Quantum Dot-Sensitized Photoreduction of CO 2 in Water with Turnover Number &gt; 80,000

Arcudi, Francesca; Đorđević, Luka; Nagasing, Benjamin; Stupp, Samuel I.; Weiss, Emily A.

doi:10.1021/jacs.1c06961

Quantum Dot-Sensitized Photoreduction of CO ₂ in Water with Turnover Number > 80,000

Journal Article · 19 October 2021 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.1c06961· OSTI ID:1978432

^[1]; ^[1]; Nagasing, Benjamin ^[2]; ^[3]; ^[4]

Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States; Center for Bio-Inspired Energy Science, Northwestern University, Chicago, Illinois 60611, United States
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States; Center for Bio-Inspired Energy Science, Northwestern University, Chicago, Illinois 60611, United States; Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States; Department of Biomedical Engineering, Northwestern University, Evanston, Illinois 60208, United States; Department of Medicine, Northwestern University, Chicago, Illinois 60611, United States
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States; Center for Bio-Inspired Energy Science, Northwestern University, Chicago, Illinois 60611, United States; Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States

Not provided.

Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0000989; SC0001329

OSTI ID:: 1978432

Journal Information:: Journal of the American Chemical Society, Vol. 143, Issue 43; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (68)

Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
The underestimated potential of solar energy to mitigate climate change Creutzig, Felix; Agoston, Peter; Goldschmidt, Jan Christoph Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.140	journal	August 2017
Designing for a green chemistry future Zimmerman, Julie B.; Anastas, Paul T.; Erythropel, Hanno C. Science, Vol. 367, Issue 6476 https://doi.org/10.1126/science.aay3060	journal	January 2020
Nature-based catalyst for visible-light-driven photocatalytic CO ₂ reduction Jiang, Zhifeng; Sun, Hongli; Wang, Tianqi Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE01781F	journal	January 2018
Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41272e	journal	January 2013
Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction Huang, Jianfeng; Hörmann, Nicolas; Oveisi, Emad Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05544-3	journal	August 2018
Enhanced photocatalytic hydrogen evolution from organic semiconductor heterojunction nanoparticles Kosco, Jan; Bidwell, Matthew; Cha, Hyojung Nature Materials, Vol. 19, Issue 5 https://doi.org/10.1038/s41563-019-0591-1	journal	February 2020
Photocatalytic water splitting with a quantum efficiency of almost unity Takata, Tsuyoshi; Jiang, Junzhe; Sakata, Yoshihisa Nature, Vol. 581, Issue 7809 https://doi.org/10.1038/s41586-020-2278-9	journal	May 2020
Excited-State Proton-Coupled Electron Transfer: Different Avenues for Promoting Proton/Electron Movement with Solar Photons Lennox, J. Christian; Kurtz, Daniel A.; Huang, Tao ACS Energy Letters, Vol. 2, Issue 5 https://doi.org/10.1021/acsenergylett.7b00063	journal	April 2017
Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts Lee, Katherine J.; Elgrishi, Noémie; Kandemir, Banu Nature Reviews Chemistry, Vol. 1, Issue 5 https://doi.org/10.1038/s41570-017-0039	journal	May 2017
Nanotechnology for catalysis and solar energy conversion Banin, U.; Waiskopf, N.; Hammarström, L. Nanotechnology, Vol. 32, Issue 4 https://doi.org/10.1088/1361-6528/abbce8	journal	November 2020
