Imaging Real-Time Amorphization of Hybrid Perovskite Solar Cells under Electrical Biasing

Kim, Min-cheol; Ahn, Namyoung; Cheng, Diyi; Xu, Mingjie; Ham, So-Yeon; Pan, Xiaoqing; Kim, Suk Jun; Luo, Yanqi; Fenning, David P.; Tan, Darren H.  S.; Zhang, Minghao; Zhu, Guomin; Jeong, Kiwan; Choi, Mansoo; Meng, Ying Shirley

doi:10.1021/acsenergylett.1c01707

Imaging Real-Time Amorphization of Hybrid Perovskite Solar Cells under Electrical Biasing

Journal Article · 14 September 2021 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.1c01707· OSTI ID:1978336

Kim, Min-cheol ^[1]; Ahn, Namyoung ^[2]; Cheng, Diyi ^[3]; Xu, Mingjie ^[4]; Ham, So-Yeon ^[3]; Pan, Xiaoqing ^[4]; Kim, Suk Jun ^[5]; ^[6]; ^[6]; Tan, Darren H. S. ^[6]; Zhang, Minghao ^[6]; Zhu, Guomin ^[6]; Jeong, Kiwan ^[2]; ^[7]; ^[8]

Department of NanoEngineering, University of California San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States; School of Mechanical Engineering, Pusan National University, Busan 46241, Korea
Global Frontier Center for Multiscale Energy Systems, Seoul National University, Seoul 08826, Republic of Korea
Materials Science and Engineering Program, University of California San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States
Irvine Materials Research Institute, University of California Irvine, Irvine, California 92697, United States
School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea
Department of NanoEngineering, University of California San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States
Global Frontier Center for Multiscale Energy Systems, Seoul National University, Seoul 08826, Republic of Korea; Department of Mechanical Engineering, Seoul National University, Seoul 08826, Republic of Korea
Department of NanoEngineering, University of California San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States; Materials Science and Engineering Program, University of California San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States

Not provided.

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0002357

OSTI ID:: 1978336

Journal Information:: ACS Energy Letters, Vol. 6, Issue 10; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (47)

Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites Kim, Daehan; Jung, Hee Joon; Park, Ik Jae Science, Vol. 368, Issue 6487 https://doi.org/10.1126/science.aba3433	journal	March 2020
Ultra-flexible perovskite solar cells with crumpling durability: toward a wearable power source Lee, Gunhee; Kim, Min-cheol; Choi, Yong Whan Energy & Environmental Science, Vol. 12, Issue 10 https://doi.org/10.1039/C9EE01944H	journal	January 2019
A technoeconomic analysis of perovskite solar module manufacturing with low-cost materials and techniques Song, Zhaoning; McElvany, Chad L.; Phillips, Adam B. Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/C7EE00757D	journal	January 2017
Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells Zuo, Lijian; Guo, Hexia; deQuilettes, Dane W. Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1700106	journal	August 2017
Degradation observations of encapsulated planar CH ₃ NH ₃ PbI ₃ perovskite solar cells at high temperatures and humidity Han, Yu; Meyer, Steffen; Dkhissi, Yasmina Journal of Materials Chemistry A, Vol. 3, Issue 15 https://doi.org/10.1039/C5TA00358J	journal	January 2015
Ionic transport in hybrid lead iodide perovskite solar cells Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8497	journal	June 2015
Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis Calado, Philip; Telford, Andrew M.; Bryant, Daniel Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13831	journal	December 2016
Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation Azpiroz, Jon M.; Mosconi, Edoardo; Bisquert, Juan Energy & Environmental Science, Vol. 8, Issue 7 https://doi.org/10.1039/C5EE01265A	journal	January 2015
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6784	journal	December 2014
Giant switchable photovoltaic effect in organometal trihalide perovskite devices Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4150	journal	December 2014
Mapping Electric Field-Induced Switchable Poling and Structural Degradation in Hybrid Lead Halide Perovskite Thin Films Leijtens, Tomas; Hoke, Eric T.; Grancini, Giulia Advanced Energy Materials, Vol. 5, Issue 20 https://doi.org/10.1002/aenm.201500962	journal	September 2015
Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability Yuan, Yongbo; Huang, Jinsong Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00420	journal	January 2016
Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells Domanski, Konrad; Roose, Bart; Matsui, Taisuke Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE03352K	journal	January 2017
Trapped charge-driven degradation of perovskite solar cells Ahn, Namyoung; Kwak, Kwisung; Jang, Min Seok Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13422	journal	November 2016
Systematic investigation of the impact of operation conditions on the degradation behaviour of perovskite solar cells Domanski, Konrad; Alharbi, Essa A.; Hagfeldt, Anders Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0060-5	journal	January 2018
Light-activated photocurrent degradation and self-healing in perovskite solar cells Nie, Wanyi; Blancon, Jean-Christophe; Neukirch, Amanda J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11574	journal	May 2016
Degradation of CH ₃ NH ₃ PbI ₃ perovskite materials by localized charges and its polarity dependency Kim, Min-cheol; Ahn, Namyoung; Lim, Eunhak Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/C9TA03180D	journal	January 2019
Ion Migration‐Induced Amorphization and Phase Segregation as a Degradation Mechanism in Planar Perovskite Solar Cells Di Girolamo, Diego; Phung, Nga; Kosasih, Felix Utama Advanced Energy Materials, Vol. 10, Issue 25 https://doi.org/10.1002/aenm.202000310	journal	June 2020
In Situ TEM Analysis of Organic–Inorganic Metal-Halide Perovskite Solar Cells under Electrical Bias Jeangros, Quentin; Duchamp, Martial; Werner, Jérémie Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03158	journal	October 2016
Light- and bias-induced structural variations in metal halide perovskites Kim, Dohyung; Yun, Jae Sung; Sharma, Pankaj Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08364-1	journal	January 2019
Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites Bischak, Connor G.; Hetherington, Craig L.; Wu, Hao Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b04453	journal	January 2017
Direct Observation of Halide Migration and its Effect on the Photoluminescence of Methylammonium Lead Bromide Perovskite Single Crystals Luo, Yanqi; Khoram, Parisa; Brittman, Sarah Advanced Materials, Vol. 29, Issue 43 https://doi.org/10.1002/adma.201703451	journal	September 2017
Caffeine Improves the Performance and Thermal Stability of Perovskite Solar Cells Wang, Rui; Xue, Jingjing; Meng, Lei Joule, Vol. 3, Issue 6 https://doi.org/10.1016/j.joule.2019.04.005	journal	June 2019
First-Principles Study of Ion Diffusion in Perovskite Solar Cell Sensitizers Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b03615	journal	August 2015
