Structure–Property Relationships for Polyether-Based Electrolytes in the High-Dielectric-Constant Regime

Pedretti, Benjamin J.; Czarnecki, Natalie J.; Zhu, Congzhi; Imbrogno, Jennifer; Rivers, Frederick; Freeman, Benny D.; Ganesan, Venkat; Lynd, Nathaniel A.

doi:10.1021/acs.macromol.2c00639

Structure–Property Relationships for Polyether-Based Electrolytes in the High-Dielectric-Constant Regime

Journal Article · 27 July 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.2c00639· OSTI ID:1978159

Pedretti, Benjamin J. ^[1]; Czarnecki, Natalie J. ^[1]; ^[1]; Imbrogno, Jennifer ^[1]; Rivers, Frederick ^[1]; ^[1]; ^[1]; ^[2]

McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States; Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, United States

Not provided.

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019272

OSTI ID:: 1978159

Journal Information:: Macromolecules, Vol. 55, Issue 15; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (53)

Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Dielectric Constants for Quantum Chemistry and Li-Ion Batteries: Solvent Blends of Ethylene Carbonate and Ethyl Methyl Carbonate Hall, David S.; Self, Julian; Dahn, J. R. The Journal of Physical Chemistry C, Vol. 119, Issue 39 https://doi.org/10.1021/acs.jpcc.5b06022	journal	September 2015
Nonaqueous Electrolytes with Advances in Solvents Ue, Makoto; Sasaki, Yukio; Tanaka, Yasutaka Modern Aspects of Electrochemistry https://doi.org/10.1007/978-1-4939-0302-3_2	book	January 2014
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Influence of Dielectric Constant on Ionic Transport in Polyether-Based Electrolytes Wheatle, Bill K.; Keith, Jordan R.; Mogurampelly, Santosh ACS Macro Letters, Vol. 6, Issue 12 https://doi.org/10.1021/acsmacrolett.7b00810	journal	November 2017
Effect of Polymer Polarity on Ion Transport: A Competition between Ion Aggregation and Polymer Segmental Dynamics Wheatle, Bill K.; Lynd, Nathaniel A.; Ganesan, Venkat ACS Macro Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acsmacrolett.8b00594	journal	September 2018
Influence of Host Polarity on Correlating Salt Concentration, Molecular Weight, and Molar Conductivity in Polymer Electrolytes Wheatle, Bill K.; Fuentes, Erick F.; Lynd, Nathaniel A. ACS Macro Letters, Vol. 8, Issue 8 https://doi.org/10.1021/acsmacrolett.9b00317	journal	July 2019
Effect of Host Incompatibility and Polarity Contrast on Ion Transport in Ternary Polymer-Polymer-Salt Blend Electrolytes Wheatle, Bill K.; Lynd, Nathaniel A.; Ganesan, Venkat Macromolecules, Vol. 53, Issue 3 https://doi.org/10.1021/acs.macromol.9b02510	journal	January 2020
Complexes of alkali metal ions with poly(ethylene oxide) Fenton, D. E.; Parker, J. M.; Wright, P. V. Polymer, Vol. 14, Issue 11 https://doi.org/10.1016/0032-3861(73)90146-8	journal	November 1973
Electrical conductivity in ionic complexes of poly(ethylene oxide) Wright, Peter V. British Polymer Journal, Vol. 7, Issue 5 https://doi.org/10.1002/pi.4980070505	journal	September 1975
Polymer Electrolytes: The Key to Lithium Polymer Batteries Scrosati, B.; Vincent, C. A. MRS Bulletin, Vol. 25, Issue 3 https://doi.org/10.1557/mrs2000.15	journal	March 2000
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries Xue, Zhigang; He, Dan; Xie, Xiaolin Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA03471J	journal	January 2015
Allyl Glycidyl Ether-Based Polymer Electrolytes for Room Temperature Lithium Batteries Barteau, Katherine P.; Wolffs, Martin; Lynd, Nathaniel A. Macromolecules, Vol. 46, Issue 22 https://doi.org/10.1021/ma401267w	journal	November 2013
Beyond PEO—Alternative host materials for Li + -conducting solid polymer electrolytes Mindemark, Jonas; Lacey, Matthew J.; Bowden, Tim Progress in Polymer Science, Vol. 81 https://doi.org/10.1016/j.progpolymsci.2017.12.004	journal	June 2018
Effect of molecular weight on conductivity of polymer electrolytes Teran, Alexander A.; Tang, Maureen H.; Mullin, Scott A. Solid State Ionics, Vol. 203, Issue 1 https://doi.org/10.1016/j.ssi.2011.09.021	journal	November 2011
Rubbery Graft Copolymer Electrolytes for Solid-State, Thin-Film Lithium Batteries Trapa, Patrick E.; Won, You-Yeon; Mui, Simon C. Journal of The Electrochemical Society, Vol. 152, Issue 1 https://doi.org/10.1149/1.1824032	journal	January 2005
