MOF-Derived Bimetallic Pd–Co Alkaline ORR Electrocatalysts

Xu, Weixuan; Yoon, Dasol; Yang, Yao; Xiong, Yin; Li, Huiqi; Zeng, Rui; Muller, David A.; Abruña, Héctor D.

doi:10.1021/acsami.2c10074

MOF-Derived Bimetallic Pd–Co Alkaline ORR Electrocatalysts

Journal Article · 26 September 2022 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.2c10074· OSTI ID:1978281

Xu, Weixuan ^[1]; ^[2]; ^[1]; ^[1]; Li, Huiqi ^[1]; ^[1]; ^[3]; ^[1]

Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States
Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, United States
School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States

Not provided.

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019445

OSTI ID:: 1978281

Journal Information:: ACS Applied Materials and Interfaces, Vol. 14, Issue 39; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (51)

Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Just a Dream—or Future Reality? Gasteiger, Hubert A.; Marković, Nenad M Science, Vol. 324, Issue 5923, p. 48-49 https://doi.org/10.1126/science.1172083	journal	April 2009
Revealing the atomic ordering of binary intermetallics using in situ heating techniques at multilength scales Xiong, Yin; Yang, Yao; Joress, Howie Proceedings of the National Academy of Sciences, Vol. 116, Issue 6 https://doi.org/10.1073/pnas.1815643116	journal	January 2019
High-Loading Intermetallic Pt ₃ Co/C Core–Shell Nanoparticles as Enhanced Activity Electrocatalysts toward the Oxygen Reduction Reaction (ORR) Xiong, Yin; Xiao, Li; Yang, Yao Chemistry of Materials, Vol. 30, Issue 5 https://doi.org/10.1021/acs.chemmater.7b04201	journal	February 2018
Energy and fuels from electrochemical interfaces Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4738	journal	December 2016
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts Wang, Deli; Xin, Huolin L.; Hovden, Robert Nature Materials, Vol. 12, Issue 1, p. 81-87 https://doi.org/10.1038/nmat3458	journal	October 2012
Carbon-Supported Pt-Based Alloy Electrocatalysts for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells: Particle Size, Shape, and Composition Manipulation and Their Impact to Activity Wang, Yan-Jie; Zhao, Nana; Fang, Baizeng Chemical Reviews, Vol. 115, Issue 9 https://doi.org/10.1021/cr500519c	journal	April 2015
Synergistic Mn-Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells Wang, Ying; Yang, Yao; Jia, Shuangfeng Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09503-4	journal	April 2019
Alkaline polymer electrolyte fuel cells completely free from noble metal catalysts Lu, S.; Pan, J.; Huang, A. Proceedings of the National Academy of Sciences, Vol. 105, Issue 52, p. 20611-20614 https://doi.org/10.1073/pnas.0810041106	journal	December 2008
Operando Methods in Electrocatalysis Yang, Yao; Xiong, Yin; Zeng, Rui ACS Catalysis, Vol. 11, Issue 3 https://doi.org/10.1021/acscatal.0c04789	journal	January 2021
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts Ge, Xiaoming; Sumboja, Afriyanti; Wuu, Delvin ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00524	journal	July 2015
Tuning the electronic structure of Ag-Pd alloys to enhance performance for alkaline oxygen reduction Zamora Zeledón, José A.; Stevens, Michaela Burke; Gunasooriya, G. T. Kasun Kalhara Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-20923-z	journal	January 2021
Enhancing the Electrocatalytic Activity of Pd/M (M = Ni, Mn) Nanoparticles for the Oxygen Reduction Reaction in Alkaline Media through Electrochemical Dealloying Lu, Xinyao; Ahmadi, Mahdi; DiSalvo, Francis J. ACS Catalysis, Vol. 10, Issue 10 https://doi.org/10.1021/acscatal.9b05499	journal	April 2020
Combinatorial Studies of Palladium-Based Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells Yang, Yao; Chen, Guanyu; Zeng, Rui Journal of the American Chemical Society, Vol. 142, Issue 8 https://doi.org/10.1021/jacs.9b13400	journal	February 2020
Spinels: Controlled Preparation, Oxygen Reduction/Evolution Reaction Application, and Beyond Zhao, Qing; Yan, Zhenhua; Chen, Chengcheng Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00051	journal	July 2017
