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Thermodynamic Analysis of LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) Voltage Hysteresis Induced through High Voltage Charge

Journal Article · · ACS Applied Energy Materials
 [1];  [2];  [2];  [2];  [3];  [3];  [3]
  1. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794, United States; Institute for Electrochemically Stored Energy, Stony Brook University, Stony Brook, New York 11794, United States
  2. Institute for Electrochemically Stored Energy, Stony Brook University, Stony Brook, New York 11794, United States; Interdisciplinary Science Department, Brookhaven National Laboratory, Upton, New York 11973, United States
  3. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794, United States; Institute for Electrochemically Stored Energy, Stony Brook University, Stony Brook, New York 11794, United States; Interdisciplinary Science Department, Brookhaven National Laboratory, Upton, New York 11973, United States; Department of Materials Science and Chemical Engineering, State University of New York at Stony Brook, Stony Brook, New York 11794, United States
+ Show Author Affiliations

Not provided.

Research Organization:
State Univ. of New York (SUNY), Albany, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012673
OSTI ID:
1978222
Journal Information:
ACS Applied Energy Materials, Vol. 4, Issue 11; ISSN 2574-0962
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (29)

Nickel-rich Nickel Manganese Cobalt (NMC622) Cathode Lithiation Mechanism and Extended Cycling Effects Using Operando X-ray Absorption Spectroscopy journal December 2020
Improved Capacity Retention of Lithium Ion Batteries under Fast Charge via Metal-Coated Graphite Electrodes journal November 2020
Capacity Fading Mechanisms in Ni-Rich Single-Crystal NCM Cathodes journal July 2021
What Limits the Capacity of Layered Oxide Cathodes in Lithium Batteries? journal July 2019
Depth-Dependent Redox Behavior of LiNi 0.6 Mn 0.2 Co 0.2 O 2 journal January 2018
Phosphorus Enrichment as a New Composition in the Solid Electrolyte Interphase of High-Voltage Cathodes and Its Effects on Battery Cycling journal October 2015
Probing Sources of Capacity Fade in LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622): An Operando XRD Study of Li/NMC622 Batteries during Extended Cycling journal March 2020
Oxygen Release and Its Effect on the Cycling Stability of LiNi x Mn y Co z O 2 (NMC) Cathode Materials for Li-Ion Batteries journal January 2017
High‐Voltage Charging‐Induced Strain, Heterogeneity, and Micro‐Cracks in Secondary Particles of a Nickel‐Rich Layered Cathode Material journal March 2019
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode journal June 2018
Insights into Reactivity of Silicon Negative Electrodes: Analysis Using Isothermal Microcalorimetry journal September 2019
Lithiation of Magnetite (Fe 3 O 4 ): Analysis Using Isothermal Microcalorimetry and Operando X-ray Absorption Spectroscopy journal April 2018
Peering into Batteries: Electrochemical Insight Through In Situ and Operando Methods over Multiple Length Scales journal January 2021
Heat Generation in NMC622 Coin Cells during Electrochemical Cycling: Separation of Reversible and Irreversible Heat Effects journal November 2020
Determination of the Voltage Dependence of Parasitic Heat Flow in Lithium Ion Cells Using Isothermal Microcalorimetry journal January 2014
The Impact of Electrolyte Composition on Parasitic Reactions in Lithium Ion Cells Charged to 4.7 V Determined Using Isothermal Microcalorimetry journal November 2015
The Effect of Different Li(Ni 1-x-y Mn x Co y )O 2 Positive Electrode Materials and Coatings on Parasitic Heat Flow as Measured by Isothermal Microcalorimetry, Ultra-High Precision Coulometry and Long Term Cycling journal January 2017
Probing the thermal effects of voltage hysteresis in anionic redox-based lithium-rich cathodes using isothermal calorimetry journal July 2019
Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 ● (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content journal December 2013
First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk journal September 2020
On stress-induced voltage hysteresis in lithium ion batteries: impacts of material property, charge rate and particle size journal July 2016
Decoupling the Voltage Hysteresis of Li‐Rich Cathodes: Electrochemical Monitoring, Modulation Anionic Redox Chemistry and Theoretical Verifying journal September 2020
Operando decoding of chemical and thermal events in commercial Na(Li)-ion cells via optical sensors journal August 2020
Isothermal Calorimetry Evaluation of Metallurgical Silicon as a Negative Electrode Material for Li-Ion Batteries journal March 2021
Heats of mixing and of entropy in porous insertion electrodes journal June 2003
Probing Depth-Dependent Transition-Metal Redox of Lithium Nickel, Manganese, and Cobalt Oxides in Li-Ion Batteries journal December 2020
The Effect of Entropy and Enthalpy Changes on the Thermal Behavior of Li-Mn-Rich Layered Composite Cathode Materials journal January 2016
Open-Circuit Voltage Comes from Non-Equilibrium Thermodynamics journal October 2020
Multiscale Understanding and Architecture Design of High Energy/Power Lithium‐Ion Battery Electrodes journal May 2020

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