High-Performance Anode-Free Li–S Batteries with an Integrated Li 2 S–Electrocatalyst Cathode

He, Jiarui; Bhargav, Amruth; Manthiram, Arumugam

doi:10.1021/acsenergylett.1c02569

High-Performance Anode-Free Li–S Batteries with an Integrated Li ₂ S–Electrocatalyst Cathode

Journal Article · 07 January 2022 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.1c02569· OSTI ID:1978342

^[1]; ^[1]; ^[1]

Materials Science and Engineering Program & Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, United States

Not provided.

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0005397

OSTI ID:: 1978342

Journal Information:: ACS Energy Letters, Vol. 7, Issue 2; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (45)

A reflection on lithium-ion battery cathode chemistry Manthiram, Arumugam Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15355-0	journal	March 2020
Lithium Metal Batteries Enabled by Synergetic Additives in Commercial Carbonate Electrolytes Piao, Nan; Liu, Sufu; Zhang, Bao ACS Energy Letters, Vol. 6, Issue 5 https://doi.org/10.1021/acsenergylett.1c00365	journal	April 2021
A compact inorganic layer for robust anode protection in lithium‐sulfur batteries Yao, Yu‐Xing; Zhang, Xue‐Qiang; Li, Bo‐Quan InfoMat, Vol. 2, Issue 2 https://doi.org/10.1002/inf2.12046	journal	November 2019
3D CoSe@C Aerogel as a Host for Dendrite‐Free Lithium‐Metal Anode and Efficient Sulfur Cathode in Li–S Full Cells He, Jiarui; Manthiram, Arumugam Advanced Energy Materials, Vol. 10, Issue 41 https://doi.org/10.1002/aenm.202002654	journal	September 2020
Mechanistic understanding of the role separators playing in advanced lithium‐sulfur batteries Wei, Zhaohuan; Ren, Yaqi; Sokolowski, Joshua InfoMat, Vol. 2, Issue 3 https://doi.org/10.1002/inf2.12097	journal	March 2020
A Dual‐Functional Conductive Framework Embedded with TiN‐VN Heterostructures for Highly Efficient Polysulfide and Lithium Regulation toward Stable Li–S Full Batteries Yao, Yu; Wang, Haiyun; Yang, Hai Advanced Materials, Vol. 32, Issue 6 https://doi.org/10.1002/adma.201905658	journal	December 2019
Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries Xin, Sen; Gu, Lin; Zhao, Na-Hong Journal of the American Chemical Society, Vol. 134, Issue 45 https://doi.org/10.1021/ja308170k	journal	October 2012
Two‐dimensional MXenes for lithium‐sulfur batteries Zhang, Chuanfang (John); Cui, Linfan; Abdolhosseinzadeh, Sina InfoMat, Vol. 2, Issue 4 https://doi.org/10.1002/inf2.12080	journal	January 2020
Layered LiTiO ₂ for the protection of Li ₂ S cathodes against dissolution: mechanisms of the remarkable performance boost Wu, Feixiang; Pollard, Travis P.; Zhao, Enbo Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/C8EE00419F	journal	January 2018
Synchronous immobilization and conversion of polysulfides on a VO ₂ –VN binary host targeting high sulfur load Li–S batteries Song, Yingze; Zhao, Wen; Kong, Long Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE01402G	journal	January 2018
Stable Dendrite-Free Sodium–Sulfur Batteries Enabled by a Localized High-Concentration Electrolyte He, Jiarui; Bhargav, Amruth; Shin, Woochul Journal of the American Chemical Society, Vol. 143, Issue 48 https://doi.org/10.1021/jacs.1c08851	journal	November 2021
Enhanced Catalytic Conversion of Polysulfides Using Bimetallic Co ₇ Fe ₃ for High-Performance Lithium–Sulfur Batteries Zeng, Pan; Liu, Cheng; Zhao, Xiaofeng ACS Nano, Vol. 14, Issue 9 https://doi.org/10.1021/acsnano.0c04054	journal	August 2020
Optimized Catalytic WS ₂ –WO ₃ Heterostructure Design for Accelerated Polysulfide Conversion in Lithium–Sulfur Batteries Zhang, Bin; Luo, Chong; Deng, Yaqian Advanced Energy Materials, Vol. 10, Issue 15 https://doi.org/10.1002/aenm.202000091	journal	February 2020