Light-driven water oxidation for solar fuels Young, Karin J.; Martini, Lauren A.; Milot, Rebecca L. Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.03.031	journal	November 2012
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst Han, Z.; Qiu, F.; Eisenberg, R. Science, Vol. 338, Issue 6112 https://doi.org/10.1126/science.1227775	journal	November 2012
Directing the reactivity of metal hydrides for selective CO ₂ reduction Ceballos, Bianca M.; Yang, Jenny Y. Proceedings of the National Academy of Sciences, Vol. 115, Issue 50 https://doi.org/10.1073/pnas.1811396115	journal	November 2018
Thermodynamic Considerations for Optimizing Selective CO ₂ Reduction by Molecular Catalysts Barlow, Jeffrey M.; Yang, Jenny Y. ACS Central Science, Vol. 5, Issue 4 https://doi.org/10.1021/acscentsci.9b00095	journal	March 2019
Semiconductor nanocrystal photocatalysis for the production of solar fuels Burke, Rebeckah; Bren, Kara L.; Krauss, Todd D. The Journal of Chemical Physics, Vol. 154, Issue 3 https://doi.org/10.1063/5.0032172	journal	January 2021
What Should We Make with CO2 and How Can We Make It? Bushuyev, Oleksandr S.; De Luna, Phil; Dinh, Cao Thang Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2017.09.003	journal	May 2018
Shining light on CO ₂ : from materials discovery to photocatalyst, photoreactor and process engineering Dong, Yuchan; Duchesne, Paul; Mohan, Abhinav Chemical Society Reviews, Vol. 49, Issue 16 https://doi.org/10.1039/D0CS00597E	journal	January 2020
Recent Advances in Solar-Driven Carbon Dioxide Conversion: Expectations versus Reality He, Jie; Janáky, Csaba ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00645	journal	May 2020
CO ₂ Reduction: From the Electrochemical to Photochemical Approach Wu, Jinghua; Huang, Yang; Ye, Wen Advanced Science, Vol. 4, Issue 11 https://doi.org/10.1002/advs.201700194	journal	September 2017
Hybrid Catalysts for Artificial Photosynthesis: Merging Approaches from Molecular, Materials, and Biological Catalysis Smith, Peter T.; Nichols, Eva M.; Cao, Zhi Accounts of Chemical Research, Vol. 53, Issue 3 https://doi.org/10.1021/acs.accounts.9b00619	journal	March 2020
Highly Efficient and Selective Photocatalytic CO ₂ Reduction by Iron and Cobalt Quaterpyridine Complexes Guo, Zhenguo; Cheng, Siwei; Cometto, Claudio Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b06002	journal	July 2016
Efficient Visible-Light-Driven CO ₂ Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride Ma, Bing; Chen, Gui; Fave, Claire Journal of the American Chemical Society, Vol. 142, Issue 13 https://doi.org/10.1021/jacs.9b13930	journal	March 2020
Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO ₂ -to-CO Conversion Ouyang, Ting; Wang, Hong-Juan; Huang, Hai-Hua Angewandte Chemie International Edition, Vol. 57, Issue 50 https://doi.org/10.1002/anie.201811010	journal	November 2018
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G. Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja4074003	journal	September 2013
Photocatalytic CO ₂ Reduction in N , N -Dimethylacetamide/Water as an Alternative Solvent System Kuramochi, Yusuke; Kamiya, Masaya; Ishida, Hitoshi Inorganic Chemistry, Vol. 53, Issue 7 https://doi.org/10.1021/ic500050q	journal	March 2014
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO ₂ reduction in water Karmakar, Sanchita; Barman, Soumitra; Rahimi, Faruk Ahamed Energy & Environmental Science, Vol. 14, Issue 4 https://doi.org/10.1039/D0EE03643A	journal	January 2021
