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Oxidation of Methylplatinum(II) Complexes K[(L)Pt II Me] with O 2 and C(sp 3 )-X (X = O and C) Reductive Elimination Reactivity of Methylplatinum(IV) Products ( L )Pt IV Me(OH): The Effect of Structure of Sulfonated CNN-Pincer Ligands L

Journal Article · · Organometallics
 [1];  [1];  [1];  [1];  [1]
  1. Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Univ. of Virginia, Charlottesville, VA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001298
OSTI ID:
1978213
Journal Information:
Organometallics, Vol. 41, Issue 19; ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (34)

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CH3–X Reductive Elimination Reactivity of PtIVMe Complexes Supported by a Sulfonated CNN Pincer Ligand (X = OH, CF3CO2, PhNMe2+) journal December 2019
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Mechanism and stereochemistry for nucleophilic attack at carbon of platinum(IV) alkyls: model reactions for hydrocarbon oxidation with aqueous platinum chlorides journal April 1993
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Mechanistic Study of the Oxidation of a Methyl Platinum(II) Complex with O 2 in Water: Pt II Me-to-Pt IV Me and Pt II Me-to-Pt IV Me 2 Reactivity journal March 2014
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Does α-Fluorination Affect the Structural trans-Influence and Kinetic trans-Effect of an Alkyl Ligand? Molecular Structures of Pd(TMEDA)(CH3)(RF) and a Kinetic Study of the trans to cis Isomerization of Pt(TMEDA)(CH3)2I(RF) [RF = CF2CF3, CFHCF3, CH2CF3] journal December 2003
Mechanism of O 2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)Pt II Me(OH n ) (2– n )– Complex from Theory with Validation from Experiment journal January 2014
Ligand dissociation as a preliminary step in methyl-for-halogen exchange reactions of platinum(II) complexes journal November 1983

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