1T′‐ReS ₂ Nanosheets In Situ Grown on Carbon Nanotubes as a Highly Efficient Polysulfide Electrocatalyst for Stable Li–S Batteries He, Jiarui; Bhargav, Amruth; Yaghoobnejad Asl, Hooman Advanced Energy Materials, Vol. 10, Issue 23 https://doi.org/10.1002/aenm.202001017	journal	May 2020
Stringed “tube on cube” nanohybrids as compact cathode matrix for high-loading and lean-electrolyte lithium–sulfur batteries Li, Gaoran; Lei, Wen; Luo, Dan Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE01377B	journal	January 2018
Three-Dimensional CNT/Graphene–Li ₂ S Aerogel as Freestanding Cathode for High-Performance Li–S Batteries He, Jiarui; Chen, Yuanfu; Lv, Weiqiang ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00272	journal	September 2016
A Rational Reconfiguration of Electrolyte for High‐Energy and Long‐Life Lithium–Chalcogen Batteries Wang, Wen‐Peng; Zhang, Juan; Yin, Ya‐Xia Advanced Materials, Vol. 32, Issue 23 https://doi.org/10.1002/adma.202000302	journal	May 2020
Electrochemical Phase Evolution of Metal‐Based Pre‐Catalysts for High‐Rate Polysulfide Conversion Zhao, Meng; Peng, Hong‐Jie; Li, Bo‐Quan Angewandte Chemie International Edition, Vol. 59, Issue 23 https://doi.org/10.1002/anie.202003136	journal	April 2020
Lithium-Sulfur Batteries: Attaining the Critical Metrics Bhargav, Amruth; He, Jiarui; Gupta, Abhay Joule, Vol. 4, Issue 2 https://doi.org/10.1016/j.joule.2020.01.001	journal	February 2020
Anode-free, Lean-Electrolyte Lithium-Sulfur Batteries Enabled by Tellurium-Stabilized Lithium Deposition Nanda, Sanjay; Bhargav, Amruth; Manthiram, Arumugam Joule, Vol. 4, Issue 5 https://doi.org/10.1016/j.joule.2020.03.020	journal	May 2020
Evoking High-Donor-Number-Assisted and Organosulfur-Mediated Conversion in Lithium–Sulfur Batteries Gupta, Abhay; Bhargav, Amruth; Manthiram, Arumugam ACS Energy Letters, Vol. 6, Issue 1 https://doi.org/10.1021/acsenergylett.0c02461	journal	December 2020
Anode‐Free Full Cells: A Pathway to High‐Energy Density Lithium‐Metal Batteries Nanda, Sanjay; Gupta, Abhay; Manthiram, Arumugam Advanced Energy Materials https://doi.org/10.1002/aenm.202000804	journal	May 2020
Fe3N@N-doped graphene as a lithiophilic interlayer for highly stable lithium metal batteries Zhang, Xiaojuan; Ma, Fei; Srinivas, Katam Energy Storage Materials, Vol. 45 https://doi.org/10.1016/j.ensm.2021.12.010	journal	March 2022
Delineating the Lithium–Electrolyte Interfacial Chemistry and the Dynamics of Lithium Deposition in Lithium–Sulfur Batteries Nanda, Sanjay; Manthiram, Arumugam Advanced Energy Materials, Vol. 11, Issue 11 https://doi.org/10.1002/aenm.202003293	journal	January 2021
Consolidating Lithiothermic‐Ready Transition Metals for Li ₂ S‐Based Cathodes Xing, Zhenyu; Tan, Guoqiang; Yuan, Yifei Advanced Materials, Vol. 32, Issue 31 https://doi.org/10.1002/adma.202002403	journal	June 2020
A High‐Efficiency CoSe Electrocatalyst with Hierarchical Porous Polyhedron Nanoarchitecture for Accelerating Polysulfides Conversion in Li–S Batteries Ye, Zhengqing; Jiang, Ying; Li, Li Advanced Materials, Vol. 32, Issue 32 https://doi.org/10.1002/adma.202002168	journal	June 2020
Mo2C quantum dots@graphene functionalized separator toward high-current-density lithium metal anodes for ultrastable Li-S batteries Yu, Bo; Chen, Dongjiang; Wang, Zegao Chemical Engineering Journal, Vol. 399 https://doi.org/10.1016/j.cej.2020.125837	journal	November 2020
Anode-Free Rechargeable Lithium Metal Batteries Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602353	journal	August 2016
A Lithium-Sulfur Cell Based on Reversible Lithium Deposition from a Li ₂ S Cathode Host onto a Hostless-Anode Substrate Nanda, Sanjay; Gupta, Abhay; Manthiram, Arumugam Advanced Energy Materials, Vol. 8, Issue 25 https://doi.org/10.1002/aenm.201801556	journal	July 2018
Implications of in situ chalcogen substitutions in polysulfides for rechargeable batteries Nanda, Sanjay; Bhargav, Amruth; Jiang, Zhou Energy & Environmental Science, Vol. 14, Issue 10 https://doi.org/10.1039/D1EE01113H	journal	January 2021