Octahedral spinel electrocatalysts for alkaline fuel cells Yang, Yao; Xiong, Yin; Holtz, Megan E. Proceedings of the National Academy of Sciences, Vol. 116, Issue 49 https://doi.org/10.1073/pnas.1906570116	journal	November 2019
Epitaxial Thin-Film Spinel Oxides as Oxygen Reduction Electrocatalysts in Alkaline Media Yang, Yao; Zeng, Rui; Paik, Hanjong Chemistry of Materials, Vol. 33, Issue 11 https://doi.org/10.1021/acs.chemmater.1c00388	journal	May 2021
Nitrogen-Rich Manganese Oxynitrides with Enhanced Catalytic Activity in the Oxygen Reduction Reaction Miura, Akira; Rosero-Navarro, Carolina; Masubuchi, Yuji Angewandte Chemie, Vol. 128, Issue 28 https://doi.org/10.1002/ange.201601568	journal	May 2016
Zirconium nitride catalysts surpass platinum for oxygen reduction Yuan, Yao; Wang, Jiacheng; Adimi, Samira Nature Materials, Vol. 19, Issue 3 https://doi.org/10.1038/s41563-019-0535-9	journal	November 2019
Copper Nitride Nanocubes: Size-Controlled Synthesis and Application as Cathode Catalyst in Alkaline Fuel Cells Wu, Haibin; Chen, Wei Journal of the American Chemical Society, Vol. 133, Issue 39 https://doi.org/10.1021/ja204748u	journal	October 2011
Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts Yang, Yao; Zeng, Rui; Xiong, Yin Journal of the American Chemical Society, Vol. 141, Issue 49 https://doi.org/10.1021/jacs.9b10809	journal	November 2019
In Situ Activation of a Manganese Perovskite Oxygen Reduction Catalyst in Concentrated Alkaline Media Aoki, Yoshitaka; Takase, Kentaro; Kiuchi, Hisao Journal of the American Chemical Society, Vol. 143, Issue 17 https://doi.org/10.1021/jacs.1c00449	journal	April 2021
Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity Yang, Gege; Zhu, Jiawei; Yuan, Pengfei Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21919-5	journal	March 2021
Noble-Metal-Free Fe–N/C Catalyst for Highly Efficient Oxygen Reduction Reaction under Both Alkaline and Acidic Conditions Lin, Ling; Zhu, Qing; Xu, An-Wu Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja504696r	journal	July 2014
High-performing commercial Fe–N–C cathode electrocatalyst for anion-exchange membrane fuel cells Adabi, Horie; Shakouri, Abolfazl; Ul Hassan, Noor Nature Energy, Vol. 6, Issue 8 https://doi.org/10.1038/s41560-021-00878-7	journal	August 2021
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Recent Progress in MOF-Derived, Heteroatom-Doped Porous Carbons as Highly Efficient Electrocatalysts for Oxygen Reduction Reaction in Fuel Cells Yang, Liu; Zeng, Xiaofei; Wang, Wenchuan Advanced Functional Materials, Vol. 28, Issue 7 https://doi.org/10.1002/adfm.201704537	journal	December 2017
MOF derived catalysts for electrochemical oxygen reduction Wang, Xiaojuan; Zhou, Junwen; Fu, He J. Mater. Chem. A, Vol. 2, Issue 34 https://doi.org/10.1039/C4TA01506A	journal	January 2014
Bimetallic Zeolitic Imidazolite Framework Derived Carbon Nanotubes Embedded with Co Nanoparticles for Efficient Bifunctional Oxygen Electrocatalyst Li, Yinle; Jia, Baoming; Fan, Yanzhong Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201702048	journal	December 2017
A new family of carbon materials: synthesis of MOF-derived nanoporous carbons and their promising applications Chaikittisilp, Watcharop; Ariga, Katsuhiko; Yamauchi, Yusuke J. Mater. Chem. A, Vol. 1, Issue 1 https://doi.org/10.1039/C2TA00278G	journal	January 2013
Metal–Organic-Framework-Derived Co–Fe Bimetallic Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells Xiong, Yin; Yang, Yao; DiSalvo, Francis J. Journal of the American Chemical Society, Vol. 141, Issue 27 https://doi.org/10.1021/jacs.9b03561	journal	June 2019
Can Boron and Nitrogen Co-doping Improve Oxygen Reduction Reaction Activity of Carbon Nanotubes? Zhao, Yu; Yang, Lijun; Chen, Sheng Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja310566z	journal	January 2013
A metal–organic framework-derived bifunctional oxygen electrocatalyst Xia, Bao Yu; Yan, Ya; Li, Nan Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.6	journal	January 2016
MOF-Derived Isolated Fe Atoms Implanted in N-Doped 3D Hierarchical Carbon as an Efficient ORR Electrocatalyst in Both Alkaline and Acidic Media Chen, Xiaodong; Wang, Ning; Shen, Kui ACS Applied Materials & Interfaces, Vol. 11, Issue 29 https://doi.org/10.1021/acsami.9b07436	journal	June 2019
