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Insertion Reactions of NH3 and H2O with the Ferriogermylenes ArGeFeCp(CO)2 (Ar = ArMe6 (-C6H3-(C6H2-2,4,6-Me3)2) or AriPr4 (-C6H3-(C6H3-2,6-iPr2)2); Cp = η5-C5H5): Structural Isomerism and Polymorphism in a Metallogermylene

Journal Article · · Organometallics
 [1];  [1];  [1]
  1. Department of Chemistry, University of California, Davis, 1 Shields Avenue, Davis, California 95616, United States
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Not provided.

Research Organization:
Univ. of California, Davis, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-07ER46475
OSTI ID:
1978205
Journal Information:
Organometallics, Vol. 40, Issue 20; ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

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Synthesis and Characterization of 2,6-Dipp 2 -H 3 C 6 SnSnC 6 H 3 -2,6-Dipp 2 (Dipp = C 6 H 3 -2,6-Pr i 2 ):  A Tin Analogue of an Alkyne May 2002
Synthesis and Characterization of the Metalloplumbylenes (η 5 -C 5 H 5 )(CO) 3 M-P̈b-C 6 H 3 -2,6-Trip 2 (M = Cr, Mo, or W; Trip = −C 6 H 2 -2,4,6-i-Pr 3 ) December 1999
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Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis January 2021
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Reversible Binding of Ethylene and Propylene by Germylenes March 2019
Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination November 2009
Main-group elements as transition metals January 2010
Unprecedented insertion reaction of a silylene into a B–B bond and generation of a novel borylsilyl anion by boron–metal exchange reaction of the resultant diborylsilane January 2004
Synthesis and Characterization of the Monomeric Diaryls M{C 6 H 3 -2,6-Mes 2 } 2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me 3 C 6 H 2 −) and Dimeric Aryl−Metal Chlorides [M(Cl){C 6 H 3 -2,6-Mes 2 }] 2 (M = Ge or Sn) April 1997
Reversible Complexation of Alkynes by a Germylene March 2019
Addition of H2 to distannynes under ambient conditions January 2008
Synthesis, Characterization, and CO Elimination of Ferrio-Substituted Two-Coordinate Germylenes and Stannylenes November 2011
Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N -Heterocyclic Carbene-Stabilized Chlorometallogermylenes October 2014
Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me 3 P) 2 (Ph 3 P)Rh≡E‐Ar*] (E=Sn, Pb) February 2021
Mechanisms of Reactions of Open-Shell, Heavier Group 14 Derivatives with Small Molecules: n−π* Back-Bonding in Isocyanide Complexes, C–H Activation under Ambient Conditions, CO Coupling, and Ancillary Molecular Interactions†This Award Article summarizes, including more recent results, one of the themes of a lecture presented on March 26th, 2012, at the 243rd Chemical Society National Meeting American in San Diego, CA, in receipt of the 2012 Award in Organometallic Chemistry sponsored by the Dow Corporation. May 2013
A Silylyne Tungsten Complex Having an Eind Group on Silicon: Its Dimer–Monomer Equilibrium and Cycloaddition Reactions with Carbodiimide and Diaryl Ketones September 2016
Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions September 2009
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Synthesis of a Base-stabilized (Chlorogermyl)metallogermylene and Its Photochemical Conversion to a (Chlorogermyl)germylyne Complex January 2013
Synthesis and Structural Characterization of Metallogermylenes, Cp-Substituted Germylene, and a Germanium(II)-Borane Adduct from Pyridyl-1-azaallyl Germanium(II) Chloride September 2012
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Synthesis and Structure of the Germylyne Complexestrans-[X(dppe)2W≡Ge(η1-Cp*)] (X=Cl, Br, I) and Comparison of the W≡E Bonds (E=C, Ge) by Density Functional Calculations August 2000
Triple Bonding to Tin: Synthesis and Characterization of the Stannylyne Complex trans-[Cl(PMe3)4WSnC6H3-2,6-Mes2] January 2003
Reactivity of Ar‘GeGeAr‘ (Ar‘ = C 6 H 3 -2,6-Dipp 2 , Dipp = C 6 H 3 -2,6- i Pr 2 ) toward Alkynes:  Isolation of a Stable Digermacyclobutadiene April 2004
Activation of Small Molecules by Compounds that Contain Triple Bonds Between Heavier Group-14 Elements November 2018
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Coordination Chemistry of [E(Idipp)] 2+ Ligands (E = Ge, Sn): Metal Germylidyne [Cp*(CO) 2 W≡Ge(Idipp)] + and Metallotetrylene [Cp*(CO) 3 W–E(Idipp)] + Cations April 2017

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