Metal Sulfide‐Decorated Carbon Sponge as a Highly Efficient Electrocatalyst and Absorbant for Polysulfide in High‐Loading Li ₂ S Batteries He, Jiarui; Chen, Yuanfu; Manthiram, Arumugam Advanced Energy Materials, Vol. 9, Issue 20 https://doi.org/10.1002/aenm.201900584	journal	April 2019
High-Energy-Density, Long-Life Lithium–Sulfur Batteries with Practically Necessary Parameters Enabled by Low-Cost Fe–Ni Nanoalloy Catalysts He, Jiarui; Bhargav, Amruth; Manthiram, Arumugam ACS Nano, Vol. 15, Issue 5 https://doi.org/10.1021/acsnano.1c00446	journal	April 2021
Bidirectional Catalysts for Liquid–Solid Redox Conversion in Lithium–Sulfur Batteries Wang, Ruochen; Luo, Chong; Wang, Tianshuai Advanced Materials, Vol. 32, Issue 32 https://doi.org/10.1002/adma.202000315	journal	July 2020
Cobalt-Doped SnS ₂ with Dual Active Centers of Synergistic Absorption-Catalysis Effect for High-S Loading Li-S Batteries Gao, Xuejie; Yang, Xiaofei; Li, Minsi Advanced Functional Materials, Vol. 29, Issue 8 https://doi.org/10.1002/adfm.201806724	journal	January 2019
Activating Inert Metallic Compounds for High‐Rate Lithium–Sulfur Batteries Through In Situ Etching of Extrinsic Metal Zhao, Meng; Peng, Hong‐Jie; Zhang, Ze‐Wen Angewandte Chemie International Edition, Vol. 58, Issue 12 https://doi.org/10.1002/anie.201812062	journal	March 2019
High performance bimetal sulfides for lithium-sulfur batteries Lu, Xianlu; Zhang, Qingfeng; Wang, Jue Chemical Engineering Journal, Vol. 358 https://doi.org/10.1016/j.cej.2018.10.104	journal	February 2019
Rational design of Co9S8/CoO heterostructures with well-defined interfaces for lithium sulfur batteries: A study of synergistic adsorption-electrocatalysis function Wang, Ning; Chen, Biao; Qin, Kaiqiang Nano Energy, Vol. 60 https://doi.org/10.1016/j.nanoen.2019.03.060	journal	June 2019
Intercalation-conversion hybrid cathodes enabling Li–S full-cell architectures with jointly superior gravimetric and volumetric energy densities Xue, Weijiang; Shi, Zhe; Suo, Liumin Nature Energy, Vol. 4, Issue 5 https://doi.org/10.1038/s41560-019-0351-0	journal	March 2019
Twinborn TiO ₂ –TiN heterostructures enabling smooth trapping–diffusion–conversion of polysulfides towards ultralong life lithium–sulfur batteries Zhou, Tianhong; Lv, Wei; Li, Jia Energy & Environmental Science, Vol. 10, Issue 7 https://doi.org/10.1039/C7EE01430A	journal	January 2017
Electrocatalysis of polysulfide conversion by sulfur-deficient MoS ₂ nanoflakes for lithium–sulfur batteries Lin, Haibin; Yang, Liuqing; Jiang, Xi Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/C7EE01047H	journal	January 2017
Toward Environmentally Friendly Lithium Sulfur Batteries: Probing the Role of Electrode Design in MoS ₂ -Containing Li–S Batteries with a Green Electrolyte Wang, Lei; Abraham, Alyson; Lutz, Diana M. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5 https://doi.org/10.1021/acssuschemeng.8b06141	journal	February 2019
Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis Babu, Ganguli; Masurkar, Nirul; Al Salem, Hesham Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b08681	journal	December 2016
2D MoN‐VN Heterostructure To Regulate Polysulfides for Highly Efficient Lithium‐Sulfur Batteries Ye, Chao; Jiao, Yan; Jin, Huanyu Angewandte Chemie International Edition, Vol. 57, Issue 51 https://doi.org/10.1002/anie.201810579	journal	December 2018
Molybdenum Boride as an Efficient Catalyst for Polysulfide Redox to Enable High‐Energy‐Density Lithium–Sulfur Batteries He, Jiarui; Bhargav, Amruth; Manthiram, Arumugam Advanced Materials, Vol. 32, Issue 40 https://doi.org/10.1002/adma.202004741	journal	August 2020
Conductive and Catalytic Triple-Phase Interfaces Enabling Uniform Nucleation in High-Rate Lithium-Sulfur Batteries Yuan, Hong; Peng, Hong-Jie; Li, Bo-Quan Advanced Energy Materials, Vol. 9, Issue 1 https://doi.org/10.1002/aenm.201802768	journal	October 2018

