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Oxo-Cluster-Based Zr/Hf IV Separation: Shedding Light on a 70-Year-Old Process

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.1c13338· OSTI ID:1978460

Not provided.

Research Organization:
Oregon State Univ., Corvallis, OR (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0010802
OSTI ID:
1978460
Journal Information:
Journal of the American Chemical Society, Vol. 144, Issue 6; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (27)

Aqueous Stability of Zirconium Clusters, Including the Zr(IV) Hexanuclear Hydrolysis Complex [Zr 6 O 4 (OH) 4 (H 2 O) 24 ] 12+ , from Density Functional Theory journal October 2021
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
A Decade of UiO-66 Research: A Historic Review of Dynamic Structure, Synthesis Mechanisms, and Characterization Techniques of an Archetypal Metal–Organic Framework journal December 2019
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends journal February 2018
Isoreticular synthesis and modification of frameworks with the UiO-66 topology journal January 2010
Postsynthetic ligand exchange as a route to functionalization of ‘inert’ metal–organic frameworks journal January 2012
Correlated defect nanoregions in a metal–organic framework journal June 2014
Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66 journal October 2016
Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study journal April 2017
Metal–Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal–Organic Framework journal April 2017
Controlling the Synthesis of Metal–Organic Framework UiO-67 by Tuning Its Kinetic Driving Force journal July 2019
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66 journal July 2014
Peroxide-Promoted Disassembly Reassembly of Zr-Polyoxocations journal September 2019
Differentiating Zr/Hf IV Aqueous Polyoxocation Chemistry with Peroxide Ligation journal January 2021
Evaluation of Thermal and Radiation Induced Chemistries of Metal Oxo–Hydroxo Clusters for Next-Generation Nanoscale Inorganic Resists journal August 2018
Chemical and Structural Investigation of High-Resolution Patterning with HafSOx journal February 2014
Mechanistic Study of HafSO x Extreme Ultraviolet Inorganic Resists journal June 2018
Solvent Extraction for the Separation of Zr and Hf from Aqueous Solutions journal September 2014
Production of nuclear grade zirconium: A review journal November 2015
Review of Extraction, Processing, Properties & Applications of Reactive Metals journal February 1999
Über die Trennung anorganischer Stoffgemische durch Verteilung zwischen zwei Lösungsmitteln. 3. Die Trennung des Hafniums vom Zirkonium durch Verteilung journal December 1947
Über die Trennung anorganischer Stoffgemische durch Verteilung zwischen zwei Lösungsmitteln. 4. Die präparative Gewinnung reiner Hafniumverbindungen durch Verteilung journal January 1948
Density Functional Theoretical Modeling of Selective Ligand for the Separation of Zr and Hf Metal Oxycations (ZrO 2+ and HfO 2+ ) journal November 2013
Noble Metals in Polyoxometalates journal August 2012
Synthesis and vibrational spectra of lead(II) thiocyanate complexes journal April 1976
A Toroidal Zr 70 Oxysulfate Cluster and Its Diverse Packing Structures journal November 2020
Synthesis, Structural, and Physicochemical Characterization of a Ti 6 and a Unique Type of Zr 6 Oxo Clusters Bearing an Electron-Rich Unsymmetrical {OON} Catecholate/Oxime Ligand and Exhibiting Metalloaromaticity journal December 2020

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