Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Atomically Reconstructed Palladium Metallene by Intercalation-Induced Lattice Expansion and Amorphization for Highly Efficient Electrocatalysis

Journal Article · · ACS Nano
 [1];  [1];  [2];  [3];  [1]
  1. Materials Science and Engineering Program and Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States
  2. Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China
  3. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, P.R. China

Not provided.

Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019019
OSTI ID:
1978394
Journal Information:
ACS Nano, Vol. 16, Issue 9; ISSN 1936-0851
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (59)

Pt‐Based Nanocrystal for Electrocatalytic Oxygen Reduction journal December 2018
Highly Durable and Active Pt-Based Nanoscale Design for Fuel-Cell Oxygen-Reduction Electrocatalysts journal January 2018
Beyond Extended Surfaces: Understanding the Oxygen Reduction Reaction on Nanocatalysts journal September 2020
Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications journal September 2015
Palladium alloys used as electrocatalysts for the oxygen reduction reaction journal January 2021
Enhancing the Electrocatalytic Activity of Pd/M (M = Ni, Mn) Nanoparticles for the Oxygen Reduction Reaction in Alkaline Media through Electrochemical Dealloying journal April 2020
Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications journal January 2019
How to Remove the Capping Agent from Pd Nanocubes without Destructing Their Surface Structure for the Maximization of Catalytic Activity? journal August 2020
Defect‐Rich Porous Palladium Metallene for Enhanced Alkaline Oxygen Reduction Electrocatalysis journal March 2021
Sublayer Stable Fe Dopant in Porous Pd Metallene Boosts Oxygen Reduction Reaction journal December 2021
High-Performance Electrocatalysis on Palladium Aerogels journal April 2012
Synthesis of PdM (M = Zn, Cd, ZnCd) Nanosheets with an Unconventional Face-Centered Tetragonal Phase as Highly Efficient Electrocatalysts for Ethanol Oxidation journal November 2019
Ligand‐Exchange‐Induced Amorphization of Pd Nanomaterials for Highly Efficient Electrocatalytic Hydrogen Evolution Reaction journal February 2020
Molecular understandings on the activation of light hydrocarbons over heterogeneous catalysts journal January 2015
Noble-Metal Nanocrystals with Controlled Shapes for Catalytic and Electrocatalytic Applications journal July 2020
Two-Dimensional Metal Nanomaterials: Synthesis, Properties, and Applications journal June 2018
General Synthesis of Large Inorganic Nanosheets via 2D Confined Assembly of Nanoparticles journal April 2022
Structural Engineering of 2D Nanomaterials for Energy Storage and Catalysis journal February 2018
Gel Electrocatalysts: An Emerging Material Platform for Electrochemical Energy Conversion journal August 2020
A mini review on two-dimensional nanomaterial assembly journal November 2019
Metallic Transition Metal Selenide Holey Nanosheets for Efficient Oxygen Evolution Electrocatalysis journal September 2017
Dual Tuning of Ni–Co–A (A = P, Se, O) Nanosheets by Anion Substitution and Holey Engineering for Efficient Hydrogen Evolution journal April 2018
Porous Two-dimensional Iron-Cyano Nanosheets for High-rate Electrochemical Nitrate Reduction journal December 2021
Electronic Modulation of Non‐van der Waals 2D Electrocatalysts for Efficient Energy Conversion journal May 2021
Metallenes as functional materials in electrocatalysis journal January 2021
Cr‐Doped Pd Metallene Endows a Practical Formaldehyde Sensor New Limit and High Selectivity journal November 2021
Hydrogen Stabilized RhPdH 2D Bimetallene Nanosheets for Efficient Alkaline Hydrogen Evolution journal February 2020
PdMo bimetallene for oxygen reduction catalysis journal September 2019
Tunable intrinsic strain in two-dimensional transition metal electrocatalysts journal February 2019
Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride journal December 2015
PdC x nanocrystals with tunable compositions for alkyne semihydrogenation journal January 2019
Hydrothermal synthesis of palladium nitrides as robust multifunctional electrocatalysts for fuel cells journal January 2021
Transition metal nitrides for electrochemical energy applications journal January 2021
Lithiation-induced amorphization of Pd3P2S8 for highly efficient hydrogen evolution journal May 2018
Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis journal March 2013
Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide journal March 2016
Characterization of bimetallic core–shell nanorings synthesized via ascorbic acid-controlled galvanic displacement followed by epitaxial growth journal January 2014
Freestanding palladium nanosheets with plasmonic and catalytic properties journal December 2010
Phase-Selective Epitaxial Growth of Heterophase Nanostructures on Unconventional 2H-Pd Nanoparticles journal October 2020
Ligand Effect of Shape-Controlled β-Palladium Hydride Nanocrystals on Liquid-Fuel Oxidation Reactions journal July 2019
Sulfurization-induced partially amorphous palladium sulfide nanosheets for highly efficient electrochemical hydrogen evolution journal January 2021
Operando Raman Spectroscopy of Amorphous Molybdenum Sulfide (MoS x ) during the Electrochemical Hydrogen Evolution Reaction: Identification of Sulfur Atoms as Catalytically Active Sites for H + Reduction journal October 2016
Design and Synthesis of Bimetallic Electrocatalyst with Multilayered Pt-Skin Surfaces journal September 2011
Synergistically Enhanced Oxygen Reduction Electrocatalysis by Subsurface Atoms in Ternary PdCuNi Alloy Catalysts journal February 2018
Insights into the morphology and composition effects of one-dimensional CuPt nanostructures on the electrocatalytic activities and methanol oxidation mechanism by in situ FTIR journal January 2020
Hydrogen-Intercalation-Induced Lattice Expansion of Pd@Pt Core–Shell Nanoparticles for Highly Efficient Electrocatalytic Alcohol Oxidation journal July 2021
Electrocatalysis of formic acid on palladium and platinum surfaces: from fundamental mechanisms to fuel cell applications journal January 2014
Platinum Monolayer Electrocatalysts for Anodic Oxidation of Alcohols journal November 2012
Unconventional p–d Hybridization Interaction in PtGa Ultrathin Nanowires Boosts Oxygen Reduction Electrocatalysis journal October 2019
Extraordinary p–d Hybridization Interaction in Heterostructural Pd‐PdSe Nanosheets Boosts C−C Bond Cleavage of Ethylene Glycol Electrooxidation journal February 2022
Transition‐Metal–Boron Intermetallics with Strong Interatomic d–sp Orbital Hybridization for High‐Performance Electrocatalysis journal January 2020
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution journal January 2014
Dimeric [Mo 2 S 12 ] 2− Cluster: A Molecular Analogue of MoS 2 Edges for Superior Hydrogen-Evolution Electrocatalysis journal October 2015
Accurate description of van der Waals complexes by density functional theory including empirical corrections journal January 2004
An all‐electron numerical method for solving the local density functional for polyatomic molecules journal January 1990
From molecules to solids with the DMol3 approach journal November 2000
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
The conductor-like screening model for polymers and surfaces journal February 2006
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient journal January 1993