https://doi.org/10.1002/adom.201801065	journal	October 2018
Stimuli-responsive Luminescent Copper(I) Complexes for Intelligent Emissive Devices Kobayashi, Atsushi; Kato, Masako Chemistry Letters, Vol. 46, Issue 2 https://doi.org/10.1246/cl.160794	journal	February 2017
Highly efficient sky blue electroluminescence from ligand-activated copper iodide clusters: Overcoming the limitations of cluster light-emitting diodes Xie, Mingchen; Han, Chunmiao; Liang, Qianqian Science Advances, Vol. 5, Issue 6 https://doi.org/10.1126/sciadv.aav9857	journal	June 2019
Brightly Phosphorescent Trinuclear Copper(I) Complexes of Pyrazolates: Substituent Effects on the Supramolecular Structure and Photophysics Dias, H. V. Rasika; Diyabalanage, Himashinie V. K.; Eldabaja, Maha G. Journal of the American Chemical Society, Vol. 127, Issue 20 https://doi.org/10.1021/ja0427146	journal	April 2005
Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime Hamze, Rasha; Peltier, Jesse L.; Sylvinson, Daniel Science, Vol. 363, Issue 6427 https://doi.org/10.1126/science.aav2865	journal	February 2019
Copper(I) halides: A versatile family in coordination chemistry and crystal engineering Peng, Rong; Li, Mian; Li, Dan Coordination Chemistry Reviews, Vol. 254, Issue 1-2 https://doi.org/10.1016/j.ccr.2009.10.003	journal	January 2010
The photoluminescence of phosphine complexes of d 10 metals Ziolo, Ronald F.; Lipton, Steven; Dori, Zvi Journal of the Chemical Society D: Chemical Communications, Issue 17 https://doi.org/10.1039/c29700001124	journal	January 1970
Electronic Transitions Involved in the Absorption Spectrum and Dual Luminescence of Tetranuclear Cubane [Cu ₄ I ₄ (pyridine) ₄ ] Cluster: a Density Functional Theory/Time-Dependent Density Functional Theory Investigation De Angelis, Filippo; Fantacci, Simona; Sgamellotti, Antonio Inorganic Chemistry, Vol. 45, Issue 26 https://doi.org/10.1021/ic061147f	journal	December 2006
A new class of deep-blue emitting Cu(i) compounds – effects of counter ions on the emission behavior Gneuß, Timo; Leitl, Markus J.; Finger, Lars H. Dalton Transactions, Vol. 44, Issue 46 https://doi.org/10.1039/C5DT03065J	journal	January 2015
Photoprocesses of Copper Complexes That Bind to DNA McMillin, David R.; McNett, Kristina M. Chemical Reviews, Vol. 98, Issue 3 https://doi.org/10.1021/cr9601167	journal	May 1998
High-performance light-emitting diodes based on carbene-metal-amides Di, Dawei; Romanov, Alexander S.; Yang, Le Science, Vol. 356, Issue 6334 https://doi.org/10.1126/science.aah4345	journal	March 2017
van der Waals Volumes and Radii Bondi, A. The Journal of Physical Chemistry, Vol. 68, Issue 3, p. 441-451 https://doi.org/10.1021/j100785a001	journal	March 1964

Similar Records

Rigidochromism of tetranuclear Cu(I)–pyrazolate macrocycles: steric crowding with trifluoromethyl groups

Journal Article · 2024 · ChemComm · OSTI ID:2447179

Strong Steric Hindrance Effect on Excited State Structural Dynamics of Cu(I) Diimine Complexes

Journal Article · 2011 · Journal of Physical Chemistry A · OSTI ID:1115881

Related Subjects

Chemistry

Copper(I)–Pyrazolate Complexes as Solid-State Phosphors: Deep-Blue Emission through a Remote Steric Effect

Citation Formats

References (42)

Similar Records

Related Subjects