Synergistic Bimetallic Metallic Organic Framework-Derived Pt–Co Oxygen Reduction Electrocatalysts Xiong, Yin; Yang, Yao; DiSalvo, Francis J. ACS Nano, Vol. 14, Issue 10 https://doi.org/10.1021/acsnano.0c04559	journal	September 2020
Simulation of annular dark field stem images using a modified multislice method Kirkland, Earl J.; Loane, Russell F.; Silcox, John Ultramicroscopy, Vol. 23, Issue 1, p. 77-96 https://doi.org/10.1016/0304-3991(87)90229-4	journal	January 1987
The quantitative analysis of thin specimens Cliff, G.; Lorimer, G. W. Journal of Microscopy, Vol. 103, Issue 2 https://doi.org/10.1111/j.1365-2818.1975.tb03895.x	journal	March 1975
Electrocatalytic Cobalt Nanoparticles Interacting with Nitrogen-Doped Carbon Nanotube in Situ Generated from a Metal–Organic Framework for the Oxygen Reduction Reaction Zhong, Haihong; Luo, Yun; He, Shi ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b14942	journal	January 2017
Novel MOF-Derived Co@N-C Bifunctional Catalysts for Highly Efficient Zn-Air Batteries and Water Splitting Zhang, Mingdao; Dai, Quanbin; Zheng, Hegen Advanced Materials, Vol. 30, Issue 10 https://doi.org/10.1002/adma.201705431	journal	January 2018
Cobalt-Embedded N-Doped Carbon Nanostructures for Oxygen Reduction and Supercapacitor Applications Devi, Bandhana; Jain, Anuj; Roy, Biswajit ACS Applied Nano Materials, Vol. 3, Issue 7 https://doi.org/10.1021/acsanm.0c00732	journal	June 2020
High-Loading Composition-Tolerant Co–Mn Spinel Oxides with Performance beyond 1 W/cm ² in Alkaline Polymer Electrolyte Fuel Cells Yang, Yao; Peng, Hanqing; Xiong, Yin ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b00597	journal	May 2019
Alkaline polymer electrolyte fuel cells without anode humidification and H2 emission Hu, Meixue; Li, Qihao; Peng, Hanqing Journal of Power Sources, Vol. 472 https://doi.org/10.1016/j.jpowsour.2020.228471	journal	October 2020
Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs Omasta, Travis J.; Park, Andrew M.; LaManna, Jacob M. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C8EE00122G	journal	January 2018
Visualization and quantification of cathode channel flooding in PEM fuel cells Hussaini, Irfan S.; Wang, Chao-Yang Journal of Power Sources, Vol. 187, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.11.030	journal	February 2009
Influence of the Discretization Methods on the Distribution of Relaxation Times Deconvolution: Implementing Radial Basis Functions with DRTtools Wan, Ting Hei; Saccoccio, Mattia; Chen, Chi Electrochimica Acta, Vol. 184 https://doi.org/10.1016/j.electacta.2015.09.097	journal	December 2015
Distribution of Relaxation Times Analysis of High-Temperature PEM Fuel Cell Impedance Spectra Weiß, Alexandra; Schindler, Stefan; Galbiati, Samuele Electrochimica Acta, Vol. 230 https://doi.org/10.1016/j.electacta.2017.02.011	journal	March 2017
Membrane/Electrode Interface Design for Effective Water Management in Alkaline Membrane Fuel Cells Jang, Segeun; Her, Min; Kim, Sungjun ACS Applied Materials & Interfaces, Vol. 11, Issue 38 https://doi.org/10.1021/acsami.9b08075	journal	June 2019
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies Yang, Yao; Peltier, Cheyenne R.; Zeng, Rui Chemical Reviews, Vol. 122, Issue 6 https://doi.org/10.1021/acs.chemrev.1c00331	journal	February 2022

Similar Records

Metal–Organic-Framework-Derived Co–Fe Bimetallic Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells

Journal Article · 2019 · Journal of the American Chemical Society · OSTI ID:1613237

Xiong, Yin; Yang, Yao; DiSalvo, Francis J.; +1 more

Atomically Dispersed Zn/Co–N–C as ORR Electrocatalysts for Alkaline Fuel Cells

Journal Article · 2024 · Journal of the American Chemical Society · OSTI ID:2342096

Xu, Weixuan; Zeng, Rui; Rebarchik, Michael; +5 more

Synergistic Bimetallic Metallic Organic Framework-Derived Pt–Co Oxygen Reduction Electrocatalysts

Journal Article · 2020 · ACS Nano · OSTI ID:1853281

Xiong, Yin; Yang, Yao; DiSalvo, Francis J.; +1 more

Related Subjects

Science & Technology - Other Topics
Materials Science

MOF-Derived Bimetallic Pd–Co Alkaline ORR Electrocatalysts

Citation Formats

References (51)

Similar Records

Related Subjects