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Surface Hydrides on Fe 2 P Electrocatalyst Reduce CO 2 at Low Overpotential: Steering Selectivity to Ethylene Glycol

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.1c03428· OSTI ID:1978427
 [1];  [2];  [1];  [1];  [1];  [2];  [1];  [3];  [4]
  1. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Road, Piscataway, New Jersey 08854, United States
  2. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States
  3. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States; Renewable and Sustainable Energy Institute, University of Colorado Boulder, Boulder, Colorado 80309, United States
  4. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Road, Piscataway, New Jersey 08854, United States; Waksman Institute of Microbiology, Rutgers, The State University of New Jersey, 190 Frelinghuysen Road, Piscataway, New Jersey 08854, United States

Not provided.

Research Organization:
Univ. of Colorado, Boulder, CO (United States); Rutgers Univ., Piscataway, NJ (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0008088; SC0019460
OSTI ID:
1978427
Journal Information:
Journal of the American Chemical Society, Vol. 143, Issue 50; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (63)

Prism-Shaped Cu Nanocatalysts for Electrochemical CO 2 Reduction to Ethylene journal December 2017
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces journal January 2012
Robust carbon dioxide reduction on molybdenum disulphide edges journal July 2014
Effect of Chloride Anions on the Synthesis and Enhanced Catalytic Activity of Silver Nanocoral Electrodes for CO 2 Electroreduction journal August 2015
Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials journal September 2011
Water Enhancement of CO2 Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate journal November 2012
Active and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires journal November 2014
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO 2 Reduction journal July 2015
Molecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell journal July 2019
Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential journal October 2014
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles journal November 2012
Electrochemical Reduction of CO 2 at Copper Nanofoams journal August 2014
Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte journal July 1995
Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate journal November 2016
Electrodeposited porous Pb electrode with improved electrocatalytic performance for the electroreduction of CO2 to formic acid journal March 2015
Electrochemical CO 2 Reduction to Formic Acid at Low Overpotential and with High Faradaic Efficiency on Carbon-Supported Bimetallic Pd–Pt Nanoparticles journal June 2015
Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide journal November 2014
Electrocatalytic CO 2 reduction by M(bpy-R)(CO) 4 (M = Mo, W; R = H, tBu) complexes. Electrochemical, spectroscopic, and computational studies and comparison with group 7 catalysts journal January 2014
Incorporation of Pendant Bases into Rh(diphosphine) 2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO 2 Hydrogenation Activity of [Rh(P 2 N 2 ) 2 ] + Complexes journal June 2015
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate journal January 2014
Molecular tuning of CO2-to-ethylene conversion journal November 2019
Electrochemical Fragmentation of Cu 2 O Nanoparticles Enhancing Selective C–C Coupling from CO 2 Reduction Reaction journal January 2019
Cu oxide/ZnO-based surfaces for a selective ethylene production from gas-phase CO2 electroconversion journal May 2019
High-Selectivity Electrochemical Conversion of CO 2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode journal September 2016
Steering CO 2 electroreduction toward ethanol production by a surface-bound Ru polypyridyl carbene catalyst on N-doped porous carbon journal December 2019
Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper journal April 2020
Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution journal June 1986
Mechanistic Insights into the Enhanced Activity and Stability of Agglomerated Cu Nanocrystals for the Electrochemical Reduction of Carbon Dioxide to n -Propanol journal December 2015
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media journal August 1994
Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals journal January 2015
Structure-Sensitive CO 2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires journal January 2017
Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution
  • Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 8 https://doi.org/10.1039/f19898502309
journal January 1989
Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions journal December 2014
CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper journal April 2016
CO 2 Electroreduction at Low Overpotential on Oxide-Derived Cu/Carbons Fabricated from Metal Organic Framework journal February 2017
Morphology Matters: Tuning the Product Distribution of CO 2 Electroreduction on Oxide-Derived Cu Foam Catalysts journal May 2016
Electrochemical Reduction of Carbon Dioxide to Ethane Using Nanostructured Cu 2 O-Derived Copper Catalyst and Palladium(II) Chloride journal November 2015
Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts journal March 2015
The Predominance of Hydrogen Evolution on Transition Metal Sulfides and Phosphides under CO 2 Reduction Conditions: An Experimental and Theoretical Study journal May 2018
Selective CO 2 reduction to C 3 and C 4 oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV journal January 2018
Climbing the Volcano of Electrocatalytic Activity while Avoiding Catalyst Corrosion: Ni 3 P, a Hydrogen Evolution Electrocatalyst Stable in Both Acid and Alkali journal April 2018
Stable Phosphorus-Enriched (0001) Surfaces of Nickel Phosphides journal July 2016
Active Role of Phosphorus in the Hydrogen Evolving Activity of Nickel Phosphide (0001) Surfaces journal October 2017
Highly Selective Electrochemical Reduction of CO 2 to Alcohols on an FeP Nanoarray journal January 2020
MoP Nanoparticles Supported on Indium-Doped Porous Carbon: Outstanding Catalysts for Highly Efficient CO 2 Electroreduction journal February 2018
CO2 electro-reduction on Cu3P: Role of Cu(I) oxidation state and surface facet structure in C1-formate production and H2 selectivity journal September 2021
Boron Phosphide Nanoparticles: A Nonmetal Catalyst for High‐Selectivity Electrochemical Reduction of CO 2 to CH 3 OH journal July 2019
Formation of 1-Butanol from CO 2 without *CO Dimerization on a Phosphorus-Rich Copper Cathode journal May 2021
Electrochemical reduction of CO 2 to ethylene glycol on imidazolium ion-terminated self-assembly monolayer-modified Au electrodes in an aqueous solution journal January 2015
Ethylene oxide-mediated reduction of CO2 to CO and ethylene glycol catalysed by ruthenium complexes journal January 1995
A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes journal January 2011
Electrocatalytic Reduction of CO 2 to CO over Ag(110) and Cu(211) Modeled by Grand-Canonical Density Functional Theory journal October 2021
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction journal June 2013
Chemical Pressure-Driven Enhancement of the Hydrogen Evolving Activity of Ni 2 P from Nonmetal Surface Doping Interpreted via Machine Learning journal March 2018
Group Contribution Method for Thermodynamic Analysis of Complex Metabolic Networks journal August 2008
Estimation of standard Gibbs energy changes of biotransformations journal August 1991
Mechanistic Insights into CO 2 Electroreduction on Ni 2 P: Understanding Its Selectivity toward Multicarbon Products journal September 2021
Nanocrystalline Ni 5 P 4 : a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media journal January 2015
JDFTx: Software for joint density-functional theory journal January 2017
Generalized Gradient Approximation Made Simple journal October 1996
Optimized norm-conserving Vanderbilt pseudopotentials journal August 2013
Optimization algorithm for the generation of ONCV pseudopotentials journal November 2015
The charge-asymmetric nonlocally determined local-electric (CANDLE) solvation model journal February 2015