Structural Relaxation and Vitrification in Dense Cross-Linked Polymer Networks: Simulation, Theory, and Experiment

Mei, Baicheng; Lin, Tsai-Wei; Sheridan, Grant S.; Evans, Christopher M.; Sing, Charles E.; Schweizer, Kenneth S.

doi:10.1021/acs.macromol.2c00277

Structural Relaxation and Vitrification in Dense Cross-Linked Polymer Networks: Simulation, Theory, and Experiment

Journal Article · 05 May 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.2c00277· OSTI ID:1978157

^[1]; Lin, Tsai-Wei ^[2]; Sheridan, Grant S. ^[1]; ^[3]; ^[3]; Schweizer, Kenneth S. ^[4]

Department of Materials Science, University of Illinois, Urbana, Illinois 61801, United States; Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States
Department of Chemical & Biomolecular Engineering, University of Illinois, Urbana, Illinois 61801, United States; Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States
Department of Materials Science, University of Illinois, Urbana, Illinois 61801, United States; Department of Chemical & Biomolecular Engineering, University of Illinois, Urbana, Illinois 61801, United States; Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States
Department of Materials Science, University of Illinois, Urbana, Illinois 61801, United States; Department of Chemistry, University of Illinois, Urbana, Illinois 61801, United States; Department of Chemical & Biomolecular Engineering, University of Illinois, Urbana, Illinois 61801, United States; Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States

Not provided.

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0020858

OSTI ID:: 1978157

Journal Information:: Macromolecules, Vol. 55, Issue 10; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (94)