Selective Photocatalytic CO ₂ Reduction in Water by Electrostatic Assembly of CdS Nanocrystals with a Dinuclear Cobalt Catalyst Bi, Qian-Qian; Wang, Jia-Wei; Lv, Jia-Xin ACS Catalysis, Vol. 8, Issue 12 https://doi.org/10.1021/acscatal.8b03457	journal	October 2018
Selective Photocatalytic CO ₂ Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals Kuehnel, Moritz F.; Orchard, Katherine L.; Dalle, Kristian E. Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b00369	journal	May 2017
Highly efficient visible-light-driven CO ₂ reduction to CO using a Ru( ii )–Re( i ) supramolecular photocatalyst in an aqueous solution Nakada, Akinobu; Koike, Kazuhide; Maeda, Kazuhiko Green Chemistry, Vol. 18, Issue 1 https://doi.org/10.1039/C5GC01720C	journal	January 2016
Visible light-driven CO ₂ reduction by enzyme coupled CdS nanocrystals Chaudhary, Yatendra S.; Woolerton, Thomas W.; Allen, Christopher S. Chem. Commun., Vol. 48, Issue 1 https://doi.org/10.1039/C1CC16107E	journal	January 2012
Highly Efficient and Selective Photocatalytic CO ₂ Reduction to CO in Water by a Cobalt Porphyrin Molecular Catalyst Call, Arnau; Cibian, Mihaela; Yamamoto, Keiya ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.8b04975	journal	April 2019
Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium Pitman, Catherine L.; Brereton, Kelsey R.; Miller, Alexander J. M. Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b12363	journal	February 2016
Rhenium( i ) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO ₂ reduction Rohacova, Jana; Ishitani, Osamu Chemical Science, Vol. 7, Issue 11 https://doi.org/10.1039/C6SC01913G	journal	January 2016
Powering a CO ₂ Reduction Catalyst with Visible Light through Multiple Sub-picosecond Electron Transfers from a Quantum Dot Lian, Shichen; Kodaimati, Mohamad S.; Dolzhnikov, Dmitriy S. Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b03134	journal	June 2017
Quantum Dot‐Catalyzed Photoreductive Removal of Sulfonyl‐Based Protecting Groups Perez, Kaitlyn A.; Rogers, Cameron R.; Weiss, Emily A. Angewandte Chemie International Edition, Vol. 59, Issue 33 https://doi.org/10.1002/anie.202005074	journal	June 2020
Photocatalytically Active Superstructures of Quantum Dots and Iron Porphyrins for Reduction of CO ₂ to CO in Water Lian, Shichen; Kodaimati, Mohamad S.; Weiss, Emily A. ACS Nano, Vol. 12, Issue 1 https://doi.org/10.1021/acsnano.7b07377	journal	January 2018
Molecular tunability of surface-functionalized metal nanocrystals for selective electrochemical CO ₂ reduction Pankhurst, James R.; Guntern, Yannick T.; Mensi, Mounir Chemical Science, Vol. 10, Issue 44 https://doi.org/10.1039/C9SC04439F	journal	January 2019
Efficient Electrosynthesis of Syngas with Tunable CO/H ₂ Ratios over Zn _x Cd _{1− x} S‐Amine Inorganic–Organic Hybrids Meng, Nannan; Liu, Cuibo; Liu, Yang Angewandte Chemie International Edition, Vol. 58, Issue 52 https://doi.org/10.1002/anie.201913003	journal	December 2019
Amine-Functionalized Graphene/CdS Composite for Photocatalytic Reduction of CO ₂ Cho, Kyeong Min; Kim, Kyoung Hwan; Park, Kangho ACS Catalysis, Vol. 7, Issue 10 https://doi.org/10.1021/acscatal.7b01908	journal	September 2017
Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction Wagner, Andreas; Sahm, Constantin D.; Reisner, Erwin Nature Catalysis, Vol. 3, Issue 10 https://doi.org/10.1038/s41929-020-00512-x	journal	September 2020
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian Nature, Vol. 519, Issue 7543 https://doi.org/10.1038/nature14327	journal	March 2015
