Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Broad Applicability of Electrochemical Impedance Spectroscopy to the Measurement of Oxygen Nonstoichiometry in Mixed Ion and Electron Conductors

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [1];  [2];  [3]
  1. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States
  2. Department of Materials Science, California Institute of Technology, Pasadena, California 91125, United States
  3. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States; Department of Applied Physics, Northwestern University, Evanston, Illinois 60208, United States; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States

Not provided.

Research Organization:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0008089
OSTI ID:
1978272
Journal Information:
ACS Applied Materials and Interfaces, Vol. 14, Issue 17; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (41)

Fuel cell materials and components☆☆☆The Golden Jubilee Issue—Selected topics in Materials Science and Engineering: Past, Present and Future, edited by S. Suresh. journal November 2003
Materials for Solid Oxide Fuel Cells journal February 2010
Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes journal October 2004
Catalytic Properties of Ceria and CeO 2 -Containing Materials journal November 1996
High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria journal December 2010
Investigation of reactive cerium-based oxides for H2 production by thermochemical two-step water-splitting journal April 2010
Thermodynamic Analysis of Cerium-Based Oxides for Solar Thermochemical Fuel Production journal February 2012
Perovskite oxides – a review on a versatile material class for solar-to-fuel conversion processes journal January 2017
The favourable thermodynamic properties of Fe-doped CaMnO 3 for thermochemical heat storage journal January 2020
A thermodynamic study of nonstoichiometric cerium dioxide journal November 1975
Ion–electron transport in strontium ferrites: relationships with structural features and stability journal September 2004
Impedance Spectroscopy as a Tool for Chemical and Electrochemical Analysis of Mixed Conductors: A Case Study of Ceria journal November 2005
Chemical resistance and chemical capacitance journal December 2019
Generalised equivalent circuits for mass and charge transport: chemical capacitance and its implications journal January 2001
Determination of Oxygen Vacancy Concentration in a Thin Film of La[sub 0.6]Sr[sub 0.4]CoO[sub 3−δ] by an Electrochemical Method journal January 2002
Electrochemical studies of capacitance in cerium oxide thin films and its relationship to anionic and electronic defect densities journal January 2009
Nonstoichiometry in Oxide Thin Films Operating under Anodic Conditions: A Chemical Capacitance Study of the Praseodymium–Cerium Oxide System journal November 2014
Impedance studies of dense polycrystalline thin films of La2NiO4+? journal January 2007
A review of defect structure and chemistry in ceria and its solid solutions journal January 2020
Electrical properties of the ZrO2-CeO2 system journal October 1996
Defect equilibria and chemical expansion in non-stoichiometric undoped and gadolinium-doped cerium oxide journal February 2009
Ceria–Zirconia Solid Solutions (Ce 1– x Zr x O 2−δ , x ≤ 0.2) for Solar Thermochemical Water Splitting: A Thermodynamic Study journal October 2014
Defect and Transport Model of Ceria–Zirconia Solid Solutions: Ce0.8Zr0.2O2−δ—An Electrical Conductivity Study journal August 2014
Electrical conductivity and point defect behavior in ceria-stabilized zirconia journal July 1993
Probing the reaction pathway in (La 0.8 Sr 0.2 ) 0.95 MnO 3+δ using libraries of thin film microelectrodes journal January 2015
Non-stoichiometry in Oxide Thin Films: A Chemical Capacitance Study of the Praseodymium-Cerium Oxide System journal November 2012
The geometry dependence of the polarization resistance of Sr-doped LaMnO3 microelectrodes on yttria-stabilized zirconia journal December 2002
Nanograin Composite Model Studies of Nanocrystalline Gadolinia-Doped Ceria: Nanograin Composite Model Studies journal November 2010
Synergy between gold and oxygen vacancies in gold supported on Zr-doped ceria catalysts for the CO oxidation journal October 2015
Electrical conductivity of single crystal and polycrystalline yttria-stabilized zirconia journal June 1984
Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials journal January 2020
Highly Enhanced Concentration and Stability of Reactive Ce 3+ on Doped CeO 2 Surface Revealed In Operando journal May 2012
Origin and Tunability of Unusually Large Surface Capacitance in Doped Cerium Oxide Studied by Ambient-Pressure X-Ray Photoelectron Spectroscopy journal March 2016
The role of point defects in the physical properties of nonstoichiometric ceria journal February 2007
Nonstoichiometry of Ce0.9Gd0.1O1.95−x journal March 1998
Oxygen nonstoichiometry and thermodynamic characterization of Zr doped ceria in the 1573–1773 K temperature range journal January 2015
Simple method to determine electronic and ionic components of the conductivity in mixed conductors a review journal May 2002
Measurements of electronic and ionic partial conductivities in mixed conductors, without the use of blocking electrodes journal February 1991
Structural characterization and oxygen nonstoichiometry of ceria-zirconia (Ce1−xZrxO2−δ) solid solutions journal June 2013
Electrical and oxygen storage/release properties of nanocrystalline ceria–zirconia solid solutions journal March 2002
Voltage-Controlled Nonstoichiometry in Oxide Thin Films: Pr 0.1 Ce 0.9 O 2−δ Case Study journal October 2014