Synthesis and light gas separations in cross-linked gemini room temperature ionic liquid polymer membranes Bara, Jason E.; Hatakeyama, Evan S.; Gabriel, Christopher J. Journal of Membrane Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.08.052	journal	May 2008
Crosslinked poly(ethylene oxide) fouling resistant coating materials for oil/water separation Ju, Hao; McCloskey, Bryan D.; Sagle, Alyson C. Journal of Membrane Science, Vol. 307, Issue 2 https://doi.org/10.1016/j.memsci.2007.09.028	journal	January 2008
Gas Separation Membrane Materials: A Perspective Baker, Richard W.; Low, Bee Ting Macromolecules, Vol. 47, Issue 20 https://doi.org/10.1021/ma501488s	journal	September 2014
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Diffusion and Mass Transfer Vrentas, James S.; Vrentas, Christine M. https://doi.org/10.1201/b12923	book	March 2013
50th Anniversary Perspective : Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities Galizia, Michele; Chi, Won Seok; Smith, Zachary P. Macromolecules, Vol. 50, Issue 20 https://doi.org/10.1021/acs.macromol.7b01718	journal	October 2017
Ultraselective glassy polymer membranes with unprecedented performance for energy-efficient sour gas separation Yi, Shouliang; Ghanem, Bader; Liu, Yang Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aaw5459	journal	May 2019
How the Shape and Chemistry of Molecular Penetrants Control Responsive Hydrogel Permeability Kanduč, Matej; Kim, Won Kyu; Roa, Rafael ACS Nano, Vol. 15, Issue 1 https://doi.org/10.1021/acsnano.0c06319	journal	December 2020
Statistical Mechanical Theory of Penetrant Diffusion in Polymer Melts and Glasses Zhang, Rui; Schweizer, Kenneth S. Macromolecules, Vol. 49, Issue 15 https://doi.org/10.1021/acs.macromol.6b00725	journal	July 2016
Correlated matrix-fluctuation-mediated activated transport of dilute penetrants in glass-forming liquids and suspensions Zhang, Rui; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 146, Issue 19 https://doi.org/10.1063/1.4983224	journal	May 2017
Activated penetrant dynamics in glass forming liquids: size effects, decoupling, slaving, collective elasticity and correlation with matrix compressibility Mei, Baicheng; Schweizer, Kenneth S. Soft Matter, Vol. 17, Issue 9 https://doi.org/10.1039/D0SM02215B	journal	January 2021
Theory of the effect of external stress on the activated dynamics and transport of dilute penetrants in supercooled liquids and glasses Mei, Baicheng; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 155, Issue 5 https://doi.org/10.1063/5.0056920	journal	August 2021
Dynamics of Nanoparticles in Polydisperse Polymer Networks: from Free Diffusion to Hopping Sorichetti, Valerio; Hugouvieux, Virginie; Kob, Walter Macromolecules, Vol. 54, Issue 18 https://doi.org/10.1021/acs.macromol.1c01394	journal	September 2021
Understanding the Roles of Mesh Size, T_g, and Segmental Dynamics on Probe Diffusion in Dense Polymer Networks Sheridan, Grant S.; Evans, Christopher M. Macromolecules, Vol. 54, Issue 23 https://doi.org/10.1021/acs.macromol.1c01767	journal	November 2021
Cooling rate dependence of the glass transition temperature of polymer melts: Molecular dynamics study Buchholz, Joachim; Paul, Wolfgang; Varnik, Fathollah The Journal of Chemical Physics, Vol. 117, Issue 15 https://doi.org/10.1063/1.1508366	journal	October 2002
Tuning polymer melt fragility with antiplasticizer additives Riggleman, Robert A.; Douglas, Jack F.; de Pablo, Juan J. The Journal of Chemical Physics, Vol. 126, Issue 23 https://doi.org/10.1063/1.2742382	journal	June 2007
The Glass Transition of a Single Macromolecule Merling, Weston L.; Mileski, Johnathon B.; Douglas, Jack F. Macromolecules, Vol. 49, Issue 19 https://doi.org/10.1021/acs.macromol.6b01461	journal	September 2016
Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time Mirigian, Stephen; Schweizer, Kenneth S. The Journal of Physical Chemistry Letters, Vol. 4, Issue 21 https://doi.org/10.1021/jz4018943	journal	October 2013
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids Mirigian, Stephen; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 140, Issue 19 https://doi.org/10.1063/1.4874842	journal	May 2014
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids Mirigian, Stephen; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 140, Issue 19 https://doi.org/10.1063/1.4874843	journal	May 2014