Cooperative carbon capture and steam regeneration with tetraamine-appended metal–organic frameworks Kim, Eugene J.; Siegelman, Rebecca L.; Jiang, Henry Z. H. Science, Vol. 369, Issue 6502 https://doi.org/10.1126/science.abb3976	journal	July 2020
Amine Scrubbing for CO2 Capture Rochelle, G. T. Science, Vol. 325, Issue 5948 https://doi.org/10.1126/science.1176731	journal	September 2009
CO ₂ photo-reduction: insights into CO ₂ activation and reaction on surfaces of photocatalysts Chang, Xiaoxia; Wang, Tuo; Gong, Jinlong Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE00383D	journal	January 2016
Covalent Organic Frameworks Linked by Amine Bonding for Concerted Electrochemical Reduction of CO2 Liu, Haoyu; Chu, Jun; Yin, Zhenglei Chem, Vol. 4, Issue 7 https://doi.org/10.1016/j.chempr.2018.05.003	journal	July 2018
Earth-Abundant Photocatalytic CO ₂ Reduction by Multielectron Chargeable Cobalt Porphyrin Catalysts: High CO/H ₂ Selectivity in Water Based on Phase Mismatch in Frontier MO Association Zhang, Xian; Yamauchi, Kosei; Sakai, Ken ACS Catalysis, Vol. 11, Issue 16 https://doi.org/10.1021/acscatal.1c02475	journal	August 2021
Clean Donor Oxidation Enhances the H ₂ Evolution Activity of a Carbon Quantum Dot-Molecular Catalyst Photosystem Martindale, Benjamin C. M.; Joliat, Evelyne; Bachmann, Cyril Angewandte Chemie International Edition, Vol. 55, Issue 32 https://doi.org/10.1002/anie.201604355	journal	June 2016
Mechanistic Insights into the Interface-Directed Transformation of Thiols into Disulfides and Molecular Hydrogen by Visible-Light Irradiation of Quantum Dots Li, Xu-Bing; Li, Zhi-Jun; Gao, Yu-Ji Angewandte Chemie, Vol. 126, Issue 8 https://doi.org/10.1002/ange.201310249	journal	January 2014
Molecular Electrochemical Reduction of CO2 beyond Two Electrons Boutin, Etienne; Robert, Marc Trends in Chemistry, Vol. 3, Issue 5 https://doi.org/10.1016/j.trechm.2021.02.003	journal	May 2021
In Situ Nuclear Magnetic Resonance Mechanistic Studies of Carbon Dioxide Reactions with Liquid Amines in Aqueous Systems: New Insights on Carbon Capture Reaction Pathways Kortunov, Pavel V.; Siskin, Michael; Baugh, Lisa Saunders Energy & Fuels, Vol. 29, Issue 9 https://doi.org/10.1021/acs.energyfuels.5b00850	journal	July 2015
Ether Functionalized Choline Tethered Amino Acid Ionic Liquids for Enhanced CO ₂ Capture Bhattacharyya, Shubhankar; Shah, Faiz Ullah ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 10 https://doi.org/10.1021/acssuschemeng.6b00824	journal	September 2016
Adsorption and Activation of CO₂ by Amine-Modified Nanoporous Materials Studied by Solid-State NMR and ¹³CO₂ Adsorption Pinto, Moisés L.; Mafra, Luís; Guil, José M. Chemistry of Materials, Vol. 23, Issue 6, p. 1387-1395 https://doi.org/10.1021/cm1029563	journal	March 2011
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO ₂ to Methanol Rezayee, Nomaan M.; Huff, Chelsea A.; Sanford, Melanie S. Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja511329m	journal	January 2015
Thermodynamic Analysis of Metal–Ligand Cooperativity of PNP Ru Complexes: Implications for CO ₂ Hydrogenation to Methanol and Catalyst Inhibition Mathis, Cheryl L.; Geary, Jackson; Ardon, Yotam Journal of the American Chemical Society, Vol. 141, Issue 36 https://doi.org/10.1021/jacs.9b06760	journal	August 2019
Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds Jiang, Feng; Siegler, Maxime A.; Sun, Xiaobo Inorganic Chemistry, Vol. 57, Issue 15 https://doi.org/10.1021/acs.inorgchem.8b00549	journal	July 2018