Polarization in Cells Containing Single-Ion Graft Copolymer Electrolytes Trapa, Patrick E.; Reyes, Allan B.; Das Gupta, Raj Shekar Journal of The Electrochemical Society, Vol. 153, Issue 6 https://doi.org/10.1149/1.2191188	journal	January 2006
Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes Singh, Mohit; Odusanya, Omolola; Wilmes, Gregg M. Macromolecules, Vol. 40, Issue 13 https://doi.org/10.1021/ma0629541	journal	June 2007
Effect of Molecular Weight and Salt Concentration on Conductivity of Block Copolymer Electrolytes Panday, Ashoutosh; Mullin, Scott; Gomez, Enrique D. Macromolecules, Vol. 42, Issue 13 https://doi.org/10.1021/ma900451e	journal	July 2009
Relationship between morphology and conductivity of block-copolymer based battery separators Wong, David T.; Mullin, Scott A.; Battaglia, Vincent S. Journal of Membrane Science, Vol. 394-395 https://doi.org/10.1016/j.memsci.2011.12.037	journal	March 2012
Block copolymer electrolytes for rechargeable lithium batteries Young, Wen-Shiue; Kuan, Wei-Fan; Epps, Thomas H. Journal of Polymer Science Part B: Polymer Physics, Vol. 52, Issue 1 https://doi.org/10.1002/polb.23404	journal	November 2013
Miscible Polyether/Poly(ether–acetal) Electrolyte Blends Gao, Kevin W.; Loo, Whitney S.; Snyder, Rachel L. Macromolecules, Vol. 53, Issue 14 https://doi.org/10.1021/acs.macromol.0c00747	journal	July 2020
Polymer electrolyte complexes of LiCIO4 and comb polymers of siloxane with oligo-oxyethylene side chains Fish, Daryle; Khan, Ishrat M.; Wu, E. British Polymer Journal, Vol. 20, Issue 3 https://doi.org/10.1002/pi.4980200320	journal	January 1988
Polymer electrolytes derived from dendritic polyether macromonomers Watanabe, M. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00079-6	journal	June 2002
Hyperbranched Poly(ethylene glycol)s: A New Class of Ion-Conducting Materials Hawker, Craig J.; Chu, Fengkui; Pomery, Peter J. Macromolecules, Vol. 29, Issue 11 https://doi.org/10.1021/ma951909i	journal	January 1996
High ionic conductivity of new polymer electrolytes based on high molecular weight polyether comb polymers Nishimoto, Atsushi; Watanabe, Masayoshi; Ikeda, Yuko Electrochimica Acta, Vol. 43, Issue 10-11 https://doi.org/10.1016/S0013-4686(97)10017-2	journal	April 1998
Structure–Conductivity Relationship for Peptoid-Based PEO–Mimetic Polymer Electrolytes Sun, Jing; Stone, Gregory M.; Balsara, Nitash P. Macromolecules, Vol. 45, Issue 12 https://doi.org/10.1021/ma300775b	journal	June 2012
Improved Li ⁺ Transport in Polyacetal Electrolytes: Conductivity and Current Fraction in a Series of Polymers Snyder, Rachel L.; Choo, Youngwoo; Gao, Kevin W. ACS Energy Letters, Vol. 6, Issue 5 https://doi.org/10.1021/acsenergylett.1c00594	journal	April 2021
Modifying Li ⁺ and Anion Diffusivities in Polyacetal Electrolytes: A Pulsed-Field-Gradient NMR Study of Ion Self-Diffusion Halat, David M.; Snyder, Rachel L.; Sundararaman, Siddharth Chemistry of Materials, Vol. 33, Issue 13 https://doi.org/10.1021/acs.chemmater.1c00339	journal	June 2021
Polymer electrolytes for lithium polymer batteries Long, Lizhen; Wang, Shuanjin; Xiao, Min Journal of Materials Chemistry A, Vol. 4, Issue 26 https://doi.org/10.1039/C6TA02621D	journal	January 2016
The history of polymer electrolytes Armand, M. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90419-7	journal	August 1994
Inhibition of Crystallization of Poly(ethylene oxide) by Ionic Liquid: Insight into Plasticizing Mechanism and Application for Solid-State Sodium Ion Batteries Chen, Guanghai; Bai, Ying; Gao, Yongsheng ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b16294	journal	October 2019
Lithium ion transport and ion–polymer interaction in PEO based polymer electrolyte plasticized with ionic liquid Kumar, Yogesh; Hashmi, S. A.; Pandey, G. P. Solid State Ionics, Vol. 201, Issue 1 https://doi.org/10.1016/j.ssi.2011.08.010	journal	October 2011
Enabling high performance all-solid-state lithium metal batteries using solid polymer electrolytes plasticized with ionic liquid Widstrom, Matthew D.; Ludwig, Kyle B.; Matthews, Jesse E. Electrochimica Acta, Vol. 345 https://doi.org/10.1016/j.electacta.2020.136156	journal	June 2020
Design of Polymeric Zwitterionic Solid Electrolytes with Superionic Lithium Transport Jones, Seamus D.; Nguyen, Howie; Richardson, Peter M. ACS Central Science, Vol. 8, Issue 2 https://doi.org/10.1021/acscentsci.1c01260	journal	January 2022