Experimental test of a predicted dynamics–structure–thermodynamics connection in molecularly complex glass-forming liquids Mei, Baicheng; Zhou, Yuxing; Schweizer, Kenneth S. Proceedings of the National Academy of Sciences, Vol. 118, Issue 18 https://doi.org/10.1073/pnas.2025341118	journal	April 2021
Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts Mirigian, Stephen; Schweizer, Kenneth S. Macromolecules, Vol. 48, Issue 6 https://doi.org/10.1021/ma5022083	journal	March 2015
Experimental Tests of a Theoretically Predicted Noncausal Correlation between Dynamics and Thermodynamics in Glass-forming Polymer Melts Mei, Baicheng; Zhou, Yuxing; Schweizer, Kenneth S. Macromolecules, Vol. 54, Issue 21 https://doi.org/10.1021/acs.macromol.1c01633	journal	October 2021
A complex plane analysis of α-dispersions in some polymer systems Havriliak, S.; Negami, S. Journal of Polymer Science Part C: Polymer Symposia, Vol. 14, Issue 1 https://doi.org/10.1002/polc.5070140111	journal	January 1966
S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS Ediger, M. D. Annual Review of Physical Chemistry, Vol. 51, Issue 1 https://doi.org/10.1146/annurev.physchem.51.1.99	journal	October 2000
Role of local structure on motions on the potential energy landscape for a model supercooled polymer Jain, Tushar S.; de Pablo, Juan J. The Journal of Chemical Physics, Vol. 122, Issue 17 https://doi.org/10.1063/1.1888505	journal	May 2005
Nonlinear Creep in a Polymer Glass Riggleman, Robert A.; Schweizer, Kenneth S.; Pablo, Juan J. de Macromolecules, Vol. 41, Issue 13 https://doi.org/10.1021/ma8001214	journal	June 2008
Nature and interrelations of fast dynamic properties in a coarse-grained glass-forming polymer melt Simmons, David S.; Douglas, Jack F. Soft Matter, Vol. 7, Issue 22 https://doi.org/10.1039/c1sm06189e	journal	January 2011
The relationship between dynamic and pseudo-thermodynamic measures of the glass transition temperature in nanostructured materials Mangalara, Jayachandra Hari; Mackura, Mark E.; Marvin, Michael D. The Journal of Chemical Physics, Vol. 146, Issue 20 https://doi.org/10.1063/1.4977520	journal	May 2017
Dynamics of entangled linear polymer melts: A molecular‐dynamics simulation Kremer, Kurt; Grest, Gary S. The Journal of Chemical Physics, Vol. 92, Issue 8 https://doi.org/10.1063/1.458541	journal	April 1990
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
A unified formulation of the constant temperature molecular dynamics methods Nosé, Shuichi The Journal of Chemical Physics, Vol. 81, Issue 1 https://doi.org/10.1063/1.447334	journal	July 1984
Canonical dynamics: Equilibrium phase-space distributions Hoover, William G. Physical Review A, Vol. 31, Issue 3 https://doi.org/10.1103/PhysRevA.31.1695	journal	March 1985
An extension of the canonical ensemble molecular dynamics method Nosé, Shūichi Molecular Physics, Vol. 57, Issue 1 https://doi.org/10.1080/00268978600100141	journal	January 1986
Influence of the isomeric structures of butyl acrylate on its single-electron transfer-degenerative chain transfer living radical polymerization in water Catalyzed by Na₂S₂O₄ Coelho, Jorge F. J.; Carvalho, Erica Y.; Marques, Dina S. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 46, Issue 19 https://doi.org/10.1002/pola.22963	journal	October 2008
Is DNA a Good Model Polymer? Tree, Douglas R.; Muralidhar, Abhiram; Doyle, Patrick S. Macromolecules, Vol. 46, Issue 20 https://doi.org/10.1021/ma401507f	journal	October 2013
Bridging Simulation Length Scales of Bottlebrush Polymers Using a Wormlike Cylinder Model Dutta, Sarit; Pan, Tianyuan; Sing, Charles E. Macromolecules, Vol. 52, Issue 13 https://doi.org/10.1021/acs.macromol.9b00363	journal	June 2019
Isostaticity and the solidification of semiflexible polymer melts Plaza-Rivera, Christian O.; Nguyen, Hong T.; Hoy, Robert S. Soft Matter, Vol. 13, Issue 43 https://doi.org/10.1039/C7SM01442B	journal	January 2017
Fiber Network Formation in Semi-Flexible Polymer Solutions: An Exploratory Computational Study Vargas-Lara, Fernando; Douglas, Jack Gels, Vol. 4, Issue 2 https://doi.org/10.3390/gels4020027	journal	March 2018
