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Universal Polymeric-to-Colloidal Transition in Melts of Hairy Nanoparticles

Journal Article · · ACS Nano
 [1];  [2];  [1];  [3];  [4];  [5];  [6];  [7];  [2];  [1]
  1. Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece
  2. Department of Chemical Engineering, Columbia University, New York, New York 10025, United States
  3. Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL Research University, 75005 Paris, France
  4. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States
  5. Department of Chemistry, Institute for Polymer Research, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada
  6. Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL Research University, 75005 Paris, France
  7. Thomas Lord Departments of Mechanical Engineering and Materials Science, Biomedical Engineering, Chemistry, and Physics, Duke University, Durham, North Carolina 27708, United States; Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo 001-0021, Japan

Not provided.

Research Organization:
Columbia Univ., New York, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021272
OSTI ID:
1978378
Journal Information:
ACS Nano, Vol. 15, Issue 10; ISSN 1936-0851
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (75)

A Versatile Method To Prepare RAFT Agent Anchored Substrates and the Preparation of PMMA Grafted Nanoparticles May 2006
Polymer-Grafted-Nanoparticles Nanocomposites: Dispersion, Grafted Chain Conformation, and Rheological Behavior January 2011
Nanocomposites with Polymer Grafted Nanoparticles April 2013
Phase stability and dynamics of entangled polymer–nanoparticle composites June 2015
Compatibilizing Immiscible Polymer Blends with Sparsely Grafted Nanoparticles November 2020
Polymers on nanoparticles: structure & dynamics January 2019
Effective interactions between grafted nanoparticles in a polymer matrix January 2012
Dynamics of solvent-free grafted nanoparticles January 2012
A Phase Diagram for Polymer-Grafted Nanoparticles in Homopolymer Matrices April 2012
Mechanical Reinforcement in Polymer Melts Filled with Polymer Grafted Nanoparticles September 2011
Tethered Nanoparticle–Polymer Composites: Phase Stability and Curvature April 2012
Grafted polymer chains suppress nanoparticle diffusion in athermal polymer melts May 2017
Static and dynamic properties of computer simulated melts of multiarm polymer stars January 1998
Structural Transitions of Solvent-Free Oligomer-Grafted Nanoparticles September 2011
Polymer-Grafted Nanoparticle Membranes with Controllable Free Volume September 2017
The Ages in a Self-Suspended Nanoparticle Liquid January 2010
Self-Suspended Suspensions of Covalently Grafted Hairy Nanoparticles March 2015
Self-suspended polymer grafted nanoparticles May 2017
Nanoparticle Brush Architecture Controls Polymer Diffusion in Nanocomposites March 2014
Thermal and Rheological Analysis of Polystyrene-Grafted Silica Nanocomposites March 2020
Dynamics of Copolymer Micelles in an Entangled Homopolymer Matrix September 1999
Optimum Graft Density for Dispersing Particles in Polymer Melts January 1996
Effects of Geometric Confinement on Caging and Dynamics of Polymer-Tethered Nanoparticle Suspensions December 2020
Steady-Shear Rheology of Block Copolymer Melts:  Zero-Shear Viscosity and Shear Disordering in Body-Centered-Cubic Systems March 2002
Steady-shear rheology of block copolymer melts and concentrated solutions: Defect-mediated flow at low stresses in body-centered-cubic systems January 2002
Star shaped polymers : a model for the conformation and its concentration dependence January 1982
Micellar Solutions of Associative Triblock Copolymers:  Entropic Attraction and Gas−Liquid Transition May 1999
Microscopic Origins of Caging and Equilibration of Self-Suspended Hairy Nanoparticles October 2019
Structure and Dynamics of Melts of Multiarm Polymer Stars December 1998
Macromolecular topology and rheology: beyond the tube model June 2016
Tunable rheology of dense soft deformable colloids December 2014
Viscoelastic response of hyperstar polymers in the linear regime July 1999
Colloidal Jamming in Multiarm Star Polymer Melts June 2019
Scaling Law for Entropic Effects at Interfaces between Grafted Layers and Polymer Melts June 1998
Wetting of Grafted Polymer Surfaces by Compatible Chains January 1994
Conformation of star polymers in high-molecular-weight solvents April 1993
Structure of Polymer-Grafted Nanoparticle Melts October 2020
Soft polymeric nanoparticle additives for next generation gas separation membranes January 2014
Nanocomposite membranes consisting of poly(vinyl chloride) graft copolymer and surface-modified silica nanoparticles October 2011
Effect of PMMA-graft-silica nanoparticles on the gas permeation properties of hexafluoroisopropylidene-based polyimide membranes April 2011
Gas separation using polymer membranes: an overview November 1994
Tuning Selectivities in Gas Separation Membranes Based on Polymer-Grafted Nanoparticles November 2020
Application of free-volume theory to self diffusion of solvents in polymers below the glass transition temperature: A review September 2011
Strong Reduction in Amplitude of the Interfacial Segmental Dynamics in Polymer Nanocomposites May 2020
Critical Role of the Interfacial Layer in Associating Polymers with Microphase Separation April 2021
Layers of Distinct Mobility in Densely Grafted Dendrimer Arborescent Polymer Hybrids May 2021
Chain Dimensions and Entanglement Spacings January 2007
Theory of Filler Reinforcement January 1945
Characterization of Fillers in Vulcanizates According to the Einstein-Guth-Gold Equation March 1990
Viscoelasticity, Nonlinear Shear Start-up, and Relaxation of Entangled Star Polymers July 2013
Dynamics and rheology of colloidal star polymers January 2010
Static and dynamic properties of block copolymer based grafted nanoparticles across the non-ergodicity transition December 2020
Dynamics of concentrated colloidal suspensions January 1997
Colloidal glasses and gels: The interplay of bonding and caging August 2009
A regularization method for nonlinear ill-posed problems November 1993
Using regularization methods for the determination of relaxation and retardation spectra of polymeric liquids January 1992
A nonlinear regularization method for the calculation of relaxation spectra January 1993
Branch-Point Motion in Architecturally Complex Polymers: Estimation of Hopping Parameters from Computer Simulations and Experiments May 2014
The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids July 1955
Molecular Dynamics Study of Fictive Temperature Dependence of Density of Vitreous Silica October 2005
Parameter-Free Theory for Stress Relaxation in Star Polymer Melts April 1997
Reptation and Contour-Length Fluctuations in Melts of Linear Polymers July 1998
Quantitative Theory for Linear Dynamics of Linear Entangled Polymers July 2002
Two-parameter scaling for polymers in Θ solvents May 1990
Power-law-like stress relaxation of block copolymers: disentanglement regimes March 1993
Hopping Diffusion of Nanoparticles in Polymer Matrices January 2015
Rheology of Polymer Brushes: Rouse Model September 1995
Stress relaxation in the lamellar copolymer mesophase February 1990
Multiarm star polymers dynamics September 2001
Rheological behavior of star-shaped polymers July 1993
Dynamics of Star-Shaped Polystyrene Molecules: From Arm Retraction to Cooperativity July 2016
Relaxation and viscoelastic properties of complex polymer systems January 1996
Relaxation of Spherical Micellar Systems of Styrene−Isoprene Diblock Copolymers. 1. Linear Viscoelastic and Dielectric Behavior January 1996
Polymer Brushes via Surface-Initiated Controlled Radical Polymerization: Synthesis, Characterization, Properties, and Applications November 2009
Synthesis of 1,4-Polybutadiene Dendrimer−Arborescent Polymer Hybrids March 2010