Similar Records

Metal Sulfide-Decorated Carbon Sponge as a Highly Efficient Electrocatalyst and Absorbant for Polysulfide in High-Loading Li ₂ S Batteries

Journal Article · 2019 · Advanced Energy Materials · OSTI ID:1610834

He, Jiarui; Chen, Yuanfu; Manthiram, Arumugam

Metal Sulfide‐Decorated Carbon Sponge as a Highly Efficient Electrocatalyst and Absorbant for Polysulfide in High‐Loading Li ₂ S Batteries

Journal Article · 2019 · Advanced Energy Materials · OSTI ID:1505655

He, Jiarui; Chen, Yuanfu; Manthiram, Arumugam

1T'-ReS ₂ Nanosheets In Situ Grown on Carbon Nanotubes as a Highly Efficient Polysulfide Electrocatalyst for Stable Li–S Batteries

Journal Article · 2020 · Advanced Energy Materials · OSTI ID:1801674

He, Jiarui; Bhargav, Amruth; Yaghoobnejad Asl, Hooman; +2 more

Related Subjects

Chemistry
Electrochemistry
Energy & Fuels
Science & Technology - Other Topics
Materials Science

High-Performance Anode-Free Li–S Batteries with an Integrated Li 2 S–Electrocatalyst Cathode

Citation Formats

References (45)

Similar Records

Related Subjects

High-Performance Anode-Free Li–S Batteries with an Integrated Li ₂ S–Electrocatalyst Cathode