Effect of Multiaxial Tensile Deformation on the Mechanical Properties of Semiflexible Polymeric Samples Kumar, Sunil; Pattanayek, Sudip Kumar The Journal of Physical Chemistry B, Vol. 123, Issue 43 https://doi.org/10.1021/acs.jpcb.9b00139	journal	October 2019
The smectic phase in semiflexible polymer materials: A large scale molecular dynamics study Milchev, Andrey; Nikoubashman, Arash; Binder, Kurt Computational Materials Science, Vol. 166 https://doi.org/10.1016/j.commatsci.2019.04.017	journal	August 2019
Glass transition and dynamics of semiflexible polymer brushes Huang, Jian-Hua; Sun, Dan-Dan; Lu, Rong-Xing Physical Chemistry Chemical Physics, Vol. 23, Issue 25 https://doi.org/10.1039/D1CP00089F	journal	January 2021
Thickness-Dependent Mechanical Failure in Thin Films of Glassy Polymer Bidisperse Blends Zhang, Tianren; Riggleman, Robert A. Macromolecules, Vol. 55, Issue 1 https://doi.org/10.1021/acs.macromol.1c01630	journal	December 2021
Polymer Chain Shape of Poly(3-alkylthiophenes) in Solution Using Small-Angle Neutron Scattering McCulloch, Bryan; Ho, Victor; Hoarfrost, Megan Macromolecules, Vol. 46, Issue 5 https://doi.org/10.1021/ma302463d	journal	February 2013
Communication: Polymer entanglement dynamics: Role of attractive interactions Grest, Gary S. The Journal of Chemical Physics, Vol. 145, Issue 14 https://doi.org/10.1063/1.4964617	journal	October 2016
A coarse-grained polymer model for studying the glass transition Hsu, Hsiao-Ping; Kremer, Kurt The Journal of Chemical Physics, Vol. 150, Issue 9 https://doi.org/10.1063/1.5089417	journal	March 2019
The influence of the magnetic filler concentration on the properties of a microgel particle: Zero-field case Minina, E. S.; Sánchez, P. A.; Likos, C. N. Journal of Magnetism and Magnetic Materials, Vol. 459 https://doi.org/10.1016/j.jmmm.2017.10.107	journal	August 2018
Computational investigation of microgels: synthesis and effect of the microstructure on the deswelling behavior Moreno, Angel J.; Lo Verso, Federica Soft Matter, Vol. 14, Issue 34 https://doi.org/10.1039/C8SM01407H	journal	January 2018
Development of a Coarse-Grained Model of Chitosan for Predicting Solution Behavior Benner, Steven W.; Hall, Carol K. The Journal of Physical Chemistry B, Vol. 120, Issue 29 https://doi.org/10.1021/acs.jpcb.6b03407	journal	July 2016
Effect of Monomer Sequence and Degree of Acetylation on the Self-Assembly and Porosity of Chitosan Networks in Solution Benner, Steven W.; Hall, Carol K. Macromolecules, Vol. 49, Issue 14 https://doi.org/10.1021/acs.macromol.6b01063	journal	July 2016
Polymer Chemistry Lodge, Timothy P.; Hiemenz, Paul C. https://doi.org/10.1201/9780429190810	book	January 2020
Glass Transition of Disentangled and Entangled Polymer Melts: Single-Chain-Nanoparticles Approach Singh, Manjesh K.; Hu, Minghan; Cang, Yu Macromolecules, Vol. 53, Issue 17 https://doi.org/10.1021/acs.macromol.0c00550	journal	August 2020
Investigating the influence of different thermodynamic paths on the structural relaxation in a glass-forming polymer melt Bennemann, Christoph; Paul, Wolfgang; Baschnagel, Jörg Journal of Physics: Condensed Matter, Vol. 11, Issue 10 https://doi.org/10.1088/0953-8984/11/10/005	journal	January 1999
Free Volume and Finite-Size Effects in a Polymer Glass under Stress Riggleman, Robert A.; Lee, Hau-Nan; Ediger, M. D. Physical Review Letters, Vol. 99, Issue 21 https://doi.org/10.1103/PhysRevLett.99.215501	journal	November 2007
Influence of Backbone Rigidity on Nanoscale Confinement Effects in Model Glass-Forming Polymers Shavit, Amit; Riggleman, Robert A. Macromolecules, Vol. 46, Issue 12 https://doi.org/10.1021/ma400210w	journal	June 2013
The microscopic origins of stretched exponential relaxation in two model glass-forming liquids as probed by simulations in the isoconfigurational ensemble Diaz Vela, Daniel; Simmons, David S. The Journal of Chemical Physics, Vol. 153, Issue 23 https://doi.org/10.1063/5.0035609	journal	December 2020
Origin of Mechanical Enhancement in Polymer Nanoparticle (NP) Composites with Ultrahigh NP Loading Lin, Emily Y.; Frischknecht, Amalie L.; Riggleman, Robert A. Macromolecules, Vol. 53, Issue 8 https://doi.org/10.1021/acs.macromol.9b02733	journal	April 2020