Electroreduction of CO ₂ to Formate with Low Overpotential using Cobalt Pyridine Thiolate Complexes Dey, Subal; Todorova, Tanya K.; Fontecave, Marc Angewandte Chemie International Edition, Vol. 59, Issue 36 https://doi.org/10.1002/anie.202006269	journal	August 2020
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Ultraefficient homogeneous catalyst for the CO ₂ -to-CO electrochemical conversion Costentin, Cyrille; Passard, Guillaume; Robert, Marc Proceedings of the National Academy of Sciences, Vol. 111, Issue 42 https://doi.org/10.1073/pnas.1416697111	journal	October 2014
Positional effects of second-sphere amide pendants on electrochemical CO ₂ reduction catalyzed by iron porphyrins Nichols, Eva M.; Derrick, Jeffrey S.; Nistanaki, Sepand K. Chemical Science, Vol. 9, Issue 11 https://doi.org/10.1039/C7SC04682K	journal	January 2018
Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO ₂ Reduction of Iron Porphyrins Gotico, Philipp; Boitrel, Bernard; Guillot, Régis Angewandte Chemie International Edition, Vol. 58, Issue 14 https://doi.org/10.1002/anie.201814339	journal	February 2019
Carbon Dioxide Reduction by Iron Hangman Porphyrins Margarit, Charles G.; Schnedermann, Christoph; Asimow, Naomi G. Organometallics, Vol. 38, Issue 6 https://doi.org/10.1021/acs.organomet.8b00334	journal	June 2018
Photocatalytic Reduction of Low Concentration of CO ₂ Nakajima, Takuya; Tamaki, Yusuke; Ueno, Kazuki Journal of the American Chemical Society, Vol. 138, Issue 42 https://doi.org/10.1021/jacs.6b08824	journal	October 2016
Porous Semiconductor Chalcogenide Aerogels Mohanan, Jaya L.; Arachchige, Indika U.; Brock, Stephanie L. Science, Vol. 307, Issue 5708 https://doi.org/10.1126/science.1104226	journal	January 2005
Self-assembling hydrogel scaffolds for photocatalytic hydrogen production Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C. Nature Chemistry, Vol. 6, Issue 11 https://doi.org/10.1038/nchem.2075	journal	October 2014
Molecularly engineered photocatalyst sheet for scalable solar formate production from carbon dioxide and water Wang, Qian; Warnan, Julien; Rodríguez-Jiménez, Santiago Nature Energy, Vol. 5, Issue 9 https://doi.org/10.1038/s41560-020-0678-6	journal	August 2020
Colloidal nanocrystals for photoelectrochemical and photocatalytic water splitting Gadiyar, Chethana; Loiudice, Anna; Buonsanti, Raffaella Journal of Physics D: Applied Physics, Vol. 50, Issue 7 https://doi.org/10.1088/1361-6463/aa50cd	journal	January 2017

Similar Records

Photocatalytically Active Superstructures of Quantum Dots and Iron Porphyrins for Reduction of CO₂ to CO in Water

Journal Article · 2018 · ACS Nano · OSTI ID:1470146

Lian, Shichen; Kodaimati, Mohamad S.; Weiss, Emily A.

Great improvement of photoelectric property from co-sensitization of TiO{sub 2} electrodes with CdS quantum dots and dye N719 in dye-sensitized solar cells

Journal Article · 2013 · Materials Research Bulletin · OSTI ID:22290467

Li, Jing; Zhao, Li; Wang, Shimin; +5 more

P-terphenyl-sensitized photoreduction of CO{sub 2} with cobalt and iron porphyrins. Interaction between CO and reduced metalloporphyrins

Journal Article · 1999 · Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, amp General Theory · OSTI ID:20000081

Dhanasekaran, T; Grodkowski, J; Neta, P; +2 more

Related Subjects

Chemistry

Quantum Dot-Sensitized Photoreduction of CO 2 in Water with Turnover Number > 80,000

Citation Formats

References (68)

Similar Records

Related Subjects

Quantum Dot-Sensitized Photoreduction of CO ₂ in Water with Turnover Number > 80,000