Focused Ion Beam Fabrication of LiPON-based Solid-state Lithium-ion Nanobatteries for In Situ Testing Lee, Jungwoo Z.; Wynn, Thomas A.; Meng, Ying Shirley Journal of Visualized Experiments, Issue 133 https://doi.org/10.3791/56259	journal	January 2018
The intrinsic properties of FA _(1−x) MA _x PbI ₃ perovskite single crystals Huang, Yuan; Li, Liang; Liu, Zonghao Journal of Materials Chemistry A, Vol. 5, Issue 18 https://doi.org/10.1039/C7TA01441D	journal	January 2017
Atomic Layer Deposition of PbI ₂ Thin Films Popov, Georgi; Mattinen, Miika; Hatanpää, Timo Chemistry of Materials, Vol. 31, Issue 3 https://doi.org/10.1021/acs.chemmater.8b04969	journal	January 2019
Challenges, myths, and opportunities of electron microscopy on halide perovskites Chen, Shulin; Gao, Peng Journal of Applied Physics, Vol. 128, Issue 1 https://doi.org/10.1063/5.0012310	journal	July 2020
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Li, Zhen; Yang, Mengjin; Park, Ji-Sang Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04107	journal	December 2015
Imperfections and their passivation in halide perovskite solar cells Chen, Bo; Rudd, Peter N.; Yang, Shuang Chemical Society Reviews, Vol. 48, Issue 14 https://doi.org/10.1039/C8CS00853A	journal	January 2019
Electric-Field-Induced Degradation of Methylammonium Lead Iodide Perovskite Solar Cells Bae, Soohyun; Kim, Seongtak; Lee, Sang-Won The Journal of Physical Chemistry Letters, Vol. 7, Issue 16 https://doi.org/10.1021/acs.jpclett.6b01176	journal	July 2016
Ionic–Electronic Ambipolar Transport in Metal Halide Perovskites: Can Electronic Conductivity Limit Ionic Diffusion? Kerner, Ross A.; Rand, Barry P. The Journal of Physical Chemistry Letters, Vol. 9, Issue 1 https://doi.org/10.1021/acs.jpclett.7b02401	journal	December 2017
Light and Electrically Induced Phase Segregation and Its Impact on the Stability of Quadruple Cation High Bandgap Perovskite Solar Cells Duong, The; Mulmudi, Hemant Kumar; Wu, YiLiang ACS Applied Materials & Interfaces, Vol. 9, Issue 32 https://doi.org/10.1021/acsami.7b06816	journal	August 2017
Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C6EE00409A	journal	January 2016
Nonradiative Losses in Metal Halide Perovskites Stranks, Samuel D. ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00239	journal	June 2017
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance Saliba, M.; Matsui, T.; Domanski, K. Science, Vol. 354, Issue 6309 https://doi.org/10.1126/science.aah5557	journal	September 2016
Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability Bag, Monojit; Renna, Lawrence A.; Adhikari, Ramesh Y. Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b08535	journal	September 2015
Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide Anaraki, Elham Halvani; Kermanpur, Ahmad; Steier, Ludmilla Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02390H	journal	January 2016
Surface Recombination and Collection Efficiency in Perovskite Solar Cells from Impedance Analysis Zarazua, Isaac; Han, Guifang; Boix, Pablo P. The Journal of Physical Chemistry Letters, Vol. 7, Issue 24 https://doi.org/10.1021/acs.jpclett.6b02193	journal	November 2016
Properties of Contact and Bulk Impedances in Hybrid Lead Halide Perovskite Solar Cells Including Inductive Loop Elements Guerrero, Antonio; Garcia-Belmonte, Germà; Mora-Sero, Ivan The Journal of Physical Chemistry C, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpcc.6b01728	journal	April 2016
Inductive Loop in the Impedance Response of Perovskite Solar Cells Explained by Surface Polarization Model Ghahremanirad, Elnaz; Bou, Agustín; Olyaee, Saeed The Journal of Physical Chemistry Letters, Vol. 8, Issue 7 https://doi.org/10.1021/acs.jpclett.7b00415	journal	March 2017
Negative capacitance or inductive loop? – A general assessment of a common low frequency impedance feature Klotz, Dino Electrochemistry Communications, Vol. 98 https://doi.org/10.1016/j.elecom.2018.11.017	journal	January 2019
Origin of apparent light-enhanced and negative capacitance in perovskite solar cells Ebadi, Firouzeh; Taghavinia, Nima; Mohammadpour, Raheleh Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09079-z	journal	April 2019
Impact of Capacitive Effect and Ion Migration on the Hysteretic Behavior of Perovskite Solar Cells Chen, Bo; Yang, Mengjin; Zheng, Xiaojia The Journal of Physical Chemistry Letters, Vol. 6, Issue 23 https://doi.org/10.1021/acs.jpclett.5b02229	journal	November 2015
Defect-induced melting and solid-state amorphization Fecht, H. J. Nature, Vol. 356, Issue 6365 https://doi.org/10.1038/356133a0	journal	March 1992
Amorphization Driven by Defect-Induced Mechanical Instability Jiang, Chao; Zheng, Ming-Jie; Morgan, Dane Physical Review Letters, Vol. 111, Issue 15 https://doi.org/10.1103/PhysRevLett.111.155501	journal	October 2013
Atomic-scale microstructure of metal halide perovskite Rothmann, Mathias Uller; Kim, Judy S.; Borchert, Juliane Science, Vol. 370, Issue 6516 https://doi.org/10.1126/science.abb5940	journal	October 2020

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