Thermodynamics–Structure–Dynamics Correlations and Nonuniversal Effects in the Elastically Collective Activated Hopping Theory of Glass-Forming Liquids Mei, Baicheng; Zhou, Yuxing; Schweizer, Kenneth S. The Journal of Physical Chemistry B, Vol. 124, Issue 28 https://doi.org/10.1021/acs.jpcb.0c03613	journal	July 2020
Microscopic Theory of the Effect of Caging and Physical Bonding on Segmental Relaxation in Associating Copolymer Liquids Ghosh, Ashesh; Schweizer, Kenneth S. Macromolecules, Vol. 53, Issue 11 https://doi.org/10.1021/acs.macromol.0c00415	journal	May 2020
Nonuniversal Coupling of Cage Scale Hopping and Collective Elastic Distortion as the Origin of Dynamic Fragility Diversity in Glass-Forming Polymer Liquids Xie, Shi-Jie; Schweizer, Kenneth S. Macromolecules, Vol. 49, Issue 24 https://doi.org/10.1021/acs.macromol.6b02272	journal	December 2016
Entropic barriers, activated hopping, and the glass transition in colloidal suspensions Schweizer, Kenneth S.; Saltzman, Erica J. The Journal of Chemical Physics, Vol. 119, Issue 2 https://doi.org/10.1063/1.1578632	journal	July 2003
Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 123, Issue 24 https://doi.org/10.1063/1.2137701	journal	December 2005
Source of non-Arrhenius average relaxation time in glass-forming liquids Dyre, Jeppe C. Journal of Non-Crystalline Solids, Vol. 235-237 https://doi.org/10.1016/S0022-3093(98)00502-X	journal	August 1998
Colloquium : The glass transition and elastic models of glass-forming liquids Dyre, Jeppe C. Reviews of Modern Physics, Vol. 78, Issue 3 https://doi.org/10.1103/RevModPhys.78.953	journal	September 2006
Brownian motion in a field of force and the diffusion model of chemical reactions Kramers, H. A. Physica, Vol. 7, Issue 4 https://doi.org/10.1016/S0031-8914(40)90098-2	journal	April 1940
Reaction-rate theory: fifty years after Kramers Hänggi, Peter; Talkner, Peter; Borkovec, Michal Reviews of Modern Physics, Vol. 62, Issue 2 https://doi.org/10.1103/RevModPhys.62.251	journal	April 1990
Integral equation theory of thermodynamics, pair structure, and growing static length scale in metastable hard sphere and Weeks-Chandler-Andersen fluids Zhou, Yuxing; Mei, Baicheng; Schweizer, Kenneth S. Physical Review E, Vol. 101, Issue 4 https://doi.org/10.1103/PhysRevE.101.042121	journal	April 2020
Local structure of semiflexible polymer melts Honnell, Kevin G.; Curro, John G.; Schweizer, Kenneth S. Macromolecules, Vol. 23, Issue 14 https://doi.org/10.1021/ma00216a018	journal	July 1990
Activated relaxation in supercooled monodisperse atomic and polymeric WCA fluids: Simulation and ECNLE theory Zhou, Yuxing; Mei, Baicheng; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 156, Issue 11 https://doi.org/10.1063/5.0079221	journal	March 2022
Ideal glass transitions, shear modulus, activated dynamics, and yielding in fluids of nonspherical objects Yatsenko, Galina; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 126, Issue 1 https://doi.org/10.1063/1.2405354	journal	January 2007
The influence of shape on the glassy dynamics of hard nonspherical particle fluids. I. Dynamic crossover and elasticity Tripathy, Mukta; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 130, Issue 24 https://doi.org/10.1063/1.3157279	journal	June 2009
Theory of activated glassy dynamics in randomly pinned fluids Phan, Anh D.; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 148, Issue 5 https://doi.org/10.1063/1.5011247	journal	February 2018
Nature of dynamic gradients, glass formation, and collective effects in ultrathin freestanding films Ghanekarade, Asieh; Phan, Anh D.; Schweizer, Kenneth S. Proceedings of the National Academy of Sciences, Vol. 118, Issue 31 https://doi.org/10.1073/pnas.2104398118	journal	July 2021
Theory of gelation, vitrification, and activated barrier hopping in mixtures of hard and sticky spheres Viehman, Douglas C.; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 128, Issue 8 https://doi.org/10.1063/1.2837295	journal	February 2008
Long Wavelength Thermal Density Fluctuations in Molecular and Polymer Glass-Forming Liquids: Experimental and Theoretical Analysis under Isobaric Conditions Mei, Baicheng; Zhou, Yuxing; Schweizer, Kenneth S. The Journal of Physical Chemistry B, Vol. 125, Issue 44 https://doi.org/10.1021/acs.jpcb.1c06840	journal	November 2021