Ion Correlation Effects in Salt-Doped Block Copolymers Brown, Jonathan R.; Seo, Youngmi; Hall, Lisa M. Physical Review Letters, Vol. 120, Issue 12 https://doi.org/10.1103/PhysRevLett.120.127801	journal	March 2018
Role of Solvation on Diffusion of Ions in Diblock Copolymers: Understanding the Molecular Weight Effect through Modeling Seo, Youngmi; Shen, Kuan-Hsuan; Brown, Jonathan R. Journal of the American Chemical Society, Vol. 141, Issue 46 https://doi.org/10.1021/jacs.9b07227	journal	October 2019
Ion Conductivity and Correlations in Model Salt-Doped Polymers: Effects of Interaction Strength and Concentration Shen, Kuan-Hsuan; Hall, Lisa M. Macromolecules, Vol. 53, Issue 10 https://doi.org/10.1021/acs.macromol.0c00216	journal	May 2020
Ionic Transport in Polymer Electrolytes: The Essential Role of Associated Ionic Species Frech, Roger; York, Shawna; Allcock, Harry Macromolecules, Vol. 37, Issue 23 https://doi.org/10.1021/ma040067x	journal	October 2004
Importance of the Ion-Pair Lifetime in Polymer Electrolytes Gudla, Harish; Shao, Yunqi; Phunnarungsi, Supho The Journal of Physical Chemistry Letters, Vol. 12, Issue 35 https://doi.org/10.1021/acs.jpclett.1c02474	journal	August 2021
Salt Diffusion Coefficients in Block Copolymer Electrolytes Mullin, Scott A.; Stone, Gregory M.; Panday, Ashoutosh Journal of The Electrochemical Society, Vol. 158, Issue 6 https://doi.org/10.1149/1.3563802	journal	January 2011
Relationship between Conductivity, Ion Diffusion, and Transference Number in Perfluoropolyether Electrolytes Chintapalli, Mahati; Timachova, Ksenia; Olson, Kevin R. Macromolecules, Vol. 49, Issue 9 https://doi.org/10.1021/acs.macromol.6b00412	journal	April 2016
Diffusion and migration in polymer electrolytes Choo, Youngwoo; Halat, David M.; Villaluenga, Irune Progress in Polymer Science, Vol. 103 https://doi.org/10.1016/j.progpolymsci.2020.101220	journal	April 2020
Relationship between Segmental Dynamics Measured by Quasi-Elastic Neutron Scattering and Conductivity in Polymer Electrolytes Mongcopa, Katrina Irene S.; Tyagi, Madhusudan; Mailoa, Jonathan P. ACS Macro Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsmacrolett.8b00159	journal	March 2018
Temperature and concentration dependence of the ionic transport properties of poly(ethylene oxide) electrolytes Hoffman, Zach J.; Shah, Deep B.; Balsara, Nitash P. Solid State Ionics, Vol. 370 https://doi.org/10.1016/j.ssi.2021.115751	journal	November 2021
Relationship between Ionic Conductivity, Glass Transition Temperature, and Dielectric Constant in Poly(vinyl ether) Lithium Electrolytes Imbrogno, Jennifer; Maruyama, Kazuya; Rivers, Frederick ACS Macro Letters, Vol. 10, Issue 8 https://doi.org/10.1021/acsmacrolett.1c00305	journal	July 2021
A Titanium(III)-Catalyzed Reductive Umpolung Reaction for the Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines Luu, Hieu-Trinh; Wiesler, Stefan; Frey, Georg Organic Letters, Vol. 17, Issue 10 https://doi.org/10.1021/acs.orglett.5b00987	journal	April 2015
Ring-Opening Polymerization of Epoxides: Facile Pathway to Functional Polyethers via a Versatile Organoaluminum Initiator Rodriguez, Christina G.; Ferrier, Robert C.; Helenic, Alysha Macromolecules, Vol. 50, Issue 8 https://doi.org/10.1021/acs.macromol.7b00196	journal	April 2017
Acid-Triggered, Acid-Generating, and Self-Amplifying Degradable Polymers Miller, Kali A.; Morado, Ephraim G.; Samanta, Shampa R. Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b07705	journal	January 2019
Cyclic sulfates: useful substrates for selective nucleophilic substitution Berridge, Marc S.; Franceschini, Mark P.; Rosenfeld, Eric The Journal of Organic Chemistry, Vol. 55, Issue 4 https://doi.org/10.1021/jo00291a020	journal	February 1990
Computing the Kirkwood g -Factor by Combining Constant Maxwell Electric Field and Electric Displacement Simulations: Application to the Dielectric Constant of Liquid Water Zhang, Chao; Hutter, Jürg; Sprik, Michiel The Journal of Physical Chemistry Letters, Vol. 7, Issue 14 https://doi.org/10.1021/acs.jpclett.6b01127	journal	June 2016
The Dielectric Polarization of Polar Liquids Kirkwood, John G. The Journal of Chemical Physics, Vol. 7, Issue 10 https://doi.org/10.1063/1.1750343	journal	October 1939

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