Relaxation in liquids, polymers and plastic crystals — strong/fragile patterns and problems Angell, C. A. Journal of Non-Crystalline Solids, Vol. 131-133 https://doi.org/10.1016/0022-3093(91)90266-9	journal	June 1991
Influence of Crosslinking on the Molecular Relaxation of an Amorphous Copolymer Near Its Glass-Transition Temperature Glatz-Reichenbach, Joachim K. W.; Sorriero, Louis; Fitzgerald, John J. Macromolecules, Vol. 27, Issue 6 https://doi.org/10.1021/ma00084a010	journal	March 1994
Segmental Dynamics in Poly(methylphenylsiloxane) Networks by Dielectric Relaxation Spectroscopy Fitz, Benjamin D.; Mijovic, Jovan Macromolecules, Vol. 32, Issue 10 https://doi.org/10.1021/ma981937b	journal	April 1999
Constraints on Local Segmental Motion in Poly(vinylethylene) Networks Roland, C. M. Macromolecules, Vol. 27, Issue 15 https://doi.org/10.1021/ma00093a027	journal	July 1994
Influence of cross-linking on the segmental dynamics in model polymer networks Kramarenko, V. Yu; Ezquerra, T. A.; Šics, I. The Journal of Chemical Physics, Vol. 113, Issue 1 https://doi.org/10.1063/1.481809	journal	July 2000
Viscoelastic Behavior of Poly(methyl methacrylate) Networks with Different Cross-Linking Degrees Alves, N. M.; Gómez Ribelles, J. L.; Gómez Tejedor, J. A. Macromolecules, Vol. 37, Issue 10 https://doi.org/10.1021/ma035626z	journal	April 2004
Segmental Relaxation Characteristics of Cross-Linked Poly(ethylene oxide) Copolymer Networks Kalakkunnath, Sumod; Kalika, Douglass S.; Lin, Haiqing Macromolecules, Vol. 38, Issue 23 https://doi.org/10.1021/ma051741t	journal	November 2005
Cross-Linking Effect on Segmental Dynamics of Well-Defined Epoxy Resins Shundo, Atsuomi; Aoki, Mika; Yamamoto, Satoru Macromolecules, Vol. 54, Issue 13 https://doi.org/10.1021/acs.macromol.1c00513	journal	June 2021
Segmental Relaxation in End-Linked Poly(dimethylsiloxane) Networks Schroeder, M. J.; Roland, C. M. Macromolecules, Vol. 35, Issue 7 https://doi.org/10.1021/ma011678h	journal	March 2002
Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers Fox, T. G.; Loshaek, S. Journal of Polymer Science, Vol. 15, Issue 80 https://doi.org/10.1002/pol.1955.120158006	journal	February 1955
Crosslinked polymers. II. Glass temperatures of copolymers of methyl methacrylate and glycol dimethacrylates Loshaek, S. Journal of Polymer Science, Vol. 15, Issue 80 https://doi.org/10.1002/pol.1955.120158007	journal	February 1955
Cross-Linking–Effect on Physical Properties of Polymers Nielsen, Lawrence E. Journal of Macromolecular Science, Part C, Vol. 3, Issue 1 https://doi.org/10.1080/15583726908545897	journal	January 1969
Glass transition elevation of polystyrene by crosslinks Glans, J. H.; Turner, D. T. Polymer, Vol. 22, Issue 11 https://doi.org/10.1016/0032-3861(81)90326-8	journal	November 1981
The heat capacity of solid and liquid polystyrene, p-substituted polystyrenes, and crosslinked polystyrenes Judovits, Lawrence H.; Bopp, R. C.; Gaur, U. Journal of Polymer Science Part B: Polymer Physics, Vol. 24, Issue 12 https://doi.org/10.1002/polb.1986.090241209	journal	December 1986
Correlation between glass transition temperature and chain structure for randomly crosslinked high polymers Bicerano, Jozef; Sammler, Robert L.; Carriere, Craig J. Journal of Polymer Science Part B: Polymer Physics, Vol. 34, Issue 13 https://doi.org/10.1002/(SICI)1099-0488(19960930)34:13<2247::AID-POLB14>3.0.CO;2-5	journal	September 1996
Influence of Network Structure on Glass Transition Temperature of Elastomers Bandzierz, Katarzyna; Reuvekamp, Louis; Dryzek, Jerzy Materials, Vol. 9, Issue 7 https://doi.org/10.3390/ma9070607	journal	July 2016
Second‐Order Transitions and Mesh Distribution Functions of Cross‐Linked Polystyrenes Ueberreiter, Kurt; Kanig, Gerhard The Journal of Chemical Physics, Vol. 18, Issue 4 https://doi.org/10.1063/1.1747650	journal	April 1950
Zur Theorie der Glastemperatur von Vernetzten Polymeren Kanig, Gerhard Journal of Polymer Science Part C: Polymer Symposia, Vol. 16, Issue 4 https://doi.org/10.1002/polc.5070160411	journal	January 1967
A generalized theory for the glass transition temperature of crosslinked and uncrosslinked polymers Stutz, H.; Illers, K. -H.; Mertes, J. Journal of Polymer Science Part B: Polymer Physics, Vol. 28, Issue 9 https://doi.org/10.1002/polb.1990.090280906	journal	August 1990

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